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  • 1
    Publication Date: 2023-07-19
    Description: Present estimates of the biogeochemical cycles of calcium, strontium, and potassium in the ocean reveal large imbalances between known input and output fluxes. Using pore fluid, incubation, and solid sediment data from North Pacific multi‐corer cores we show that, contrary to the common paradigm, the top centimeters of abyssal sediments can be an active site of authigenic precipitation of clay minerals. In this region, clay authigenesis is the dominant sink for potassium and strontium and consumes nearly all calcium released from benthic dissolution of calcium carbonates. These observations support the idea that clay authigenesis occurring over broad regions of the world ocean may be a major buffer for ocean chemistry on the time scale of the ocean overturning circulation, and key to the long‐term stability of Earth's climate.
    Description: Key Points: North Pacific red clay sediments are a sink for marine calcium, strontium, and potassium. Authigenic formation of clay minerals is prevalent in pelagic sediments throughout the North Pacific. The main mechanism for clay formation is recrystallization of aluminosilicates, neoformation can occur in biogenic silica rich sediments.
    Description: EC H2020 PRIORITY “Excellent science” H2020 European Research Council http://dx.doi.org/10.13039/100010663
    Description: Blavatnik Family Foundation http://dx.doi.org/10.13039/100011643
    Description: Isaac Newton Trust http://dx.doi.org/10.13039/501100004815
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.pangaea.de/10.1594/PANGAEA.946881
    Keywords: ddc:549 ; reverse weathering ; clay authigenesis ; calcium ; potassium ; porewater ; strontium
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2024-03-13
    Description: The PERCIVAL detector is a CMOS imager designed for the soft X‐ray regime at photon sources. Although still in its final development phase, it has recently seen its first user experiments: ptychography at a free‐electron laser, holographic imaging at a storage ring and preliminary tests on X‐ray photon correlation spectroscopy. The detector performed remarkably well in terms of spatial resolution achievable in the sample plane, owing to its small pixel size, large active area and very large dynamic range; but also in terms of its frame rate, which is significantly faster than traditional CCDs. In particular, it is the combination of these features which makes PERCIVAL an attractive option for soft X‐ray science.
    Keywords: ddc:548 ; X‐ray detectors ; soft X‐rays ; ptychography ; holographic imaging ; XPCS ; detectors
    Language: English
    Type: doc-type:article
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  • 3
    Publication Date: 2021-03-29
    Description: During the first week of the 2011 El Hierro submarine eruption, abundant light-coloured pumiceous, high-silica volcanic bombs coated in dark basanite were found floating on the sea. The composition of the light-coloured frothy material (‘xeno-pumice’) is akin to that of sedimentary rocks from the region, but the textures resemble felsic magmatic pumice, leaving their exact mode of formation unclear. To help decipher their origin, we investigated representative El Hierro xeno-pumice samples using X-ray computed microtomography for their internal vesicle shapes, volumes, and bulk porosity, as well as for the spatial arrangement and size distributions of vesicles in three dimensions (3D). We find a wide range of vesicle morphologies, which are especially variable around small fragments of rock contained in the xeno-pumice samples. Notably, these rock fragments are almost exclusively of sedimentary origin, and we therefore interpret them as relicts an the original sedimentary ocean crust protolith(s). The irregular vesiculation textures observed probably resulted from pulsatory release of volatiles from multiple sources during xeno-pumice formation, most likely by successive release of pore water and mineral water during incremental heating and decompression of the sedimentary protoliths.
    Keywords: El Hierro; Xeno-pumice; X-CT imaging; Vesicle morphologies; Vesicle size distribution; Heterogeneous vesiculation; Sedimentary ocean crust ; 551
    Language: English
    Type: article , publishedVersion
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  • 4
    Publication Date: 2021-03-30
    Description: The ATSAS software suite encompasses a number of programs for the processing, visualization, analysis and modelling of small‐angle scattering data, with a focus on the data measured from biological macromolecules. Here, new developments in the ATSAS 3.0 package are described. They include IMSIM, for simulating isotropic 2D scattering patterns; IMOP, to perform operations on 2D images and masks; DATRESAMPLE, a method for variance estimation of structural invariants through parametric resampling; DATFT, which computes the pair distance distribution function by a direct Fourier transform of the scattering data; PDDFFIT, to compute the scattering data from a pair distance distribution function, allowing comparison with the experimental data; a new module in DATMW for Bayesian consensus‐based concentration‐independent molecular weight estimation; DATMIF, an ab initio shape analysis method that optimizes the search model directly against the scattering data; DAMEMB, an application to set up the initial search volume for multiphase modelling of membrane proteins; ELLLIP, to perform quasi‐atomistic modelling of liposomes with elliptical shapes; NMATOR, which models conformational changes in nucleic acid structures through normal mode analysis in torsion angle space; DAMMIX, which reconstructs the shape of an unknown intermediate in an evolving system; and LIPMIX and BILMIX, for modelling multilamellar and asymmetric lipid vesicles, respectively. In addition, technical updates were deployed to facilitate maintainability of the package, which include porting the PRIMUS graphical interface to Qt5, updating SASpy – a PyMOL plugin to run a subset of ATSAS tools – to be both Python 2 and 3 compatible, and adding utilities to facilitate mmCIF compatibility in future ATSAS releases. All these features are implemented in ATSAS 3.0, freely available for academic users at https://www.embl‐hamburg.de/biosaxs/software.html.
    Description: ATSAS is a comprehensive software suite for the processing, visualization, analysis and modelling of small‐angle scattering data. This article describes developments in the ATSAS 3.0 release, including new programs for data simulation and for the structural modelling of lipids, nucleic acids and polydisperse systems. image
    Keywords: 548 ; small‐angle scattering ; data analysis ; biological macromolecules ; structural modelling ; ATSAS
    Type: article
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  • 5
    Publication Date: 2021-03-29
    Description: Methane-related carbonates from Hydrate Ridge typically show several macroscopically distinguishable mineral phases, namely whitish aragonite, lucent aragonite, and gray micrite. The relationship of these phases to particular microorganisms or biogeochemical processes is as yet unclear. We used a miniaturized biomarker technique on mg samples, combined with factor analysis and subsequent electron microprobe analysis, to study lipid biomarkers and chemical compositions of the individual phases. This allows us to identify particular mechanisms involved in the formation of the different carbonate precipitates. Our combined analysis of biomarkers and petrographic traits shows that most of the lipids related to the anaerobic oxidation of methane (〉90% by weight) are concentrated within only a minor compartment ( 20% by volume) of the Hydrate Ridge carbonates, the whitish aragonite. The patterns indicate that the whitish aragonite represents fossilized biofilms of methanotrophic consortia containing mainly archaea of the ANME-2 group and sulfate reducing bacteria, whereas the precipitation of the lucent aragonite may have lacked the immediate proximity of microorganisms during formation. By contrast, the gray micrite formed by incorporation of allochthonous organic and inorganic matter during carbonate precipitation induced by the anaerobic oxidation of methane involving ANME-1 archaea.
    Keywords: mineral phases; ANME-1 archaea ; 551
    Language: English
    Type: article , publishedVersion
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  • 6
    Publication Date: 2021-07-04
    Description: More than 40 model groups worldwide are participating in the Coupled Model Intercomparison Project Phase 6 (CMIP6), providing a new and rich source of information to better understand past, present, and future climate change. Here, we use the Earth System Model Evaluation Tool (ESMValTool) to assess the performance of the CMIP6 ensemble compared to the previous generations CMIP3 and CMIP5. While CMIP5 models did not capture the observed pause in the increase in global mean surface temperature between 1998 and 2013, the historical CMIP6 simulations agree well with the observed recent temperature increase, but some models have difficulties in reproducing the observed global mean surface temperature record of the second half of the twentieth century. While systematic biases in annual mean surface temperature and precipitation remain in the CMIP6 multimodel mean, individual models and high‐resolution versions of the models show significant reductions in many long‐standing biases. Some improvements are also found in the vertical temperature, water vapor, and zonal wind speed distributions, and root‐mean‐square errors for selected fields are generally smaller with reduced intermodel spread and higher average skill in the correlation patterns relative to observations. An emerging property of the CMIP6 ensemble is a higher effective climate sensitivity with an increased range between 2.3 and 5.6 K. A possible reason for this increase in some models is improvements in cloud representation resulting in stronger shortwave cloud feedbacks than in their predecessor versions.
    Description: Key Points: Temperature, water vapor, and zonal wind speed show improvements in CMIP6 with amplitudes of many long‐standing biases smaller than CMIP3/5. High‐resolution models show significant improvements in their historical CMIP6 simulations for temperature and precipitation mean biases. Spread in effective climate sensitivity in CMIP6 is larger than in previous phases.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: National Center for Atmospheric Research (NCAR) http://dx.doi.org/10.13039/100005323
    Description: U.S. Department of Energy (DOE) http://dx.doi.org/10.13039/100000015
    Description: European Space Agency (ESA) http://dx.doi.org/10.13039/501100000844
    Description: German Federal Ministry of Education and Research (BMBF)
    Description: PRIMAVERA
    Description: Coordinated Research in Earth Systems and Climate: Experiments, kNowledge, Dissemination and Outreach (CRESCENDO)
    Description: European Union's Framework Programme Horizon 2020 for Research and Innovation
    Keywords: 551.6 ; climate model ; evaluation ; CMIP
    Type: article
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  • 7
    Publication Date: 2021-06-26
    Description: The high‐precision X‐ray diffraction setup for work with diamond anvil cells (DACs) in interaction chamber 2 (IC2) of the High Energy Density instrument of the European X‐ray Free‐Electron Laser is described. This includes beamline optics, sample positioning and detector systems located in the multipurpose vacuum chamber. Concepts for pump–probe X‐ray diffraction experiments in the DAC are described and their implementation demonstrated during the First User Community Assisted Commissioning experiment. X‐ray heating and diffraction of Bi under pressure, obtained using 20 fs X‐ray pulses at 17.8 keV and 2.2 MHz repetition, is illustrated through splitting of diffraction peaks, and interpreted employing finite element modeling of the sample chamber in the DAC.
    Description: The high‐precision X‐ray diffraction (XRD) setup for work with diamond anvil cells (DACs) in Interaction Chamber 2 of the High Energy Density (HED) instrument of the European X‐ray Free‐Electron Laser is described. image
    Keywords: 548 ; diamond anvil cells ; X‐ray free‐electron lasers ; high‐precision X‐ray diffraction ; finite element modeling
    Type: article
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  • 8
    Publication Date: 2021-07-21
    Description: The lunar meteorite Dhofar 1436 is dominated by solar wind type noble gases. Solar argon is equilibrated with “parentless” 40Ar commonly known as lunar orphan argon. Ar‐Ar isochron analyses determined the lunar trapped 40Ar/36Ar ratio to 2.51 ± 0.04, yielding a corrected plateau age of 4.1 ± 0.1 Ga, consistent with the lunar Late Heavy Bombardment period. Lunar trapped and radiogenic argon components are all released at high temperatures (1200–1400 °C). Surprisingly, solar noble gases and lunar trapped argon can largely be released by crushing. Initial crushing steps mainly release elementally fractionated solar wind gases, while in advanced crushing steps, cosmogenic components dominate. Cosmogenic noble gases indicate irradiation at the lunar surface; they are less fractionated than solar wind species. We favor a scenario in which both solar and a large fraction of cosmogenic gases were acquired before the 4.1 Ga event, which caused shock metamorphism and formation of the regolith breccia. Sintering and agglutination along grain boundaries resulted in mobilization of solar wind, reimplanted, radiogenic, and cosmogenic noble gases, and resulted in their partial homogenization, fractionation, and retrapping in voids and/or defects accessible by crushing. An alternative scenario would be complete reset of the K‐Ar system 4.1 Ga ago accompanied by loss of all previously accumulated solar and cosmogenic noble gases. Later, the precursor of Dhofar 1436 became lunar regolith and accumulated solar and cosmogenic noble gases and reimplanted 40Ar before its final formation of the polymict impact breccia. The C abundance of the step‐combusted Dhofar 1436 is 555.3 ppm, with δ13C of −28‰ to +11‰. Nitrogen contents released by crushing and combustion are 3.2 ppm and 20.8 ppm, respectively. The lightest nitrogen composition (δ15N = −79‰) is likely due to release from voids of shock metamorphic phases and is rather a result of the mobilization of nitrogen components that accumulated prior to the 4.1 Ga event.
    Description: Klaus Tschira Stiftung http://dx.doi.org/10.13039/501100007316
    Keywords: 523.51 ; 551.9 ; 549.112 ; lunar meteorite Dhofar 1436 ; impact melt breccia ; argon isotope data ; noble gas measurements
    Type: article
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  • 9
    Publication Date: 2021-09-27
    Description: How the solar electromagnetic energy entering the Earth's atmosphere varied since preindustrial times is an important consideration in the climate change debate. Detrimental to this debate, estimates of the change in total solar irradiance (TSI) since the Maunder minimum, an extended period of weak solar activity preceding the industrial revolution, differ markedly, ranging from a drop of 0.75 W m−2 to a rise of 6.3 W m−2. Consequently, the exact contribution by solar forcing to the rise in global temperatures over the past centuries remains inconclusive. Adopting a novel approach based on state-of-the-art solar imagery and numerical simulations, we establish the TSI level of the Sun when it is in its least-active state to be 2.0 ± 0.7 W m−2 below the 2019 level. This means TSI could not have risen since the Maunder minimum by more than this amount, thus restricting the possible role of solar forcing in global warming.
    Keywords: 551.5 ; total solar irradiance
    Language: English
    Type: map
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  • 10
    Publication Date: 2023-09-14
    Description: Crustal architecture strongly influences the development and emplacement of mineral zones. In this study, we image the crustal structure beneath a metallogenic belt and its surroundings in the Bayankhongor area of central Mongolia. In this region, an ophiolite belt marks the location of an ancient suture zone, which is presently associated with a reactivated fault system. Nearby, metamorphic and volcanic belts host important mineralization zones and constitute a significant metallogenic belt that includes sources of copper and gold. However, the crustal structure of these features, and their relationships, are poorly studied. We analyze magnetotelluric data acquired across this region and generate three-dimensional electrical resistivity models of the crustal structure, which is found to be locally highly heterogeneous. Because the upper crust (〈 25 km) is found to be generally highly resistive (〉 1000 Ωm), low-resistivity (〈 50 Ωm) features are conspicuous. Anomalous low-resistivity zones are congruent with the suture zone, and ophiolite belt, which is revealed to be a major crustal-scale feature. Furthermore, broadening low-resistivity zones located down-dip from the suture zone suggest that the narrow deformation zone observed at the surface transforms to a wide area in the deeper crust. Other low-resistivity anomalies are spatially associated with the surface expressions of known mineralization zones; thus, their links to deeper crustal structures are imaged. Considering the available evidence, we determine that, in both cases, the low resistivity can be explained by hydrothermal alteration along fossil fluid pathways. This illustrates the pivotal role that crustal fluids play in diverse geological processes, and highlights their inherent link in a unified system, which has implications for models of mineral genesis and emplacement. The results demonstrate that the crustal architecture—including the major crustal boundary—acts as a first‐order control on the location of the metallogenic belt.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711
    Description: Westfälische Wilhelms-Universität Münster (1056)
    Keywords: ddc:553 ; Metallogenic belt ; Ophiolite belt ; Fault zone ; Mineralization ; Mineral emplacement ; Electrical resistivity
    Language: English
    Type: doc-type:article
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