ISSN:
1573-9171
Keywords:
EPR
;
radical ions
;
aryl- and diaryldiazocyanides
;
electrochemical reduction
;
calculation of spin density
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract EPR and quantum chemical methods have been used to establish the nature of the distribution of spin density in electrochemically generated radical anions of diaryldiazocyanides. For the symmetrical diphenyldiazocyanides the unshared electron is distributed over the entire molecule, whereas the introduction of a bridge between the benzene rings leads to the localization of the unshared electron only on one fragment of the molecule.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00864181
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