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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Experiments in fluids 16 (1993), S. 36-41 
    ISSN: 1432-1114
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract LDA measurements were made of mean velocity and of turbulence intensity in a 39.4mm diameter tube, the first measurements in three directions on drag reducing surfactant solutions (0.05% and 0.1% Habon G). Drag reduction exceeded the predictions of the Virk maximum drag reduction asymptote and elastic sublayer mean velocity profiles are steeper than the profile proposed by Virk for maximum drag reducing asymptote solutions. Axial turbulence intensities for Habon G solutions are higher than those for water near the wall, lower in most of the outer region and about the same at the center. Tangential and radial turbulence intensities are lower than those for water.
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 33 (1994), S. 3256-3261 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 61 (1969), S. 22-30 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 247 (1974), S. 243-244 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SIR-Results described in the letter by Kudin et a/.1 increase the number of types of materials which have been cut by an impacting jet containing traces of soluble polymers. The hypothesis propounded by the authors, that increase in erosion capability is due to the rigidity of large aggregates of ...
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  • 5
    ISSN: 1435-1528
    Keywords: Key words Mixed cationic surfactants ; Turbulent drag reduction ; Rheology ; Apparent extensional viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract Experimental studies of the effects of mixtures of cationic surfactants on their drag reduction and rheological behaviors are reported. Cationic alkyl trimethyl quaternary ammonium surfactants with alkyl chain lengths of C12 and C22 were mixed at different molar ratios (total surfactant concentrations were kept at 5 mM with 12.5 mM sodium salicylate (NaSal) as counterion). Drag reduction tests showed that by adding 10% (mol) of C12, the effective drag reduction range expanded to 4–120 °C, compared with 80–130 °C with only the C22 surfactant. Thus mixing cationic surfactants with different alkyl chain lengths is an effective way of tuning the drag reduction temperature range. Cryo-TEM micrographs revealed thread-like micellar networks for surfactant solutions in the drag reducing temperature range, while vesicles were the dominant microstructures at non-drag reducing temperatures. High extensional viscosity was the main rheological feature for all solutions except 50% C12 (mol) solution, which also does not show strong viscoelasticity. It is not clear why this low extensional viscosity solution with relatively weak viscoelasticity is a good drag reducer.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Flow, turbulence and combustion 55 (1995), S. 297-310 
    ISSN: 1573-1987
    Keywords: cationic surfactant drag reduction ; shear induced structure ; viscoelasticity ; turbulence intensities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract There is considerable interest in the use of viscoelastic cationic surfactant-counterion mixtures in district heating and cooling systems to reduce pressure losses. A recent field test in a secondary system near Prague showed a 30+% reduction in pumping energy requirements. We have studied a number of commercial surfactants and we report here results of rheological, drag reduction and turbulence measurements on Arquad 18–50 (octadecyl trimethyl ammonium chloride (AR 18)) with an excess of sodium salicylate (NA). The concentration studied was 1.6 mM AR 18 and 4.0 mM NA which is about one third the concentration for excellent drag reduction in this surfactant's effective temperature range 30–90°C. Viscosity, η, vs. shear rate,D, first normal stress difference,N 1, vs. shear rate, drag reduction (as pressure drop,i=ΔP/1) vs. average velocity,U ave, in a 39.4 mm tube for AR 18, and turbulence intensity data for three drag reducing surfactants are reported. Of particular interest are the generally low turbulence intensities in all three directions which correspond to reduced heat, mass and momentum transfer rates compared to water, and the existence of large normal stress differences at 20°C for AR 18, a temperature at which no drag reduction occurs with this surfactant, indicating that normal stress effects do not correlate directly with drag reduction. The effect of time of pumping on increasing drag reduction demonstrates that this factor overwhelms the expected increase in drag reduction as temperature is raised from 18–19°C to 40.5°C.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 513-519 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Longitudinal turbulence intensities, autocorrelations, and energy spectra have been measured in the flow of toluene, benzene, and cyclohexane in smooth, round 1- and 2-in. I.D. tubes. These measurements were made with a constant-temperature hot-film anemometer and covered radial positions from the center to r/a = 0.85 in the 2-in. tube and to r/a = 0.75 in the 1-in. tube.The turbulence intensity data were found to be similar to those obtained for air in a 10-in. pipe by Laufer. A slight diameter effect was observed, the intensities in the 1-in. tube being slightly lower than those in the 2-in. tube at equal Reynolds numbers.The energy spectra were similar to the spectrum reported by Lee and Brodkey for water. The spectra reached higher frequencies at the lowest measurable energy levels for higher velocities. There was little effect of tube diameter or radial position on the spectra from the center to r/a = 0.85. A short inertial subrange with a log-log slope of -5/3 seemed evident in high velocity spectra, and the log-log slope of -7 was approached at high frequencies by the lowest velocity spectrum.The peak energy dissipation frequencies for all the energy spectra measured were approximately proportional to bulk mean velocity to the 1.4 power with little effect of tube diameter or radial position from the center to r/a = 0.85.Integral scales of the turbulence were proportional to bulk mean velocity to a power less than one for a given tube. These measurements indicated that the ratio of integral scale to pipe diameter is not a function of Reynolds number only.Microscale values were relatively independent of velocity and pipe diameter.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 391-397 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Turbulent measurements in capillary tubes and in pipes were made on nonpolar solutions of seven polymer species, three at more than one molecular weight, over wide concentration ranges.A critical concentration, Cc, was taken as the minimum concentration for disappearance of the turbulence transition region. Above this concentration, friction factor-generalized Reynolds number data show only a gradual deviation from extension of the laminar line. Cc increases with tube diameter and decreases with molecular weight. The critical dimensionless volume friction Cc [η] is less dependent on molecular weight.The levels of Cc [η] for different polymer species in a given tube show marked differences which are related to β, the molecular rigidity parameter. Low β values, or high flexibility, are associated with low Cc [η] values. Available data for Cc [η] in good and in poor solvents show little solvency effect.Polymer samples of low m′, the ratio of the polymer molecular weight to the critical tanglement molecular weight of the polymer, give solutions with little or no drag-reducing capacity, even those with low β values. Samples must have m′ values of 50 or more to show significant drag reduction. This allows prediction of the minimum useful molecular weights for drag reduction for any polymer species.For solutions above Cc, all of these data and literature data (for aqueous and nonaqueous systems with a wide range of n′ values) fit a single f/fpv versus generalized Reynolds number relationship.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 1455-1473 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Length-temperature measurements on a series of polymer blends over the whole range of composition from pure polyethylene to pure polypropylene and one set of determinations on a 50:50 copolymer and on polystyrene are evaluated. The total crystallinity of the samples did not exceed 54%. The experimental procedure utilized a linear variable differential transformer without the use of a confining fluid, and the temperature ranged from about +20 to -185°C. A least-square numerical differentiation procedure based on moving arcs is applied to yield directly the coefficients of thermal expansion as a function of temperature. The linear voltage differential transformer (LVDT) technique can detect transitions in which the change in thermal expansion coefficients is less than 10-5°C.-1. In polypropylene as well as the blends, the principal glass transition is clearly seen in the range observed by others, namely at about -9 to -14°C. Its location varies only slightly with composition at polyethylene contents less than 88 mole-%. For polyethylene the transition region broadens noticeably. The results are suggestive of two transitions for 0 〉 T 〉 -40°C. A second transition region is observed for either pure component around -126°C. Its location varies some what with composition. However, our results do not indicate the appearance of an additional transition region characteristic of the mixture. The copolymer exhibits a major transition at -61°C. in good agreement with earlier workers. The thermal expansion decreases again around -150°C. In general our observations concerning transitions below Tg are consistent with dynamic results.
    Additional Material: 12 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 3235-3240 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Experimental results on mechanical degradation in capillary tubes of polyisobutylene polymers in dilute solution are described. In laminar flow, degradation is independent of tube length, indicating that entrance effects are dominant. This shows that capillary experiments do not yield explicit information on the effect of shear stress on mechanical degradation. In turbulent flow, large entrance effects are also observed, but some degradation does take place in the fully developed flow region.
    Additional Material: 5 Ill.
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