ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Chemistry of Silicon-Sulphur Compounds. XVI. Derivatives of Trialkoxysilanethiols with the Main Groups I and II Elements and Preparation of Pure TrialkoxysilanethiolsTrialkoxysilanethiolates: (RO)3SiSMI and [(RO)3SiS]2MII (R 7dbond; Me, i-Pr, s-Bu, t-Bu, s-Am; MI = Li, Na, K; MII = Ca, Sr, Ba) were prepared in reaction of trialkoxysilanethiols and metals. Hydrates and THF solvates of these salts can also be formed.From sodium trialkoxysilanethiolates pure thiols (i-PrO)3SiSH and (s-BuO)3SiSH were prepared.
Notes:
Trialkoxythiosilanolate: (RO)3SiSMI und [(RO)3SiS]2MII (R = Me, i-Pr, s-Bu, t-Bu, s-Am; MI = Li, Na, K; MII = Ca, Sr, Ba) wurden aus Trialkoxysilanthiolen und Metallen erhalten. Diese Salze bilden auch Hydrate und THF-Solvate.Aus den Natrium-Trialkoxythiosilanolaten wurden die reinen Thiole (i-PrO)3SiSH und (s-BuO)3SiSH erhalten.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19744030213
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