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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 30 (1994), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : In the past, much effort has been put into the development of sophisticated mathematical models to describe settlement and consolidation of water deposited sediments. Such models often aim at completeness and accuracy in modeling the physical processes involved. However, as a result of the generality of the descriptions, the models often fail to compute local circumstances satisfactorily. In specific cases, the empirical approach may prove to be highly competitive and reliable. In large water bodies in the central part of the The Netherlands, the alluvial “IJsselmeer-deposit” is a common type of fresh water sediment. Its deposition and settlement started in 1932, when anthropogenic activities changed the physical and chemical conditions of the lakes drastically. Five representative cores of this sediment were taken in deep zones of the lakes. Periodic water depth surveys over the last sixty years at these locations provided information on the net sedimentation rate and the total thickness of this Ijsselmeer-deposit at known time intervals. In order to calculate a time-equivalent of the depth scale, correction factors for soil consolidation are introduced. A decrease in the total thickness of individual sediment layers is proportional to the decrease of its volume, which is derived from in situ characteristics. Correction factors are based on a simplification of various stages of compression (i.e., O percent, 30 percent, and 45 percent). A factor n, which represents changes of water content of the sediment as a dependence of clay content, is derived for each layer, allowing an inverse calculation procedure to determine the initial, uncompressed thickness of each layer. Hence, a fairly reliable time scale in depth can be reconstructed. Furthermore, the radionuclide activity was measured in some cores and the degree of organic and inorganic pollution was determined in numerous layers of all cores. Cs-isotopic tracers (137Cs, 134Cs) give a good reconstruction of the last six decades of physical changes of the sediment and the degree of pollution, assuming post depositional redistribution and transformation of pollutants to be negligible. The results showed close coherence to calculated time-scales.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract  The synthesis of L-isoleucine by Corynebacterium glutamicum involves 11 reaction steps, with at least 5 of them regulated in activity or expression. Using gene replacement we constructed a vector-free C. glutamicum strain having feedback-resistant aspartate kinase and feedback-resistant homoserine dehydrogenase activity. Isogenic strains carrying in addition one or several copies of feedback-resistant threonine dehydratase were made and their product accumulations compared. With strain SM1, with high threonine dehydratase activity, accumulation of 50 mM L-isoleucine was achieved, whereas with the parent strain only 4 mM L-isoleucine was obtained. Applying a closed-loop control fed-batch strategy to strain SM1 a final titre of 138 mM L-isoleucine was achieved with an integral molar yield of 0.11 mol/mol, and a maximal specific productivity of 0.28 mmol (g h)-1. This shows that high L-isoleucine yields can be obtained in the presence of one copy of feedback-resistant homoserine dehydrogenase by applying the appropriate fermentation strategy. In addition, the specific profiles of 2-oxoglutarate and pyruvate accumulation during fermentation revealed a major transition of the metabolism of C. glutamicum during the fermentation process.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 114 (1939), S. 455-458 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Zusammenfassung Einleitung. — Herstellung der Proben und Erzeugung der Ga-K-Strahlung. — Auswertung der Photometerkurven an Pulver- und Texturaufnahmen. — Vergleich und Diskussion der Überstrukturlinien.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-2932
    Keywords: heavy metals ; redox ; sulfides ; wetland soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The objective of this study was to measure the mobility of heavy metals in freshwater estuary soils that are seasonally inundated and to characterize the distribution of sulfide precipitates in these soils. Precipitation and dissolution of labile sulfides may account for changing pore water concentrations of heavy metals in freshwater wetland soils that are subject to temporary flooding or fluctuating groundwater levels. The presence of authigenic zinc- and iron-(mono)sulfide in this type of soils during periods with a high groundwater level was demonstrated by electron microprobe analyses. Because sulfide precipitates are strongly associated with root remnants, fresh soil organic material may be an important intermediary in the sulfur cycling and, consequently, in the behavior of heavy metals in these freshwater soils. Oxidation of labile sulfides may be partly responsible for the increased zinc and sulfate concentrations in the pore water during periods with low groundwater levels. Heavy metals may also be mobilized by degradation of their host phase organic matter during periods with high biodegradation.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    OR spectrum 5 (1983), S. 175-192 
    ISSN: 1436-6304
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Description / Table of Contents: Summary This paper is concerned with multiobjective linear programming and presents an algorithm for displaying computer graphics. The method is based on the classical oneparametric linear programming. It determines a spectrum of efficient criteria values, which can be visualized by means of piecewise linear functions. By some examples it is shown how to use the new algorithm for extending standard LP-packages to a flexible graphical multicriteria analysis.
    Notes: Zusammenfassung In diesem Artikel wird ein Algorithmus zur Erstellung von Computergraphiken für den Fall der linearen Optimierung bei mehrfacher Zielsetzung vorgestellt. Das Verfahren beruht auf der klassischen einparametrischen linearen Optimierung und bestimmt ein Spektrum effizienter Kriterienwerte, die mit Hilfe stückweise linearer Funktionen dargestellt werden können. Beispielhaft wird gezeigt, wie sich jedes Standard-LP-Paket mit dem vorgestellten Verfahren in einfacher Weise für eine flexible graphische Multikriteria-Analyse erweitern läßt.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 320 (1985), S. 674-675 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 191-198 
    ISSN: 0009-2940
    Keywords: Iron complexes ; Carbonylation ; Carene ; Cycloheptanes ; Bicyclo[4.1.1]octanes ; Bicyclo[3.2.1]octanes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Stereospecific Conversions of (+)-2- and (+)-3-Carene into Optically Active Seven-Membered Ring SystemsThe reactions of (+)-2-carene (6b) and (+)-3-carene (15) with iron carbonyls are studied under various conditions. Besides double bond isomerization and interconversion of the two isomeric hydrocarbons, at least two different modes of ring opening leading to six- and seven-membered ring products are observed. Under mild conditions the primary ring opening complex 7b is isolated without loss of sterical information. Carbonylation of 7b under various conditions yields optically active cycloheptane systems 18, 19, and 20 or the bicyclic systems 9b and 10b.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0009-2940
    Keywords: Acorane skeleton ; Carbonylation of 1,4-dienes ; Catalysis, rhodium ; Methylenecyclopropane rearrangement ; Rearrangement, metal-induced ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Hydrocarbonylating Cyclization of Dienes, 6. - Metal-Induced Skeletal Rearrangements during an Attempted Synthesis of the Acorane System from Substituted 1,1-DivinylcyclohexanesIn attempts of a regio- and stereoselective synthesis of the acorane skeleton 2, substituted 1,1-divinylcyclohexanes 1 were treated under the conditions of hydrocarbonylating cyclization. Substrates with higher degree of substitution surprisingly did not lead to the expected spiro products but to isomeric dienes 12 formed by skeleton rearrangements and hydrocarbonylation products thereof. Based on mechanistic considerations of this skeleton rearrangement, metallated methylcyclopropanes are considered as intermediates. These are also formed starting from methylenecyclopropanes which under hydrocarbonylating conditions also yield cyclopentanones.
    Notes: Bei Versuchen zur regio- und stereoselektiven Synthese des Acorangerüsts 2 wurden substituierte Divinylcyclohexane 1 den Bedingungen der hydrocarbonylierenden Cyclisierung unterworfen. Dabei wurden bei höheren Substitutionsgraden überraschenderweise nicht die erwarteten Spiroprodukte und das Acorangerüst, sondern unter metallinduzierter Gerüstumlagerung die isomeren Diene 12 und deren Hydrocarbonylierungsprodukte erhalten. Mechanistische Überlegungen zu dieser Umlagerung lassen auf metallierte Methylcyclopropane als Zwischenprodukte schließen. Diese werden auch beim Einsatz von Methylencyclopropanen gebildet und führen unter Hydrocarbonylierungsbedingungen ebenfalls zu Cyclopentanonen.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 9
    Publication Date: 2024-04-17
    Keywords: Chironomidae; DEPTH, sediment/rock; Holocene; Lake sediment; Late-Glacial; Loss on ignition; Netherlands; PCUWI; Piston corer, UWITEC; pollen; Sample ID; Sedimentology; UDD-E; Uddelermeer, Netherlands
    Type: Dataset
    Format: text/tab-separated-values, 2824 data points
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  • 10
    Publication Date: 2024-04-17
    Keywords: Achnanthes amoena; AGE; Alnus; Alona; Amphisphaerella dispersella; Amphitremum flavum; Aphanizomenon; Apiaceae; Artemisia; Asteraceae; Betula; Botryococcus; Brassicaceae; Byssothecium circinans; Campanula; Carpinus; Caryophyllaceae; Castanea; Centaurea jacea-type; Centaurea scabiosa-type; Cerealia; cf. Cylindrocystis brebissonii; cf. Gentianaceae; cf. Persiciospora; Chaetomium; Chenopodiaceae; Chironomidae; Clasterosporium cavicinum; Convolvulus arvensis; Corylus; Counting; Cyperaceae; Debarya; DEPTH, sediment/rock; Diporotheca; Empetrum; Ephedra distachya-type; Ephedra fragilis-type; Epicoccum purpurascens; Epilobium; Equisetum; Ericales; Fabaceae; Fagopyrum; Fagus; Fern spores, monolete psilate; Fern spores, monolete verrucate; Filinia; Filipendula; Fraxinus; Galium; Gelasinospora cf. retispora; Gelasinospora sp.; Geoglossum sphagnophilum; Hedera helix; Helianthemum; Holocene; Humulus/Cannabis; Hydrocotyle; Hypericum; Isoetes; Juglans; Juniperus; Kretzschmaria deusta; Lake sediment; Late-Glacial; Littorella; Lonicera; Lotus; Lycopodium (added); Lysimachia; Lythrum; Melampyrum; Meliola cf. niessleana; Mentha; Menyanthes; Mougeotia; Myrica; Myriophyllum alterniflorum; Myriophyllum spicatum/verticillatum-type; Netherlands; Neurospora; Nuphar; Nymphaea; Osmunda regalis; PCUWI; Pediastrum; Persicaria amphibia; Persicaria maculosa-type; Picea; Pinus; Piston corer, UWITEC; Plantago lanceolata-type; Plantago major/media-type; Poaceae; Podospora; pollen; Polygonum aviculare-type; Populus; Potamogeton; Potentilla-type; Prunella-type; Pteridium; Quercus; Ranunculaceae; Rhamnus frangula; Rhynchospora alba; Rosaceae undifferentiated; Rumex acetosella-type; Salix; Sanguisorba officinalis; Scenedesmus; Secale; Sedimentology; Selaginella selaginoides; Solanum dulcamara; Sordaria; Spergula arvensis; Sphagnum; Spirogyra; Sporormiella; Succisa; Tetraedron minimum; Thalictrum; Tilia; Tilletia sphagni; Typha angustifolia/Sparganium; Typha latifolia; UDD-E; Uddelermeer, Netherlands; Ulmus; Urtica; Valeriana; Viscum; Zea mays; Zygnema-type
    Type: Dataset
    Format: text/tab-separated-values, 14410 data points
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