ALBERT

Description: Accessory mineral geochronometers such as apatite, baddeleyite, monazite, xenotime and zircon are increasingly being recognized for their ability to preserve diagnostic microstructural evidence of hypervelocity-impact processes. To date, little is known about the response of titanite to shock metamorphism, even though it is a widespread accessory phase and a U–Pb geochronometer. Here we report two new mechanical twin modes in titanite within shocked granitoid from the Chicxulub impact structure, Mexico. Titanite grains in the newly acquired core from the International Ocean Discovery Program Hole M0077A preserve multiple sets of polysynthetic twins, most commonly with composition planes (K1) = ~ {1¯11} { 1 ¯ 11 } , and shear direction (η1) = 〈 110 〉 , and less commonly with the mode K1 = {130}, η1 = ~ 〈522 〉 . In some grains, {130} deformation bands have formed concurrently with the deformation twins, indicating dislocation slip with Burgers vector b = 〈 341 〉 can be active during impact metamorphism. Titanite twins in the modes described here have not been reported from endogenically deformed rocks; we, therefore, propose this newly identified twin form as a result of shock deformation. Formation conditions of the twins have not been experimentally calibrated, and are here empirically constrained by the presence of planar deformation features in quartz (12 ± 5 and ~ 17 ± 5 GPa) and the absence of shock twins in zircon (〈 20 GPa). While the lower threshold of titanite twin formation remains poorly constrained, identification of these twins highlight the utility of titanite as a shock indicator over the pressure range between 12 and 17 GPa. Given the challenges to find diagnostic indicators of shock metamorphism to identify both ancient and recent impact evidence on Earth, microstructural analysis of titanite is here demonstrated to provide a new tool for recognizing impact deformation in rocks where other impact evidence may be erased, altered, or did not manifest due to generally low (〈 20 GPa) shock pressure.

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fan, S., Hager, T. F., Prior, D. J., Cross, A. J., Goldsby, D. L., Qi, C., Negrini, M., & Wheeler, J. Temperature and strain controls on ice deformation mechanisms: Insights from the microstructures of samples deformed to progressively higher strains at-10,-20 and-30 degrees C. Cryosphere, 14(11), (2020): 3875-3905, doi:10.5194/tc-14-3875-2020.

Description: In order to better understand ice deformation mechanisms, we document the microstructural evolution of ice with increasing strain. We include data from experiments at relatively low temperatures (−20 and −30 ∘C), where the microstructural evolution with axial strain has never before been documented. Polycrystalline pure water ice was deformed under a constant displacement rate (strain rate ∼1.0×10−5 s−1) to progressively higher strains (∼ 3 %, 5 %, 8 %, 12 % and 20 %) at temperatures of −10, −20 and −30 ∘C. Microstructural data were generated from cryogenic electron backscattered diffraction (cryo-EBSD) analyses. All deformed samples contain subgrain (low-angle misorientations) structures with misorientation axes that lie dominantly in the basal plane, suggesting the activity of dislocation creep (glide primarily on the basal plane), recovery and subgrain rotation. Grain boundaries are lobate in all experiments, suggesting the operation of strain-induced grain boundary migration (GBM). Deformed ice samples are characterized by interlocking big and small grains and are, on average, finer grained than undeformed samples. Misorientation analyses between nearby grains in 2-D EBSD maps are consistent with some 2-D grains being different limbs of the same irregular grain in the 3-D volume. The proportion of repeated (i.e. interconnected) grains is greater in the higher-temperature experiments suggesting that grains have more irregular shapes, probably because GBM is more widespread at higher temperatures. The number of grains per unit area (accounting for multiple occurrences of the same 3-D grain) is higher in deformed samples than undeformed samples, and it increases with strain, suggesting that nucleation is involved in recrystallization. “Core-and-mantle” structures (rings of small grains surrounding big grains) occur in −20 and −30 ∘C experiments, suggesting that subgrain rotation recrystallization is active. At temperatures warmer than −20 ∘C, c axes develop a crystallographic preferred orientation (CPO) characterized by a cone (i.e. small circle) around the compression axis. We suggest the c-axis cone forms via the selective growth of grains in easy slip orientations (i.e. ∼ 45∘ to shortening direction) by GBM. The opening angle of the c-axis cone decreases with strain, suggesting strain-induced GBM is balanced by grain rotation. Furthermore, the opening angle of the c-axis cone decreases with temperature. At −30 ∘C, the c-axis CPO changes from a narrow cone to a cluster, parallel to compression, with increasing strain. This closure of the c-axis cone is interpreted as the result of a more active grain rotation together with a less effective GBM. We suggest that lattice rotation, facilitated by intracrystalline dislocation glide on the basal plane, is the dominant mechanism controlling grain rotation. Low-angle neighbour-pair misorientations, relating to subgrain boundaries, are more extensive and extend to higher misorientation angles at lower temperatures and higher strains supporting a relative increase in the importance of dislocation activity. As the temperature decreases, the overall CPO intensity decreases, primarily because the CPO of small grains is weaker. High-angle grain boundaries between small grains have misorientation axes that have distributed crystallographic orientations. This implies that, in contrast to subgrain boundaries, grain boundary misorientation is not controlled by crystallography. Nucleation during recrystallization cannot be explained by subgrain rotation recrystallization alone. Grain boundary sliding of finer grains or a different nucleation mechanism that generates grains with random orientations could explain the weaker CPO of the fine-grained fraction and the lack of crystallographic control on high-angle grain boundaries.

Description: This research has been supported by the NASA Fund (grant no. NNX15AM69G) and the Marsden Fund of the Royal Society of New Zealand (grant nos. UOO1116, UOO052).

Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 127(8), (2022): e2022JB024497, https://doi.org/10.1029/2022JB024497.

Description: During plastic deformation, strain weakening can be achieved, in part, via strain energy reduction associated with intragranular boundary development and grain boundary formation. Grain boundaries (in 2D) are segments between triple junctions, that connect to encircle grains; every boundary segment in the encircling loop has a high (〉10°) misorientation angle. Intragranular boundaries terminate within grains or dissect grains, usually containing boundary segments with a low (〈10°) misorientation angle. We analyze electron backscatter diffraction (EBSD) data from ice deformed at −30°C (Th≈ 0.9). Misorientation and weighted Burgers vector (WBV) statistics are calculated along planar intragranular boundaries. Misorientation angles change markedly along each intragranular boundary, linking low- (〈10°) and high-angle (10–38°) segments that exhibit distinct misorientation axes and WBV directions. We suggest that these boundaries might be produced by the growth and intersection of individual intragranular boundary segments comprising dislocations with distinct slip systems. There is a fundamental difference between misorientation axis distributions of intragranular boundaries (misorientation axes mostly confined to ice basal plane) and grain boundaries (no preferred misorientation axis). These observations suggest during progressive subgrain rotation, intragranular boundaries remain crystallographically controlled up to large misorientation angles (〉〉10°). In contrast, the apparent lack of crystallographic control for grain boundaries suggests misorientation axes become randomized, likely due to the activation of additional mechanisms (such as grain boundary sliding) after grain boundary formation, linking boundary segments to encircle a grain. Our findings on ice intragranular boundary development and grain boundary formation may apply more broadly to other rock-forming minerals (e.g., olivine, quartz).

Description: This work was supported by a NASA fund (Grant No. NNX15AM69G) to David L. Goldsby and two Marsden Funds of the Royal Society of New Zealand (Grant Nos. UOO1116, UOO052) to David J. Prior. Sheng Fan was supported by the University of Otago doctoral scholarship, the Antarctica New Zealand doctoral scholarship, a research grant from New Zealand Ministry of Business, Innovation and Employment through the Antarctic Science Platform (ANTA1801) (Grant No. ASP-023-03), and a New Zealand Antarctic Research Institute (NZARI) Early Career Researcher Seed Grant (Grant No. NZARI 2020-1-5). Open access publishing facilitated by University of Otago, as part of the Wiley – University of Otago agreement via the Council of Australian University Librarians.