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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 46 (1990), S. 60-62 
    ISSN: 1420-9071
    Keywords: Fetuin ; galactose ; galactose oxidase ; in vitro ; N-acetylgalactosamine ; ovine submaxillary mucin ; radiolabeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The primary alcohol group on the carbon 6 of terminal galactosyl and N-acetylgalactosaminyl moieties of glycoproteins can be oxidized to an aldehyde by treatment with galactose oxidase. By reacting these aldehyde groups with14C-labeled sodium cyanide,14C-labeled cyanohydrin derivatives were obtained. Similarly, reduction of these aldehyde groups with tritiated sodium borohydride following standard procedures, yields3H-labeled glycoproteins.14C- and3H-labeled derivatives of asialofetuin and asialo ovine submaxillary mucin with high specific radioactivities were prepared using these procedures. Mixtures containing microgram amounts of14C- and3H-labeled glycoproteins were subjected to column chromatography and gradient ultracentrifugation and the position of the individual glycoproteins was determined by simultaneous counting for14C and3H. These experiments demonstrate the usefulness of this approach for comparative analytical studies using biological specimens available in minute quantities.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 32 (1997), S. 505-519 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Sanbaqi uranium deposit in Hunan Province, south China, is the largest of a group of paleokarst-hosted uranium deposits in Lower Carboniferous limestone. Mineralization is localized in cavities and fault-breccias formed by dissolution of carbonates. Four episodes of karst formation are recognized: late Triassic-early Jurassic, late Jurassic-early Cretaceous, Cretaceous-Tertiary and Recent. Field relations indicate that the main uranium mineralization is related to the second karst episode. This is supported by isotopic ages of two pitchblende samples at 129 Ma and 134 Ma, as indicated by their nearly concordant data points on concordia plot. These ages are in the time range of the early Yanshanian tectonic movements that affected southern China, and the faulting related to the movements likely triggered the mineralization process at the Sanbaqi deposit. Associated minerals include pyrite, millerite, ullmannite, niccolite, molybdenite, chalcopyrite, sphalerite, galena, calcite and dolomite. Fluid inclusion studies on calcite reveal that temperature of ore deposition was from 181° to 150 °C. The δ18O and δD values of the ore fluids range from 1.5 to 7.9 per mil and from −30.4 and −54.8 per mil, respectively. The mineralogical, fluid inclusion and isotopic data indicate that the minerlization took place in episodic pulses of hydrothermal fluids that were introduced along a set of ring faults. Mobilization and redeposition of earlier formed ore minerals in an open system added to the complexity of the paragenetic sequence. Younger episodes of mineralization occurred during the later karst events as suggested by the geological and additional pitchblende U-Pb isotopic data, during the Cretaceous-Tertiary late Yanshanian tectonic movements and recently. Finally, a comparison of the Sanbaqi uranium deposit with the uranium deposits hosted by solution collapse breccia pipes of the Colorado Plateau, USA, shows that they have many similarities.
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Analytical Biochemistry 137 (1984), S. 429-436 
    ISSN: 0003-2697
    Keywords: carbohydrates ; glycoconjugates ; glycoproteins ; mucins ; radiolabeling ; sialic acid
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    BBA - Protein Structure 536 (1978), S. 184-196 
    ISSN: 0005-2795
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0005-2760
    Keywords: (Human plasma) ; Apolipoprotein B ; Immunoaffinity chromatography ; Lipoprotein ; Monoclonal antibody
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 2486-2494 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Diagrammatic valence bond (DVB) theory is a general approach to electron correlations in quantum cell models that conserve total spin. VB diagrams are a convenient many-electron basis for combining spin, point-group, and other symmetries in oligomers with a large but finite basis. Half-filled Hubbard or Pariser–Parr–Pople (PPP) models with 16 sites have ∼34.7×106 singlet diagrams. Improved DVB methods yield exact low-lying states of the 16-site polyene in C2h symmetry and of pyrene in D2h symmetry. Several generalizations of symmetry adaptation are necessary for large bases, including new rules for linearly independent basis vectors and an iterative method for Hamiltonian matrix elements that avoids overlap and inversion. The number and dimensions of the disjoint invariant subspaces Sm encountered in symmetry adaptation depend on the connectivity. D2h symmetry adaptation is much simpler for acenes than for pyrene, linear stilbene, or polyphenyls. Standard PPP parameters account well for the 11 pyrene states identified in linear and two-photon spectra. Polyenes to N=16 show systematic deviations, with the 2 1Ag threshold decreasing less rapidly with N than experiment. We discuss perturbations that break electron-hole, parity, or point-group symmetry on the low-energy states, test the second π-electron approximation for pyrene, and comment on the feasibility of DVB for N=18 or 20 sites. © 1998 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 3072-3074 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A large magnetic entropy change has been observed in an intermetallic compound LaFe10.6Si2.4. The maximum −ΔSM(approximate)3.2 J/kg K was found at its Curie temperature, ∼242 K, upon a 2 T magnetic field change. Although the entropy change is slightly smaller than that of pure Gd metal, such Fe-rich compounds still appear to be very attractive candidates since (a) the raw materials are much cheaper than pure Gd metal; (b) the Curie temperature can be easily shifted by tuning the composition; (c) the materials are much more chemically stable than pure Gd metal. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 831-833 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Cubic structured CdS, CdSe, and CdTe, II–VI semiconductor nanoparticles have been synthesized using aqueous solution precipitation at room temperature. The "as-prepared'' particles have a size of about 30 A(ring). Thermal annealing causes (a) an increase in particle size; (b) a structural transition from the cubic to the bulk, hexagonal structure for CdS and CdSe; and (c) no structural transition for CdTe. The unexpected cubic phase for small particles of CdS and CdSe may be due to either metastability or an equilibrium surface effect. The latter would imply a strong correlation between structure and the size and surface properties, and that there is a minimum size for hexagonal phase stability. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Comparative Biochemistry and Physiology -- Part A: Physiology 74 (1983), S. 869-872 
    ISSN: 0300-9629
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Comparative Biochemistry and Physiology -- Part A: Physiology 106 (1993), S. 81-86 
    ISSN: 0300-9629
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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