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  • 1
    ISSN: 1436-5073
    Keywords: ICP-MS ; MO+ ions ; M2+ ions ; spectral interferences
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract In addition to peaks from singly charged ions (M+), signals from oxide (MO+), hydroxide (MOH+) and doubly charged (M2+) ions, which may lead to spectral overlap interferences, are observed in ICP-MS spectra. Using a VG PlasmaQuad ratios of MO+/M+, MOH+/M+ and M2+/M+ were determined for a number of elements, covering a wide range of atomic masses, first and second ionisation energies and chemical properties. The temporal stability of the MO+/M+ and M2+/M+ ratios was investigated. The correlation between the ratios of MO+/M+ and M2+/M+ with the M-O bond strength and the difference between the second and the first ionisation energy respectively is discussed. The influence of several instrumental parameters, associated with sample introduction and plasma operation, on the M+, M2+ and MO+ signals and on the MO+/M+ and M2+/M+ ratios is studied. Simple qualitative explanations are given in order to explain some of the observed results. No quantitative results are given for the MO+/M+ and M2+/M+ ratios as the experiments pointed out that they are influenced to a large extent by several instrumental parameters.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The potential of a new commercially available microbore anion exchange column for chromium speciation (Cetac ANX-3202) was evaluated and its characteristics were studied. Nitric acid was used as mobile phase, making the technique ideal for coupling with inductively coupled plasma mass spectrometry (ICPMS). Because of the low operating flow rate of the column, a microconcentric nebulizer was used as an interface between the microbore column and the ICP-mass spectrometer. Co was added to the mobile phase and its signal intensity was continuously monitored and used as an internal standard to correct for signal drift and instrumental instability. Excellent results were obtained in terms of repeatability. Detection limits for Cr(III) and Cr(VI) are less than 1 μg · L–1, using either 52Cr or 53Cr. The accuracy was determined by analyzing a certified reference material (BCR CRM 544). The concentrations found were in good agreement with those certified. The occurrence of C- and Cl-based molecular ions was studied and their influence on the determination of chromium was evaluated.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1436-5073
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2023-06-27
    Keywords: 307-U1317E; Carbonates; Counting 〉150 µm fraction; DEPTH, sediment/rock; Dolomite; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Exp307; Grains; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Number; Porcupine Basin Carbonate Mounds; Quartz and Feldspar; Rock fragments; Sample code/label; Volcanic fragments
    Type: Dataset
    Format: text/tab-separated-values, 120 data points
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  • 5
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    PANGAEA
    In:  Supplement to: Thierens, Mieke; Pirlet, Hans; Colin, C; Latruwe, Kris; Vanhaecke, Frank; Lee, J R; Stuut, Jan-Berend W; Titschack, Jürgen; Huvenne, Veerle A I; Dorschel, Boris; Wheeler, Andrew J; Henriet, Jean-Pierre (2012): Ice-rafting from the British–Irish ice sheet since the earliest Pleistocene (2.6 million years ago): implications for long-term mid-latitudinal ice-sheet growth in the North Atlantic region. Quaternary Science Reviews, 44, 229-240, https://doi.org/10.1016/j.quascirev.2010.12.020
    Publication Date: 2023-06-27
    Description: The Plio-Pleistocene intensification of Northern Hemisphere continental ice-sheet development is known to have profoundly affected the global climate system. Evidence for early continental glaciation is preserved in sediments throughout the North Atlantic Ocean, where ice-rafted detritus (IRD) layers attest to the calving of sediment-loaded icebergs from circum-Atlantic ice sheets. So far, Early-Pleistocene IRD deposition has been attributed to the presence of high-latitudinal ice sheets, whereas the existence and extent of ice accumulation in more temperate, mid-latitudinal regions remains enigmatic. Here we present results from the multiproxy provenance analysis of a unique, Pleistocene-Holocene IRD sequence from the Irish NE Atlantic continental margin. There, the Challenger coral carbonate mound (IODP Expedition 307 site U1317) preserved an Early-Pleistocene record of 16 distinctive IRD events, deposited between ca 2.6 and 1.7 Ma. Strong and complex IRD signals are also identified during the mid-Pleistocene climate transition (ca 1.2 to 0.65 Ma) and throughout the Middle-Late Pleistocene interval. Radiogenic isotope source-fingerprinting, in combination with coarse lithic component analysis, indicates a dominant sediment source in the nearby British-Irish Isles, even for the oldest, Early-Pleistocene IRD deposits. Hence, our findings demonstrate, for the first time, repeated and substantial (i.e. marine-terminating) ice accumulation on the British-Irish Isles since the beginning of the Pleistocene. Contemporaneous expansion of both high- and mid-latitudinal ice sheets in the North Atlantic region is therefore implied at the onset of the Pleistocene. Moreover, it suggests the recurrent establishment of (climatically) favourable conditions for ice sheet inception, growth and instability in mid-latitudinal regions, even in the earliest stages of Northern Hemisphere glacial expansion and in an obliquity-driven climate system.
    Keywords: 307-U1317E; DRILL; Drilling/drill rig; Exp307; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Porcupine Basin Carbonate Mounds
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 6
    Publication Date: 2023-06-27
    Keywords: 307-U1317E; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Exp307; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS); Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, error; Number; Porcupine Basin Carbonate Mounds; Sample code/label; Sediment type; Size fraction 〈 0.002 mm, clay; Strontium-87/Strontium-86 ratio; Strontium-87/Strontium-86 ratio, error; ε-Neodymium (0)
    Type: Dataset
    Format: text/tab-separated-values, 144 data points
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  • 7
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    Unknown
    PANGAEA
    In:  Supplement to: Pirlet, Hans; Colin, Christophe; Thierens, Mieke; Latruwe, Kris; Van Rooij, David; Foubert, Anneleen; Frank, Norbert; Blamart, Dominique; Huvenne, Veerle A I; Swennen, Rudy; Vanhaecke, Frank; Henriet, Jean-Pierre (2011): The importance of the terrigenous fraction within a cold-water coral mound: A case study. Marine Geology, 282(1-2), 13-25, https://doi.org/10.1016/j.margeo.2010.05.008
    Publication Date: 2023-07-05
    Description: In the nineties, cold-water coral mounds were discovered in the Porcupine Seabight (NE Atlantic, west of Ireland). A decade later, this discovery led to the drilling of the entire Challenger cold-water coral mound (Eastern slope, Porcupine Seabight) during IODP Expedition 307. As more than 50% of the sediment within Challenger Mound consists of terrigenous material, the terrigenous component is equally important for the build-up of the mound as the framework-building corals. Moreover, the terrigenous fraction contains important information on the dynamics and the conditions of the depositional environment during mound development. In this study, the first in-depth investigation of the terrigenous sediment fraction of a cold-water coral mound is performed, combining clay mineralogy, sedimentology, petrography and Sr-Nd-isotopic analysis on a gravity core (MD01-2451G) collected at the top of Challenger Mound. Sr- and Nd-isotopic fingerprinting identifies Ireland as the main contributor of terrigenous material in Challenger Mound. Besides this, a variable input of volcanic material from the northern volcanic provinces (Iceland and/or the NW British Isles) is recognized in most of the samples. This volcanic material was most likely transported to Challenger Mound during cold climatic stages. In three samples, the isotopic ratios indicate a minor contribution of sediment deriving from the old cratons on Greenland, Scandinavia or Canada. The grain-size distributions of glacial sediments demonstrate that ice-rafted debris was deposited with little or no sorting, indicating a slow bottom-current regime. In contrast, interglacial intervals contain strongly current-sorted sediments, including reworked glacio-marine grains. The micro textures of the quartz-sand grains confirm the presence of grains transported by icebergs in interglacial intervals. These observations highlight the role of ice-rafting as an important transport mechanism of terrigenous material towards the mound during the Late Quaternary. Furthermore, elevated smectite content in the siliciclastic, glaciomarine sediment intervals is linked to the deglaciation history of the British-Irish Ice Sheet (BIIS). The increase of smectite is attributed to the initial stage of chemical weathering processes, which became activated following glacial retreat and the onset of warmer climatic conditions. During these deglaciations a significant change in the signature of the detrital fraction and a lack of coral growth is observed. Therefore, we postulate that the deglaciation of the BIIS has an important effect on mound growth. It can seriously alter the hydrography, nutrient supply and sedimentation processes, thereby affecting both sediment input and coral growth and hence, coral mound development.
    Keywords: DEPTH, sediment/rock; GEOSCIENCES, MARMARCORE; HERMES; HERMIONE; Hotspot Ecosystem Research and Mans Impact On European Seas; Hotspot Ecosystem Research on the Margins of European Seas; ICP-MS, Thermo Scientific Neptune; Marion Dufresne (1995); MD01-2451; MD123; Neodymium-143/Neodymium-144 ratio; Position; Strontium-87/Strontium-86 ratio; TC; Trigger corer; ε-Neodymium (0)
    Type: Dataset
    Format: text/tab-separated-values, 68 data points
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  • 8
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    Unknown
    PANGAEA
    In:  Supplement to: Vallelonga, Paul T; Gabrielli, Paolo; Balliana, E; Wegner, Anna; Delmonte, Barbara; Turetta, Clara; Burton, G; Vanhaecke, Frank; Rosman, K J R; Hong, Sungmin; Boutron, Claude F; Cescon, Paolo; Barbante, Carlo (2010): Lead isotopic compositions in the EPICA Dome C ice core and southern hemisphere potential source areas. Quaternary Science Reviews, 29(1-2), 247-255, https://doi.org/10.1016/j.quascirev.2009.06.019
    Publication Date: 2024-03-16
    Description: A record of Pb isotopic compositions and Pb and Ba concentrations are presented for the EPICA Dome C ice core covering the past 220 ky, indicating the characteristics of dust and volcanic Pb deposition in central East Antarctica. Lead isotopic compositions are also reported in a suite of soil and loess samples from the Southern Hemisphere (Australia, Southern Africa, Southern South America, New Zealand, Antarctica) in order to evaluate the provenance of dust present in Antarctic ice. Lead isotopic compositions in Dome C ice support the contention that Southern South America was an important source of dust in Antarctica during the last two glacial maxima, and furthermore suggest occasional dust contributions from local Antarctic sources. The isotopic signature of Pb in Antarctic ice is altered by the presence of volcanic Pb, inhibiting the evaluation of glacial–interglacial changes in dust sources and the evaluation of Australia as a source of dust to Antarctica. Consequently, an accurate evaluation of the predominant source(s) of Antarctic dust can only be obtained from glacial maxima, when dust-Pb concentrations were greatest. These data confirm that volcanic Pb is present throughout Antarctica and is emitted in a physical phase that is free from Ba, while dust Pb is transported within a matrix containing Ba and other crustal elements.
    Keywords: AGE; Barium; DEPTH, ice/snow; Dome C; Dome C, Antarctica; EDC; EPICA; EPICA Dome C; European Project for Ice Coring in Antarctica; ICEDRILL; Ice drill; Lead; Lead/Barium ratio; Lead-206/Lead-204 ratio; Lead-206/Lead-204 ratio, error; Lead-206/Lead-207 ratio; Lead-208/Lead-207, error; Lead-208/Lead-207 ratio
    Type: Dataset
    Format: text/tab-separated-values, 666 data points
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  • 9
  • 10
    Publication Date: 2009-09-25
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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