ISSN:
1434-193X
Keywords:
14,20-Bis-epi Inhoffen-Lythgoe diol
;
Hajos-Wiechert ketone, enantiomeric purity
;
Acyclic diastereoselective alkylation
;
Alkylations
;
Hydroborations
;
Epimerisation
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
14,20-Bis-epi-1α,25-dihydroxy-19-norvitamin D3 and side chain analogues thereof have been synthesised via the 14,20-bis-epi-Inhoffen-Lythgoe diol 9. The synthesis of this precursor was performed via degradation of vitamin D2 and by total synthesis starting from Hajos-Wiechert ketone 24.
Type of Medium:
Electronic Resource
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