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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 455 (1979), S. 93-98 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Oxidation of Triphenylarsine in Iron(III) Chloride ComplexesComplexes of the composition of FeCl3(OAsPh3)1,5 and FeCl3(OAsPh3)2 were separated at increased temperature from the system FeCl3-AsPh3-acetonitrile. In the course of the reaction in the presence of iron(III) chloride complexes oxidation of AsPh3 takes place to give OAsPh3. On the basis of magnetic and spectral data the sterochemistry of the separated complexes is discussed.
    Notes: Aus dem System FeCl3-AsPh3-Acetonitril wurden bei erhöhter Temperatur Komplexe der Zusammensetzung FeCl3(OAsPh3)1,5 und FeCl3(OAsPh3)2 isoliert. (PPh3 = Triphenylphosphin; OPPh3 = Triphenylphosphinoxid; AsPh3 = Triphenylarsin; OAsPh3 = Triphenylarsinoxid). In Gegenwart von Eisen(III)-chlorid-Komplexen kommt es im Verlauf der Reaktion zur Oxydation von AsPh3 zu OAsPh3. Auf Grund der magnetischen und spektralen Daten wird die Stereochemie der isolierten Komplexe besprochen.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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