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  • 1
    Electronic Resource
    Electronic Resource
    Transformation of Nε-Z-l-Lysine to Z-l-Oxylysine Using L-Amino Acid Oxidase from Providencia alcalifaciens and l-2-Hydroxyisocaproate Dehydrogenase from Lactobacillus confusus (1992)
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 672 (1992), S. 0 
    Details
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1749-6632.1992.tb35681.x
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  • 2
    Electronic Resource
    Electronic Resource
    Stereoselective Enzymatic Esterification of 3-BenzoyIthio-2-methylpropanoic Acid (1992)
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 672 (1992), S. 0 
    Details
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1749-6632.1992.tb35651.x
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  • 3
    Electronic Resource
    Electronic Resource
    Stereoselective Microbial Reduction of 2-Keto-3-(N-Benzoylamino)-3-Phenyl Propionic Acid Ethyl Ester (1995)
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 750 (1995), S. 0 
    Details
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1749-6632.1995.tb19946.x
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  • 4
    Electronic Resource
    Electronic Resource
    A compact representation of magnetotelluric responses for two-layer models[ Received ] (1997)
    Oxford, UK : Blackwell Science Ltd
    Geophysical prospecting 45 (1997), S. 0 
    Details
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: In this paper the locations where ρapp = ρ1 and ϕ = π/4 and where these parameters reach an extreme value in two-layer magnetotelluric (MT) sounding curves are summarized in an extremely compact form. The key parameters over two-layer models with conductivities σ1, σ2 and upper layer thickness h are the real S and α, where S is the conductivity contrast and α is the distance between the observation site and the conductivity interface, normalized to the half skindepth in the first layer. If the impedance components, various resistivity definitions ( ρRe Z, ρIm Z and ρ|Z|, based on different parts of the complex impedance Z ) and the magnetotelluric phase ϕ are derived as a function of S and α, then the conditions for the apparent resistivity ρapp and the phase ϕ are that they either satisfy ρapp = ρ1 and ϕ = π/4 or attain extreme values which can be given in terms of simple algebraic equations between S and α. All equations are valid for observation sites at any depth 0 ≤ z ≤ h in the first layer. The set of equations, presented in a tabular form, may make it possible to determine a layer boundary from the short period part of the sounding curves, in particular the ρRe Z and the ϕMT curves.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1046/j.1365-2478.1997.470284.x
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  • 5
    Electronic Resource
    Electronic Resource
    A field test of imaging properties of rotational invariants of the magnetotelluric impedance tensor (2005)
    PO Box 1354, 9600 Garsington Road , Oxford OX4 2XG , UK . : Blackwell Science Ltd
    Geophysical prospecting 53 (2005), S. 0 
    Details
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A part of the Békés Basin (an extensional sub-basin of the Pannonian Basin, where the basement under thick Pannonian sediments is well known from deep boreholes and from seismic measurements, and where many magnetotelluric (MT) soundings have been carried out for frequencies ranging from 1 to 10−3 Hz) was selected as a test area to assess the imaging performances of various apparent-resistivity definitions computed with rotational invariants of either the real part of the complex impedance tensor, or its imaginary part, or both. A comparison (based on earlier 3D numerical studies) has been made between the magnetotelluric images obtained in this way and the depths to the high-resistivity basement, as known from boreholes and seismic investigations. The correlation coefficient between the series of basement depth values at 39 MT sites and the apparent-resistivity values was found to be stronger and high correlation appeared at a shorter period when it was computed with apparent resistivities based on the real tensor rather than with apparent resistivities based on the imaginary tensor. In the light of our studies, ρReZ and the impedance phase seem to be more informative than any other combination of magnetotelluric interpretation parameters.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2478.2005.00477.x
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  • 6
    Electronic Resource
    Electronic Resource
    An approximate analytical approach to compute geoelectric dipole–dipole responses due to a small buried cube (2000)
    Oxford, UK : Blackwell Science Ltd
    Geophysical prospecting 48 (2000), S. 0 
    Details
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A simple analytical solution is presented for computing direct current (DC) electric field distortion due to a small cube in a homogeneous half-space, measured with a dipole–dipole array on the surface. Both the transmitter and the receiver may have any orientation; furthermore their position on the horizontal surface and the depth of the cube can be freely selected. It is shown that a simple approximate analytical method may replace more complicated 3D numerical modelling algorithms.The approximation lies in the linearization of the problem: the secondary source (i.e. the cube) is considered as a system of three perpendicular electric dipoles. In spite of this first-order approximation, in the case of realistic depths z (zR≈0.1–0.5, where R is the transmitter–receiver distance), this approximate solution fits very well with true 3D numerical modelling results, and with analogue modelling results if aR≤0.1, where a is the length of the side of the cube. Due to its simplicity, this method could be used for computing DC field distortion effects, estimating parameter-sensitivities, or even determining some initial models for further inversions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1046/j.1365-2478.2000.00222.x
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  • 7
    Electronic Resource
    Electronic Resource
    Geophysical aspects of man-made electromagnetic noise in the earth—A review (1987)
    Springer
    Surveys in geophysics 9 (1987), S. 287-318 
    Details
    ISSN: 1573-0956
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The paper gives a summary of geophysical aspects of man-made electromagnetic noise in the Earth as follows: - EM distortion effects of man-made constructions below and over the Earth's surface defined as ‘passive-noise’, - field observation of EM disturbances due to ‘active’ man-made sources, - EM source mechanism of some important active sources from a geophysical point of view, - efforts in order to improve the signal-to noise ratio by instrumental, methodological and dataprocessing ways, - application of man-made EM noise for geophysical prospecting. The paper is based on world-wide EM noise survey studies published mainly in geophysical journals.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01901627
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  • 8
    Electronic Resource
    Electronic Resource
    Stereoselective enzymatic esterification of 3-benzoylthio-2-methylpropanoic acid (1991)
    Springer
    Applied microbiology and biotechnology 36 (1991), S. 29-34 
    Details
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Summary A key intermediate, S-(−)-3-benzoylthio-2-methylpropanoic acid (1) was made in high optical purity by the lipase-catalyzed stereoselective esterification of racemic 1 with methanol in an organic solvent system. Among various lipases evaluated, Amano P-30 lipase from Pseudomonas sp. efficiently catalyzed the esterification of 1 to yield R-(+) methyl ester and unreacted S-(−) 1. A reaction yield of 40 mol% and an optical purity of 97.2% were obtained for compound 1 at a substrate concentration of 0.1 m (22 mg/ml). Lipase P-30 was immobilized on Accurel polypropylene (PP) and the immobilized enzyme was reused (23 cycles) in the esterification reaction without loss of enzyme acitivity, productivity or optical purity. Among various solvents evaluated, toluene was found to be the most suitable organic solvent and methanol was the best alcohol for the esterification of racemic 1 by immobilized lipase. Substrate concentrations as high as 1.0 m were used in the esterification reaction. When the temperature was increased from 28° C to 60° C, the reaction time required for the esterification of 0.1 m substrate decreased from 16 h to 2 h. On increasing the methanol to substrate molar ratio from 1:1 to 4:1, the rate of esterification decreased. A lipase fermentation using Pseudomonas sp. ATCC 21 808 was developed. In the batch-fermentation process, 56 units/ml of extracellular lipase activity was obtained. A fed-batch process using soybean oil gave a significant increase in the lipase activity (126 units/ml). Crude lipase recovered from the filtrate by ethanol precipitation and immobilized on Accurel PP was also effective: S-(−) compound 1 was obtained in 35 mol% yield and 95% optical purity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00164694
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  • 9
    Electronic Resource
    Electronic Resource
    Transformation of Nε-CBZ-l-lysine to CBZ-l-oxylysine using l-amino acid oxidase from Providencia alcalifaciens and l-2-hydroxy-isocaproate dehydrogenase from Lactobacillus confusus (1992)
    Springer
    Applied microbiology and biotechnology 37 (1992), S. 599-603 
    Details
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Summary Biotransformations were developed to oxidize Nε-carbobenzoxy(CBZ)-l-lysine and to reduce the product keto acid to l-CBZ-oxylysine. Lysyl oxidase (l-lysine: O2 oxidoreductase, EC 1.4.3.14) from Trichoderma viride was relatively specific for l-lysine and had very low activity with Nε-substituted derivatives. l-Amino acid oxidase (l-amino acid: O2 oxidoreductase [deaminating], EC 1.4.3.2) from Crotalus adamanteus venom had low activity with l-lysine but high activity with Nε-formyl-, t-butyoxycarbonyl(BOC)-, acetyl-, trifluoroacetyl-, or CBZ-l-lysine. l-2-Hydroxyisocaproate dehydrogenase (EC 1.1.1.-) from Lactobacillus confusus catalyzed the reduction by NADH of the keto acids from Nε-acetyl-, trifluoroacetyl-, formyl- and CBZ-l-lysine but was inactive with the products from oxidation of l-lysine, l-lysine methyl ester, l-lysine ethyl ester or Nε-t-BOC-l-lysine. Providencia alcalifaciens (SC9036, ATCC 13159) was a good microbial substitute for the snake venom oxidase and also provided catalase (H2O2:H2O2 oxidoreductase EC 1.11.1.6). Nε-CBZ-l-Lysine was converted to CBZ-l-oxylysine in 95% yield with 98.5% optical purity by oxidation using P. alcalifaciens cells followed by reduction of the keto acid using l-2-hydroxyisocaproate dehydrogenase. NADH was regenerated using formate dehydrogenase (formate: NAD oxidoreductase, EC 1.2.1.2) from Candida boidinii. The Providencia oxidase was localized in the particulate fraction and catalase activity was predominantly in the soluble fraction of sonicated cells. The pH optima and kinetic constants were determined for the reactions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00240733
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  • 10
    Electronic Resource
    Electronic Resource
    Enantioselective enzymatic acetylation of racemic [4-[4α,6β (E)]]-6-[4,4-bis(4-fluorophenyl)-3-(1-methyl-1H-tetrazol-5-yl)-1,3-butadienyl]-tetrahydro-4-hydroxy-2H-pyran-2-one (1992)
    Springer
    Applied microbiology and biotechnology 38 (1992), S. 56-60 
    Details
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Summary A chiral compound [4R-[4α,6ß(E)]]-6-[4,4-bis(4-fluorophenyl)-3-(1-methyl-1H-tetrazol-5-yl)-1,3-butadienyl]-tetrahydro-4-hydroxy-2H-pyran-2-one (R-(+)-1) was prepared by the lipase-catalysed stereoselective acetylation of racemic 1 in an organic solvent. Chiral R-(+)-1 is a hydroxymethyl glutaryl coenzyme A (HMG CoA) reductase inhibitor and a potential anticholesterol drug candidate. Among various lipases evaluated, lipase PS-30 from Pseudomonas species efficiently catalysed acetylation of the undesired enantiomer of racemic 1 to yield the S-(−)-acetylated product 2 and unreacted desired R-(+)-1. A reaction yield of 48 mol% and an optical purity of 98% were obtained for R-(+)-1 when the reaction was conducted in toluence as solvent in the presence of isopropenyl acetate as acyl donor. Lipase PS-30 was immobilized on Accurel polypropylene (PP) and the immobilized enzyme was reused (five cycles) in the acetylation reaction without loss of enzyme activity, productivity, or optical purity of the R-(+)-1. The enzymatic acetylation process was scaled-up to 501 and a 640-l volume (preparative batches) at a substrate concentration of 4 g/l. R-(+)–1 was recovered from the preparative batches in 68–71% recovery yield with 98.5% gas chromatography homogeneity index and 98.5% optical purity. The S-(−) acetate 2 produced by the acetylation reaction was enzymatically hydrolysed by lipase PS-30 in a biphasic system to prepare the corresponding S-(−)-1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00169419
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