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  • 1
    Publication Date: 2019-07-17
    Description: H2O2 is an important component of the atmospheric oxidizingcapacity, determining the lifetime of atmospheric tracespecies. Bi-directional summertime H2O2 fluxes from thesnowpack at Summit, Greenland, reveal a daytime release fromthe surface snow reservoir during the warm part of the dayand a partial re-deposition at night. The data also providethe first direct evidence of a strong net summertime H2O2release from the snowpack, increasing average boundary layerH2O2 concentrations ~ 7-fold and the OH and HO2concentrations by 70% and 50%, respectively. Changes in H2O2concentration in the snow combined with photochemical andair-snow interaction modeling show that the net snowpackrelease is driven by temperature induced desorption of H2O2as deposited snow, which is supersaturated with respect toice-air partitioning, approaches equilibrium. The resultsshow that the physical cycling of H2O2, and possibly othervolatile species is a key to understanding snowpacks ascomplex physical-photochemical reactors and has far reachingimplications for the interpretation of ice core records aswell as for the photochemistry in polar regions and in thevicinity of snowpacks in general.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 2
    Publication Date: 2019-07-17
    Description: Hydrogen peroxide (H2O2) contributes to the atmospheres oxidizing capacity, which determinesthe lifetime of atmospheric trace species. Measured bidirectional summertime H2O2 fluxes fromthe snowpack at Summit, Greenland, in June 1996 reveal a daytime H2O2 release from thesurface snow reservoir and a partial redeposition at night. The observations also provide the firstdirect evidence of a strong net summertime H2O2 release from the snowpack, enhancing averageboundary layer H2O2 concentrations approximately sevenfold and the OH and HO2concentrations by 70% and 50%, respectively, relative to that estimated from photochemicalmodeling in the absence of the snowpack source. The total H2O2 release over a 12-day periodwas of the order of 5 * 10(13) molecules m(-2) s(-1) and compares well with observed concentrationchanges in the top snow layer. Photochemical and air-snow interaction modeling indicate thatthe net snowpack release is driven by temperature-induced uptake and release of H2O2 asdeposited snow, which is supersaturated with respect to ice-air partitioning, approachesequilibrium. The results show that the physical cycling of H2O2 and possibly other volatilespecies is a key to understanding snowpacks as complex physical-photochemical reactors and hasfar reaching implications for the interpretation of ice core records as well as for thephotochemistry in polar regions and in the vicinity of snowpacks in general.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 3
    Publication Date: 2021-06-28
    Description: Knowledge on the determinants and patterns of water demand for different consumers supports the design of customized demand management strategies. Smart meters coupled with big data analytics tools create a unique opportunity to support such strategies. Yet, at present, the information content of smart meter data is not fully mined and usually needs to be complemented with water fixture inventory and survey data to achieve detailed customer segmentation based on end use water usage. In this paper, we developed a data‐driven approach that extracts information on heterogeneous water end use routines, main end use components, and temporal characteristics, only via data mining existing smart meter readings at the scale of individual households. We tested our approach on data from 327 households in Australia, each monitored with smart meters logging water use readings every 5 s. As part of the approach, we first disaggregated the household‐level water use time series into different end uses via Autoflow. We then adapted a customer segmentation based on eigenbehavior analysis to discriminate among heterogeneous water end use routines and identify clusters of consumers presenting similar routines. Results revealed three main water end use profile clusters, each characterized by a primary end use: shower, clothes washing, and irrigation. Time‐of‐use and intensity‐of‐use differences exist within each class, as well as different characteristics of regularity and periodicity over time. Our customer segmentation analysis approach provides utilities with a concise snapshot of recurrent water use routines from smart meter data and can be used to support customized demand management strategies.
    Description: Key Points: We investigate which water use behaviors can be identified from nonintrusive, single‐point, smart meter data We identify and cluster primary water use behaviors of single‐family households from disaggregated end use data We reveal the main water end uses driving different behaviors, usage patterns, and regularity, to support customized demand management
    Keywords: 333.91 ; water demand management ; water end uses ; segmentation analysis ; data mining ; water use behaviors ; smart meters
    Type: article
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  • 4
    Publication Date: 2022-06-08
    Description: Observations of volcanoes extruding andesitic lava to produce lava domes often reveal cyclic behavior. At Soufrière Hills Volcano, Montserrat, cycles with subdaily and multiweek periods have been recognized on many occasions. Observations clearly show that the period of subdaily cycles is modulated by the multiweek cycle. The subdaily and multiweek cycles have been modeled separately as stick-slip magma flow at the junction between a dyke and an overlying cylindrical conduit and as the filling and discharge of magma through the elastic-walled dyke, respectively. Here, we couple these two models to describe the behavior over a period of well-observed multiweek cycles, with accompanying subdaily cycles, from 13 May to 21 September 1997. The coupled model captures well the asymmetrical first-order behavior: the first 40% of the multiweek cycle consists of high rates of lava extrusion during short period/high amplitude subdaily cycles as the dyke reservoir discharges itself. The remainder of the cycle involves increasing pressurization as more magma is stored, and extrusion rate falls, followed by a gradual increase in the period of the subdaily cycles.
    Description: Published
    Description: 1895-1903
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 12 (1973), S. 2944-2949 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 7 (1968), S. 1942-1944 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 96 (1974), S. 1793-1798 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of chemical & engineering data 11 (1966), S. 231-233 
    ISSN: 1520-5134
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Environmental science & technology 9 (1975), S. 92-92 
    ISSN: 1520-5851
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 96 (1974), S. 6948-6955 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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