ISSN:
0947-3440
Keywords:
Carotenoids
;
Isonorastacene synthesis
;
Singlet oxygen
;
Effective chain length
;
Second-order quenching rate constants
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The bimolecular rate constants kq for quenching of singlet oxygen (1Δg state) by 26 different natural and novel synthetic carotenoids were determined at 37 °C in a mixture of chloroform and ethanol. The steady-state technique used involves the generation of 1O2 by thermal decomposition of disodium 3,3′-naphtalene-1,4-diyl-dipropionate endoperoxide (NDPO2) and the detection of its luminescence intensity at 1270 nm. Excitation energies (π,π*, 11Ag → 11Bu) and absorption maxima (430-590 nm) vary in the broadest range. Deeply coloured blue carotenoids are also included in the studies for the first time. An empirical correlation between the π,π* (11Ag → 11Bu) excitation energy and carotenoid structure (effective chain length Neff) was found: E(S) = 12642 cm-1 + 92027 cm-1 × 1/Neff. The quenching ability of the investigated carotenoids depends on the excitation energy of their transition at long wavelengths in a characteristic way showing as limiting factors either the thermal Arrhenius activation or the diffusion-controlled rate. This dependence and the suspected relationship between singlet E(S) and triplet E(T) energies, respectively, are discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970913
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