ALBERT

Description: The Mead Stream section (South Island, New Zealand) consists of a 650-m-thick series of continuous, well-exposed strata deposited on a South Pacific continental slope from the Late Cretaceous to the middle Eocene. We examined the uppermost Paleocene–middle Eocene part of the section, which consists of ~360 m of limestone and marl, for detailed magnetic polarity stratigraphy and calcareous nannofossil and foraminifera biostratigraphy. Magneto-biostratigraphic data indicate that the section straddles magnetic polarity chrons from C24r to C18n, calcareous nannofossil zones from NP9a to NP17 (CNP11–CNE15, following a recently revised Paleogene zonation), and from the Waipawan to the Bortonian New Zealand stages (i.e., from the base of the Ypresian to the Bartonian international stages). The Mead Stream section thus encompasses 17 m.y. (56–39 Ma) of southwest Pacific Ocean history. The ages of calcareous nannofossil biohorizons are consistent with low- to midlatitude data from the literature, indicating that during the early–middle Eocene, the low- to midlatitude calcareous nannofossil domain extended at least to ~50°S–55°S in the South Pacific. Correlation of the magnetic polarity stratigraphy from the Mead Stream section with the geomagnetic polarity time scale allows us to derive sediment accumulation rates (SAR), which range between 8 and 44 m/m.y. Comparing the SAR with paleotemperature proxy records, we found that two intervals of increased SAR occurred during the early Eocene climatic optimum (52–50 Ma) and during the transient warming event peaking with the middle Eocene climatic optimum (40.5 Ma). This correlation indicates that, at Mead Stream, the climate evolution of the early–middle Eocene is recorded in a sedimentation pattern whereby, on a million-year time scale, warmer climate promoted continental weathering, transportation, and accumulation of terrigenous sediments.

Description: The Cretaceous to early Paleogene (ca. 140–50 Ma) was characterized by a greenhouse baseline climate, driven by elevated concentrations of atmospheric CO 2 . Hypotheses for the elevated CO 2 concentrations invoke an increase in volcanic CO 2 production due to higher oceanic crust production rates, higher frequency of large igneous provinces, or increases in pelagic carbonate deposition, the last leading to enhanced carbonate subduction into the mantle source regions of arc volcanoes. However, these are not the only volcanic sources of CO 2 during this time interval. We show here that ocean-continent subduction zones, manifested as a global chain of continental arc volcanoes, were as much as 200% longer in the Cretaceous and early Paleogene than in the late Paleogene to present, when a cooler climate prevailed. In particular, many of these continental arcs, unlike island arcs, intersected ancient continental platform carbonates stored on the continental upper plate. We show that the greater length of Cretaceous–Paleogene continental arcs, specifically carbonate-intersecting arcs, could have increased global production of CO 2 by at least 3.7–5.5 times that of the present day. This magmatically driven crustal decarbonation flux of CO 2 through continental arcs exceeds that delivered by Cretaceous oceanic crust production, and was sufficient to drive Cretaceous–Paleogene greenhouse conditions. Thus, carbonate-intersecting continental arc volcanoes likely played an important role in driving greenhouse conditions in the Cretaceous–Paleogene. If so, the waning of North American and Eurasian continental arcs in the Late Cretaceous to early Paleogene, followed by a fundamental shift in western Pacific subduction zones ca. 52 Ma to an island arc–dominated regime, would have been manifested as a decline in global volcanic CO 2 production, prompting a return to an icehouse baseline in the Neogene. Our analysis leads us to speculate that long-term (〉50 m.y.) greenhouse-icehouse oscillations may be linked to fluctuations between continental- and island arc–dominated states. These tectonic fluctuations may result from large-scale changes in the nature of subduction zones, changes we speculate may be tied to the assembly and dispersal of continents. Specifically, dispersal of continents may drive the leading edge of continents to override subduction zones, resulting in continental arc volcanism, whereas assembly of continents or closing of large ocean basins may be manifested as large-scale slab rollback, resulting in the development of intraoceanic volcanic arcs. We suggest that greenhouse-icehouse oscillations are a natural consequence of plate tectonics operating in the presence of continental masses, serving as a large capacitor of carbonates that can be episodically purged during global flare-ups in continental arcs. Importantly, if the global crustal carbonate reservoir has grown with time, as might be expected because platform carbonates on continents do not generally subduct, the greenhouse-driving potential of continental arcs would have been small during the Archean, but would have increased in the Neoproterozoic and Phanerozoic after a significant reservoir of crustal carbonates had formed in response to the evolution of life and the growth of continents.

Description: Major variations in global carbon cycling occurred between 62 and 48 Ma. To better constrain the cause and magnitude of these changes, the community needs early Paleogene carbon isotope and carbonate accumulation records from widely separated deep-sea sediment sections, especially including the Indian Ocean. With the potential for renewed scientific drilling in the Indian Ocean, we examine lithologic, nannofossil assemblage, carbon isotope, and carbonate content records for late Paleocene – early Eocene sediment recovered at three existing sites spanning Ninetyeast Ridge: Deep Sea Drilling Project (DSDP) Sites 213 (deep, east), 214 (shallow, central), and 215 (deep, west). The sediment sections are not ideal, because they were recovered in single holes using rotary coring methods. Site 214 was very shallow during the late Paleocene, when it received significant amounts of neritic carbonate. The δ13C records at Sites 213 and 215 are similar to those generated at several locations in the Atlantic and Pacific. The prominent high in δ13C across the Paleocene carbon isotope maximum (PCIM) occurs at Site 215, and the prominent low in δ13C across the early Eocene Climatic Optimum (EECO) occurs at both Site 213 and Site 215. The Paleocene–Eocene thermal maximum (PETM) and the K/X event are found at Site 213 but not at Site 215, presumably because of coring gaps. Carbonate content at both Sites 213 and 215 drops to 〈 5% shortly after the first occurrence of Discoaster lodoensis and the early Eocene rise in δ13C (~ 52 Ma). This reflects a rapid shoaling of the calcite compensation depth (CCD), and likely a major decrease in the net flux of 13C-depleted carbon to the ocean. Our work further constrains knowledge of the early Paleogene CCD, but more importantly suggests that excellent early Paleogene carbonate accumulation records might be recovered from the central Indian Ocean with future scientific drilling.

Description: Major variations in global carbon cycling occurred between 62 and 48 Ma, and these very likely related to changes in the total carbon inventory of the ocean-atmosphere system. Based on carbon cycle theory, variations in the mass of the ocean carbon should be reflected in contemporaneous global ocean carbonate accumulation on the seafloor and, thereby, the depth of the calcite compensation depth (CCD). To better constrain the cause and magnitude of these changes, the community needs early Paleogene carbon isotope and carbonate accumulation records from widely separated deep-sea sediment sections, especially including the Indian Ocean. Several CCD reconstructions for this time interval have been generated using scientific drill sites in the Atlantic and Pacific oceans; however, corresponding information from the Indian Ocean has been extremely limited. To assess the depth of the CCD and the potential for renewed scientific drilling of Paleogene sequences in the Indian Ocean, we examine lithologic, nannofossil, carbon isotope, and carbonate content records for late Paleocene – early Eocene sediments recovered at three sites spanning Ninetyeast Ridge: Deep Sea Drilling Project (DSDP) Sites 213 (deep, east), 214 (shallow, central), and 215 (deep, west). The disturbed, discontinuous sediment sections are not ideal, because they were recovered in single holes using rotary coring methods, but remain the best Paleogene sediments available from the central Indian Ocean. The δ13C records at Sites 213 and 215 are similar to those generated at several locations in the Atlantic and Pacific, including the prominent high in δ13C across the Paleocene carbon isotope maximum (PCIM) at Site 215, and the prominent low in δ13C across the early Eocene Climatic Optimum (EECO) at both Site 213 and Site 215. The Paleocene-Eocene thermal maximum (PETM) and the K/X event are found at Site 213 but not at Site 215, presumably because of coring gaps. Carbonate content at both Sites 213 and 215 drops to

Description: The Cretaceous to early Paleogene (ca. 140–50 Ma) was characterized by a greenhouse baseline climate, driven by elevated concentrations of atmospheric CO2. Hypotheses for the elevated CO2 concentrations invoke an increase in volcanic CO2 production due to higher oceanic crust production rates, higher frequency of large igneous provinces, or increases in pelagic carbonate deposition, the last leading to enhanced carbonate subduction into the mantle source regions of arc volcanoes. However, these are not the only volcanic sources of CO2 during this time interval. We show here that ocean-continent subduction zones, manifested as a global chain of continental arc volcanoes, were as much as 200% longer in the Cretaceous and early Paleogene than in the late Paleogene to present, when a cooler climate prevailed. In particular, many of these continental arcs, unlike island arcs, intersected ancient continental platform carbonates stored on the continental upper plate. We show that the greater length of Cretaceous–Paleogene continental arcs, specifically carbonate-intersecting arcs, could have increased global production of CO2 by at least 3.7–5.5 times that of the present day. This magmatically driven crustal decarbonation flux of CO2 through continental arcs exceeds that delivered by Cretaceous oceanic crust production, and was sufficient to drive Cretaceous–Paleogene greenhouse conditions. Thus, carbonate-intersecting continental arc volcanoes likely played an important role in driving greenhouse conditions in the Cretaceous–Paleogene. If so, the waning of North American and Eurasian continental arcs in the Late Cretaceous to early Paleogene, followed by a fundamental shift in western Pacific subduction zones ca. 52 Ma to an island arc–dominated regime, would have been manifested as a decline in global volcanic CO2 production, prompting a return to an icehouse baseline in the Neogene. Our analysis leads us to speculate that long-term (〉50 m.y.) greenhouse-icehouse oscillations may be linked to fluctuations between continental- and island arc–dominated states. These tectonic fluctuations may result from large-scale changes in the nature of subduction zones, changes we speculate may be tied to the assembly and dispersal of continents. Specifically, dispersal of continents may drive the leading edge of continents to override subduction zones, resulting in continental arc volcanism, whereas assembly of continents or closing of large ocean basins may be manifested as large-scale slab rollback, resulting in the development of intraoceanic volcanic arcs. We suggest that greenhouse-icehouse oscillations are a natural consequence of plate tectonics operating in the presence of continental masses, serving as a large capacitor of carbonates that can be episodically purged during global flare-ups in continental arcs. Importantly, if the global crustal carbonate reservoir has grown with time, as might be expected because platform carbonates on continents do not generally subduct, the greenhouse-driving potential of continental arcs would have been small during the Archean, but would have increased in the Neoproterozoic and Phanerozoic after a significant reservoir of crustal carbonates had formed in response to the evolution of life and the growth of continents.

Description: The Cretaceous to early Paleogene (ca. 140–50 Ma) was characterized by a greenhouse baseline climate, driven by elevated concentrations of atmospheric CO2. Hypotheses for the elevated CO2 concentrations invoke an increase in volcanic CO2 production due to higher oceanic crust production rates, higher frequency of large igneous provinces, or increases in pelagic carbonate deposition, the last leading to enhanced carbonate subduction into the mantle source regions of arc volcanoes. However, these are not the only volcanic sources of CO2 during this time interval. We show here that ocean-continent subduction zones, manifested as a global chain of continental arc volcanoes, were as much as 200% longer in the Cretaceous and early Paleogene than in the late Paleogene to present, when a cooler climate prevailed. In particular, many of these continental arcs, unlike island arcs, intersected ancient continental platform carbonates stored on the continental upper plate. We show that the greater length of Cretaceous–Paleogene continental arcs, specifically carbonate-intersecting arcs, could have increased global production of CO2 by at least 3.7–5.5 times that of the present day. This magmatically driven crustal decarbonation flux of CO2 through continental arcs exceeds that delivered by Cretaceous oceanic crust production, and was sufficient to drive Cretaceous–Paleogene greenhouse conditions. Thus, carbonate-intersecting continental arc volcanoes likely played an important role in driving greenhouse conditions in the Cretaceous–Paleogene. If so, the waning of North American and Eurasian continental arcs in the Late Cretaceous to early Paleogene, followed by a fundamental shift in western Pacific subduction zones ca. 52 Ma to an island arc–dominated regime, would have been manifested as a decline in global volcanic CO2 production, prompting a return to an icehouse baseline in the Neogene. Our analysis leads us to speculate that long-term (〉50 m.y.) greenhouse-icehouse oscillations may be linked to fluctuations between continental- and island arc–dominated states. These tectonic fluctuations may result from large-scale changes in the nature of subduction zones, changes we speculate may be tied to the assembly and dispersal of continents. Specifically, dispersal of continents may drive the leading edge of continents to override subduction zones, resulting in continental arc volcanism, whereas assembly of continents or closing of large ocean basins may be manifested as large-scale slab rollback, resulting in the development of intraoceanic volcanic arcs. We suggest that greenhouse-icehouse oscillations are a natural consequence of plate tectonics operating in the presence of continental masses, serving as a large capacitor of carbonates that can be episodically purged during global flare-ups in continental arcs. Importantly, if the global crustal carbonate reservoir has grown with time, as might be expected because platform carbonates on continents do not generally subduct, the greenhouse-driving potential of continental arcs would have been small during the Archean, but would have increased in the Neoproterozoic and Phanerozoic after a significant reservoir of crustal carbonates had formed in response to the evolution of life and the growth of continents.

Description: The Cretaceous to early Paleogene (ca. 140–50 Ma) was characterized by a greenhouse baseline climate, driven by elevated concentrations of atmospheric CO2. Hypotheses for the elevated CO2 concentrations invoke an increase in volcanic CO2 production due to higher oceanic crust production rates, higher frequency of large igneous provinces, or increases in pelagic carbonate deposition, the last leading to enhanced carbonate subduction into the mantle source regions of arc volcanoes. However, these are not the only volcanic sources of CO2 during this time interval. We show here that ocean-continent subduction zones, manifested as a global chain of continental arc volcanoes, were as much as 200% longer in the Cretaceous and early Paleogene than in the late Paleogene to present, when a cooler climate prevailed. In particular, many of these continental arcs, unlike island arcs, intersected ancient continental platform carbonates stored on the continental upper plate. We show that the greater length of Cretaceous–Paleogene continental arcs, specifically carbonate-intersecting arcs, could have increased global production of CO2 by at least 3.7–5.5 times that of the present day. This magmatically driven crustal decarbonation flux of CO2 through continental arcs exceeds that delivered by Cretaceous oceanic crust production, and was sufficient to drive Cretaceous–Paleogene greenhouse conditions. Thus, carbonate-intersecting continental arc volcanoes likely played an important role in driving greenhouse conditions in the Cretaceous–Paleogene. If so, the waning of North American and Eurasian continental arcs in the Late Cretaceous to early Paleogene, followed by a fundamental shift in western Pacific subduction zones ca. 52 Ma to an island arc–dominated regime, would have been manifested as a decline in global volcanic CO2 production, prompting a return to an icehouse baseline in the Neogene. Our analysis leads us to speculate that long-term (〉50 m.y.) greenhouse-icehouse oscillations may be linked to fluctuations between continental- and island arc–dominated states. These tectonic fluctuations may result from large-scale changes in the nature of subduction zones, changes we speculate may be tied to the assembly and dispersal of continents. Specifically, dispersal of continents may drive the leading edge of continents to override subduction zones, resulting in continental arc volcanism, whereas assembly of continents or closing of large ocean basins may be manifested as large-scale slab rollback, resulting in the development of intraoceanic volcanic arcs. We suggest that greenhouse-icehouse oscillations are a natural consequence of plate tectonics operating in the presence of continental masses, serving as a large capacitor of carbonates that can be episodically purged during global flare-ups in continental arcs. Importantly, if the global crustal carbonate reservoir has grown with time, as might be expected because platform carbonates on continents do not generally subduct, the greenhouse-driving potential of continental arcs would have been small during the Archean, but would have increased in the Neoproterozoic and Phanerozoic after a significant reservoir of crustal carbonates had formed in response to the evolution of life and the growth of continents.