Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
108 (1998), S. 4054-4059
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The (BaF)2 cluster has been produced in a supersonic expansion of a mixture of helium and CH3F which contained laser desorbed barium. Its photodepletion action spectrum measured by time-of-flight mass spectrometry displays low depletion cross sections ((approximate)3 Å2) and a clear vibrational structure. This structure has been analyzed to obtain spectroscopic constants of the excited state involved in the photofragmentation of the cluster. Furthermore, its ionization potential (I.P.) has been determined to be 4.03 eV, and a discussion on the spectroscopy, structure, and dynamics of the cluster is also presented. © 1998 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.475842
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