ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
O=As(NMe2)3 (HMAsT) is obtained in low yields by reacting O=AsCl3 with excess HNMe2 or by ozonolysis of As(NMe2)3; however, it is formed in yields 〉65% by using (Me3Si)2O2 and As(NMe2)3 in hydrocarbon solution. The structure of HMAsT was established by IR/Raman, NMR and mass spectroscopy, and single crystal X-ray structure analysis. The structure determination revealed (sp3C)-H…O-hydrogen bonding in the solid state. Acid-base reaction by methanolysis affords ionic [Me2NH2] [O2As(OMe)2] while iodide is oxidized to iodine.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520020604
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