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  • 1
    ISSN: 1432-0630
    Keywords: PACS: 75.30.GW; 75.50.WW; 81.20.-N
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. The effect of additive C on characterization of crystalline texture and magnetic properties of anisotropic melt-spun Sm(CoZr)7 alloy has been investigated. A few percent of C addition was found to not only significantly enhance the coercivity of the ribbons but also affect the characterization of crystalline texture. The easy-magnetization c axis is changed from parallel to the ribbon plane for SmCo6.5Zr0.5 ribbons, to normal to the ribbon plane for the SmCo6.5Zr0.5C0.5 one. Maximum energy product of SmCo6.5Zr0.5C0.5 ribbons prepared at 5 m/s, pulse magnetized to 5 T and measured normal or parallel to the ribbon plane is 8.6 MGOe or 3.2 MGOe, respectively. The domain structure was studied by magnetic-force microscope. A strip-shaped domain can be observed on the surface of the SmCo6.5Zr0.5 ribbons and the walls lie straight and parallel. For C-doped ribbons, the domain walls form a maze domain pattern of grains with c axis normal to the ribbon plane. Scanning electron micrography analysis showed that a dendrite structure was present in the SmCoZr ribbon surface. C addition leads to the diminishing of the above dendrite and the grains become equiaxial. The characterization of crystalline texture in C-free and C-doped ribbons has been correlated with their microstructure.
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Until now, the origin of hard magnetic properties of rapidly quenched Nd-Fe-B alloys with lower Nd concentration is not clear. In this paper, the phase compositions of rapidly quenched Nd4Fe77.5B18.5 alloys annealed under different conditions have been studied by using zero-field spin-echo nuclear magnetic resonance (NMR) and Mössbauer effect (ME) techniques. It is found that there exists a certain amount of Nd2Fe14B phase in the samples annealed at 960 °C and ingot alloy, which have poor hard magnetic properties; while, the sample annealed under optimal condition consists only of bct-Fe3B as the main phase and a small amount of a-Fe. However, the ME result indicates that about 5 at. % Fe atoms in FeIII (8 g) site of bct-Fe3B have been replaced by Nd atoms; the NMR result demonstrates that 11B NMR spectrum is the characteristic peak of bct-Fe3B, but it broadens asymmetrically to the high frequency side, which is due to the bct-Fe3B influenced by Nd atoms. The amplitude of radio frequency (rf) excitation field required to get the maximum 11B spin-echo signal from bct-Fe3B in the sample annealed at 839 °C is only about one third as much as that required to excite the 11B in the bct-Fe3B influenced by Nd atoms in the sample annealed at 670 °C for a short time, which implies the latter has a larger coercivity field than the former. It is concluded that the origin of hard magnetic properties of Nd4Fe77.5B18.5 alloy is not related to the 2:14:1 phase, but to the change of bct-Fe3B itself.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 3965-3970 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The magnetic properties of [Fe(20 A(ring))/Pd(x A(ring))]25 multilayers prepared by ultrahigh vacuum electron-beam evaporation are presented. It is found that the crystal structure of Fe layers change from bcc to fcc when the thickness of Pd layers dPd≥36 A(ring). The saturation magnetization per unit Fe volume at 5 K is enhanced and oscillates with the increment of the thickness of Pd layers, due to the polarization of Pd atoms. The magnetic hysteresis loops of samples indicate low coercive forces, and ferromagnetic coupling between the Fe layers for all Pd thicknesses (6–60 A(ring)). The conversion electron Mössbauer spectra measurements proved that the magnetic moment of fcc Fe is the same as that of the bcc Fe. It is also found that the magnetic anisotropy dependence on dPd is similar to that of the saturation magnetization, and relates to the Fe layer structure transition. The Curie temperature of Fe/Pd multilayers decreases monotonously with the increasing of dPd. The low temperature magnetization measurement of Fe/Pd multilayers suggests that the interlayer coupling between Fe layers and polarization of Pd layers influences the temperature dependence of saturation magnetization. No evidence of antiferromagnetic coupling between Fe layers and giant magnetoresistance effect is found. The relationship among structure, polarization of Pd layers, and magnetic coupling is discussed. © 1995 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 6955-6957 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The metastable compound Nd6Fe77B17 has been obtained by the crystallization from the amorphous phase in the Nd-Fe-B system. Its crystal structure is similar to that of the compound Nd2Fe23B3. At high temperature this metastable compound decomposes into α-Fe and Nd1.1Fe4B4 phases. The room temperature magnetization and coercivity are 154 A m2/kg and 12 kA/m, respectively.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 4918-4920 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic granular CoCu alloy ribbons were prepared by the melt-spun method, and the structural, magnetotransport, magnetic properties, and the effects of annealing on these properties were studied by x-ray diffraction, vibrating sample magnetometer, and magnetoresistance (MR) measurements at room temperature. Giant magnetoresistance was observed over a broad range of Co concentrations with a maximum MR ratio of 7.8% (at x=0.20 and 500 °C annealing) under a magnetic field of 20 kOe at room temperature. It is found that the relationship between MR and magnetic field H depended strongly on the annealing temperature and a linear MR-H relation could be obtained at an optimum annealing condition. The MR ratio did not depend on the direction between H and electric current I. These features are very suitable for making isotropic magnetic field transducers.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 8351-8353 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Pr8Fe88B4 ribbons prepared by melt spinning have been investigated by x-ray diffraction, differential thermal analysis, thermomagnetic analysis, atom force microscopy, and superconducting quantum interface device magnetometer. The results show that the annealed ribbons consist of the Pr2Fe14B and α-Fe phases. The magnetization of soft α-Fe phase remains parallel to the magnetization of the hard Pr2Fe14B phase for fields less than the exchange field (Hex). The exchange field in exchange-spring magnets, determined from the demagnetization curves measured at various temperatures, increases with decreasing grain size and measure temperature. The temperature dependence of exchange field was analyzed qualitatively by the expression Hex=(AK)1/2/(Mst). © 2001 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 1331-1335 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Structural and magnetic properties of La1−xSmxCoO3 with x=0, 0.02, 0.04, 0.06, 0.08, 0.12, 0.16, and 0.2 have been systematically studied. LaCoO3 exhibits a rhombohedral structure of R3¯C symmetry. The lattice parameters decrease progressively with the incorporation of Sm, and a second orthorhombic phase of Pbnm symmetry appears for x≥0.12. The volume fraction of the orthorhombic phase is a sensitive function of the Sm content in the compounds, and increases from 16% for x=0.12 to 75% for x=0.2. Accordingly, the low-spin-to-high-spin transition of the trivalent Co ions, characterized by a steep rise of the magnetization, shifts to higher temperatures. A molecular field analysis indicates an increased energy gap, from 317 K for x=0 to 500 K for x=0.2, between the low-spin and the high-spin state, implying a stabilization of the low-spin trivalent Co ions by the presence of Sm. The enhanced compressive chemical pressure due to the introduction of Sm is suggested to be responsible for the present observations. © 2001 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 3873-3877 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The influence of substitution of B for Fe on the microstructure, magnetic properties, and giant magnetoimpedance (GMI) effect has been studied for the nanocrystalline soft magnetic ribbons Fe92−2Zr7BxCu1 (x=2,4,6,8,10) annealed at 873 K for 20 min. The experimental results show that the thermal stability of the amorphous precursor is enhanced and the body-centered-cubic phase grains become smaller with increasing B content. The coercive force Hc exhibits a minimum of 2.51 A/m for the ribbon with x=8, where the effective permeability reaches the maximum. The frequency and field dependence of GMI effect is very sensitive to B content. For the ribbon with x=8, The maximal GMI ratio (ΔZ/Z)ΔZ/Z=[Z(H)−Z(Hmax)]/Z(Hmax) is about 260% at f=6.5 MHz, and the maximal sensitivity reaches value up to about 0.88% (A/m)−1 (66.6% Oe−1) at f=10.5 MHz. The correlation between the magnetic properties and the GMI effect shows that the excellent soft magnetic properties and proper transverse anisotropy play a decisive role in the occurrence of the GMI effect. © 1999 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 3863-3865 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The low-temperature magnetic and transport properties of La2/3Sr1/3MnO3 nanoparticles have been investigated. It is found that a surface spin-glass behavior exists in La2/3Sr1/3MnO3 nanoparticles, which undergo a magnetic transition to a frozen state below 45 K. The low-temperature surface spin-glass behavior exists even at the highest field used (H=50 kOe). Moreover, the spin-glass-like transition disappears for particles above 50 nm. In addition, the suppressed low-field magnetoconductivity (LFMC) observed at low temperature for nanosized La2/3Sr1/3MnO3 is obviously lower than the expected upper limit of LFMC, 1/3, for polycrystalline manganites, which is proposed to arise from the higher-order tunneling through the insulating spin-glass-like surface layers. © 2001 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 1790-1791 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
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