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  • 1
    Electronic Resource
    Electronic Resource
    Effect of dentate number of anchored phosphine ligands on the composition and catalytic properties of their palladium complexes (1979)
    Springer
    Reaction kinetics and catalysis letters 10 (1979), S. 105-110 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Проведён синтез моно-, ди- и трифосфиновых литандов, закр еплённых связью Si−C с поверхностью силикагеля. Получены комплексные соедине ния Pd(II) и Pd(O) с этими лигандами. На основании данных элементного анализа и УФ-спектроскопии предложены структуры образуюшихся комплексов. Сопоставлены катал итические свойства полученных комплексов в реакции селективного гидриров ания циклопентадиена.
    Notes: Abstract Mono-, di- and triphosphine ligands anchored by a Si−C bond to the surface of silica have been synthesized. Complexes of Pd(II) and Pd(O) with these ligands have been obtained. On the basis of elemental analysis and UV spectroscopy, structures of the complexes formed are suggested. The catalytic properties of the above complexes in the selective hydrogenation of cyclopentadiene are compared.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02067521
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  • 2
    Electronic Resource
    Electronic Resource
    Ethylene oligomerization on heterogenized titanium and zirconium complexes (1979)
    Springer
    Reaction kinetics and catalysis letters 11 (1979), S. 301-305 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Наряду с другими продуктами были получены высшие олефины линейной структуры в олигомеризации этилена при низкой температуре с селективностью 30–58 вес.% и линейностью до 85%. Активированные титан- и цирконий-содержащие комплексы, используемые в качестве катализаторов, были закреплены на SiO2 через связанные на поверхности бидентатные S- и N-содержащие лиганды. При этом первые оказались лучшими, чем последние, с точки зрения качества продукта.
    Notes: Abstract Besides other products, linear middle-range olefins were obtained in the low temperature oligomerization of ethylene with a selectivity of 30–58% and a linearity up to 85%. Activated ticanium and zirconium complexes as catalysts were attached to SiO2 through surface bounded bidentate S- and N-containing ligands, the former being superior to the latter with respect to product quality.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02079716
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  • 3
    Electronic Resource
    Electronic Resource
    Catalytic properties of palladium complexes with silica-anchored phosphine ligands in vinyl exchange reaction (1979)
    Springer
    Reaction kinetics and catalysis letters 12 (1979), S. 177-181 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Изучены каталитические свойства комплексов палладия с закрепленными на поверхности силикагеля фосфиновыми лигандами. Исследовано влияние степени окисления иона палладия и кислотности спиртов на скорость реакции винильного обмена. Предложен возможный механизм реакции винильного обмена.
    Notes: Abstract Catalytic properties of Pd complexes with phosphine ligands anchored to silica have been studied. The valence state of Pd and the acidity of the alcohol were found to influence the rate of vinyl exhange. A possible reaction mechanism is proposed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02071907
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  • 4
    Electronic Resource
    Electronic Resource
    Influence of alkaline and acidic promoters on the catalytic properties of metallic palladium and rhodium in CO hydrogenation (1986)
    Springer
    Reaction kinetics and catalysis letters 31 (1986), S. 55-60 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Исследовано влияние добавок щелочей и кислот на состав продуктов гидрирования окиси углерода на металлических палладии и родии, нанесенных на силикагель. Показано, что добавки щелочи увеличивают выход метанола, а добавки кислоты —этанола.
    Notes: Abstract Influence of alkaline and acidic promoters on the composition of CO hydrogenation products on SiO2-supported metallic palladium and rhodium has been examined. Alkaline and acidic promoters have been established to increase the yield of methanol and ethanol, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02062511
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  • 5
    Electronic Resource
    Electronic Resource
    New carbon-carbonaceous composites for catalysis and adsorption (1995)
    Springer
    Reaction kinetics and catalysis letters 54 (1995), S. 381-411 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Properties, structural features, and basic principles for the synthesis of some new carbon-carbonaceous composite materials (CCM) originating at the Boreskov Institute of Catalysis are discussed. The CCM are synthesized via chemical growth of carbon deposits in a pre-formed porous carbon matrix. Among the CCM are: Sibunit produced by supporting pyrocarbon (PC) on carbon black granules, carbon filaments (CFC) produced by decomposition of CH4 over Ni or Ni−Cu catalysts, CFC on Sibunit, CFC on ultradispersed diamond, and systems such as CFC/CFC, PC/CFC, etc. Basic mechanisms of structure and texture formation of CCM and some of their properties as adsorbents and catalyst supports are reported.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02071033
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  • 6
    Electronic Resource
    Electronic Resource
    A new cellular carbon support for catalysts: preparation and study of structure (1998)
    Springer
    Reaction kinetics and catalysis letters 63 (1998), S. 157-163 
    Details
    ISSN: 1588-2837
    Keywords: Carbon support ; preparation ; structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Cellular carbon has been prepared by pyrolysis of a propane—butane mixture in a flow reactor at 700–1250 K. Its structural characteristics were studied by scanning electron microscopy, high resolution transmission electron microscopy, X-ray diffraction and adsorption methods. It was shown that cell-type carbon possesses a unique structure in contrast to carbon composite “Sibunnit” and filamentous carbons and it may be a promising support for catalyst preparation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02475445
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  • 7
    Electronic Resource
    Electronic Resource
    Sintering of Pd particles on the surface of carbon supports in hydrogen (1993)
    Springer
    Reaction kinetics and catalysis letters 51 (1993), S. 507-515 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract High resolution electron microscopy methods have been used to study the sintering of Pd particles on the surface of carbon support. It was found that geometric non-uniformities, fractures and edge planes of graphite-like carbon, can function as localization centers of Pd particles.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02069098
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  • 8
    Electronic Resource
    Electronic Resource
    Pd/C catalysts. Deactivation and behavior of supported Pd particles upon heating (1993)
    Springer
    Reaction kinetics and catalysis letters 51 (1993), S. 517-524 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Deactivation of Pd/C catalysts upon heating in H2 has been studied as a function of support surface composition. The behavior of Pd particles on a chosen part of surface upon sample heating in an electron microscope chamber has been investigated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02069099
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  • 9
    Electronic Resource
    Electronic Resource
    Monooxygenase activity of immobilized iron(III) porphyrins (1981)
    Springer
    Reaction kinetics and catalysis letters 18 (1981), S. 277-281 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Найдены новые системы — иммобилизованные на силикагеле порфирины железа, обладающие монооксигеназной активностью в реакции окисления анилина в п-аминофенол. Показано, что каталитическая активность зависит как от структуры порфирина, так и от координации аксиальным лигандом. Максимальной активностью в данной реакции обладает гемин, координированный имидазолом. Показано, что гидроксилирование в данной системе осуществляется нерадикальным путём.
    Notes: Abstract New silica-immobilized iron(III) porphyrin systems possessing monooxygenase activity in aniline oxidation to p-aminophenol, have been found. The catalytic activity depends on both the porphyrin structure and coordination by an axial ligand. The maximum activity in this reaction is observed for imidazol-coordinated hemin. The hydroxylation in the above system is shown to follow a non-radical mechanism.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02065607
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  • 10
    Electronic Resource
    Electronic Resource
    Effect of medium composition on the monooxygenase activity of immobilized hemin in aniline oxidation (1981)
    Springer
    Reaction kinetics and catalysis letters 18 (1981), S. 289-293 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Изучено влияние состава реакционной среды на скорость окисления анилина в п-аминиофенол перекисью водорода на гемине, иммобилизованном на силикагеле, модифицированном γ-пропил-имидащолом. Показано, что добавки органических растворителей (спиртов, эфиров, нитрилов) повышают скорость реакции. Наблюдаемый эффект объяснён уменяшением дизлектрической проницаемости среды.
    Notes: Abstract The effect of the composition of the reaction medium on the rate of aniline oxidation to p-aminophenol by hydrogen peroxide on hemin immobilized on γ-propylimidazole-modified silica has been studied. Organic solvent additives (alcohols, esters and nitriles) are shown to increase the reaction rate. The observed effect is attributed to the decrease of the medium dielectric constant.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02065609
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