ISSN:
1573-8779
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The different electronic states of ozone (1A1,3B2,3A2,3B1, and 21A1) were calculated by a nonempirical method in the basis 4–31 G (d, p) taking into account the electronic correlation according to the Meller-Plesset theory of a fourth order perturbation theory (MP4). The geometric structures of the ions O 3 − and O3H+ were calculated. The evaluation of the affinity to the proton for O3 gave a value (PA=6.8 eV) 1 eV lower than that for H2O.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00761468
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