Wiley InterScience Backfile Collection 1832-2000
Chemistry and Pharmacology
Condensation of SiO with sodium or potassium, respectively, leads to the formation of Na+(SiO)- and K+(SiO)-. The SiO force constant is reduced to 6.15 mdyn/Å and 6.30 mdyn/Å with respect to uncoordinated SiO (f = 9.0 mdyn/Å). From these results a similar type of bonding can be concluded for the charge transfer complexes Ag+(SiO)- and Ag+(SiS)- published recently.
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