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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 211 (1966), S. 844-845 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The purpose of this paper is to outline a method which has been very useful in a recently completed photosynthesis study, and which may offer a solution to these problems. Goldman1'2 has dealt successfully with these two problems by oxidizing all organic carbon to carbon dioxide, and measuring ...
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 250 (1974), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
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  • 3
    ISSN: 1573-515X
    Keywords: lake acidification ; sulfate reduction ; denitrification ; alkalinity generation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Sulfate and nitrate removal, and the resulting sulfuric and nitric acid neutralization within acid-sensitive lakes, were predicted from a simple model requiring knowledge only of water residence time, mean depth, and average mass transfer coefficients for nitrate and sulfate removal. The model applies to lakes with oxic hypolimnia which are typical of acid-sensitive lakes. Average mass transfer coefficients for sulfate and nitrate were obtained by two independent methods which agreed well with each other. A model such as this is necessary for predicting the rates at which different lakes acidify and recover from acidification, and explains why lakes with short water residence times are especially susceptible to acidification.
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  • 4
    ISSN: 1573-515X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-515X
    Keywords: acidification ; alkalinity generation ; metaphyton ; sulfur ; sulfate reduction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Experimental acidification of a softwater lake to below pH 5 fundamentally changed the sulfur cycle and lowered internal alkalinity generation (IAG). Prior to reaching pH 4.5, the balance of sulfur reduction and oxidation reactions within the lake was in favour of reduction, and the lake was a net sink for sulfate. In the four years at pH 4.5 the balance of reduction and oxidation reactions was in favour of oxidation, and there was a net production of sulfate (SO4 2−) within the lake. Evidence indicating a decrease in net SO4 2− reduction at pH 4.5 was also obtained in an anthropogenically acidified lake that had been acidified for many decades. In both lakes, the decrease in net SO4 2− reduction appeared to be linked not to a simple inhibition of SO4 2− reduction but rather to changes in benthic ecosystem structure, especially the development of metaphytic filamentous green algae, which altered the balance between SO4 2− reduction and sulfur oxidation. At pH's above 4.5, net SO4 2− reduction was the major contributor to IAG in the experimental lake, as it is in many previously studied lakes at pH 5 and above. At pH 4.5, the change in net annual SO4 2− reduction (a decrease of 110%) resulted in a 38% decrease in total IAG. Because of the important role of net SO4 2− reduction in acid neutralization in softwater lakes, models for predicting acidification and recovery of lakes may need to be modified for lakes acidified to pH 〈5.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 1 (1985), S. 117-133 
    ISSN: 1573-515X
    Keywords: acidity ; alkalinity ; lake acidification ; lake fertilization ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Fertilization of a small lake with ammonium chloride for four years as part of a eutrophication experiment caused it to acidify to pH values as low as 4.6. Implications for acidification of lakes via precipitation polluted with ammonium compounds are discussed. When phosphate was supplied with the ammonium, biological nitrogen uptake, apparently by phytoplankton, was the main mechanism causing acidification. When ammonium was applied without phosphate, it accumulated to high concentrations in solution, after which nitrification caused rapid acidification. In both cases, the whole-lake efficiency of acidification was low, averaging about 13% of the potential acidification of supplied ammonium chloride (Table 2). Subsequent application of phosphate plus sodium nitrate for two years caused the pH of the lake to increase. The efficiency of alkalinization was higher than for acidification, averaging 69% of the potential alkalinization of the supplied sodium nitrate.
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  • 7
    ISSN: 1572-9729
    Keywords: fire ; climate change ; boreal forest ; stream ; sulfate ; acidity ; watershed
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In a boreal forest catchment in the Experimental Lakes Area in northwestern Ontario, wildfire caused an increase in the concentrations of strong acid anions and base cations of the stream. In the naturally base-poor Northwest (NW) Subbasin, a 1980 wildfire caused exports of strong acid anions to increase more than export of base cations, causing a 2.5 fold increase in the acidity of the stream. Mean annual stream pH declined from 5.15 prior to fire to 4.76 two years after fire. Acid-neutralizing capacity (ANC), calculated as the difference between total base cations and strong acid anions, decreased to 20% of pre-fire values. Sulfate and chloride were the strong acid anions responsible for the decline in ANC, increasing four-fold. While nitrate increased eleven-fold, concentrations were too low to significantly affect ANC. There was a significant correlation between weekly sulfate concentration and base cation concentration (r 2 = 0.83) in the two years after fire. Recovery of ANC was caused by the more rapid decline in concentration of sulfate than by changes in base cations. Drought produced a similar but weaker response than fire, with increased sulfate concentrations and decreased stream pH. Climatic warming that increases drought and fire frequency would have effects that mimic the impacts of acidic precipitation (i.e. higher sulfate concentrations and acidic stream waters). Areas which have higher concentrations of stored S from past acid precipitation or have large areas of peatlands in the watershed may have aggravated losses of S and H+ after drought and fire.
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  • 8
    ISSN: 1573-5117
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Effects of natural factors (drought and forest fire), and experimental perturbations (fertilization and acidification) on dissolved organic carbon (DOC) concentrations and ratios to other nutrients in lakes of the Experimental Lakes Area are examined using data obtained over a period of 20 years. DOC concentration, and the ratio of dissolved iron to DOC in lakes of the area were strongly correlated with the relative size of the catchment to the lake. DOC in many lakes of the area declined over 20 years, due to increased water residence times caused by increasing average temperature and decreasing precipitation. Inexplicably, Lake 382 was an exception to this general observation. Acidification of Lake 302S to below pH 5.0 also caused DOC to decrease. The lesser acidification of Lake 223 (min. pH 5.0) did not significantly affect DOC. Experimental acidification of a small peatland also caused a temporary decline in DOC concentrations in bog pools. Changes in DOC appear to affect the availability of mercury for methylation. Addition of aluminum to a small acidic lake caused a two-fold decline in DOC. Fertilization of Lake 227 caused a considerable increase in DOC, and in ratios of DOC to other carbon fractions. New stable ratios did not occur for a decade after fertilization began. Lake 226N, fertilized at a lower rate, showed similar but less pronounced increases in DOC, but the experiment was terminated after only eight years. Phosphorus fertilization caused a dramatic increase in the lability of the DOC pool in Lake 226N, where the autochthonous carbon pool was labelled with DI14C. A large increase in autochthonous production of DOC and increased microbial utilization of allochthonous DOC appear to have occurred. DOC concentrations in streams were higher after drought, but concentrations were unrelated to flow volume during wet periods. Due to lower streamflows in drought years, annual yields of DOC from streams were unaffected by drought. Mesocosm experiments showed that DOC's primary effect on iron is to inhibit sedimentation, possibly by suppressing flocculation reactions that are known to control the cycles of many metals. The changes in DOC in lakes brought about by changes in water renewal, acidification, or other perturbations can have major effects on the cycles of metals, lake transparency, and phytoplankton production and standing crop.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 30 (1986), S. 779-789 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Indicator taxa are identified, based on both synoptic surveys and whole lake acidification experiments, for lake acidification in the pH 6.0 to 5.0 range. Acidobiontic diatoms (e.g Asterionella ralfsii, Fragillaria acidobiontica, etc.), periphyton (Mougeotia and related species), macroinvertebrates (e.g. Hyalella azteca, Orconectes sp., etc.), leeches, and cyprinid fishes (e.g. Pimephales promelas, Notropis cornutus, etc.) are identified as target organisms during early phases of lake acidification.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 30 (1986), S. 931-944 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Alkalinity production in terrestrial and aquatic ecosystems of Canada, the U.S.A., Norway and Sweden is calculated from either strong acid titrations or budgets for base cations and strong acid anions, using mass-balance budgets. Where alkalinity budgets for lakes and their catchments are calculated in acid-vulnerable geological settings, in-lake processes often contribute more to lake alkalinity than yield from terrestrial catchments. Nitrate and sulfate removal, and Ca exchange with sediments are the predominant alkalinity generating mechanisms in lakes. Nitrate and sulfte removal rates increase as the concentrations of NO− 3 and SO4 2− in lake water increase, so that in-lake acid neutralizing capacity increases as acid deposition increases. Both processes occur in sediments overlain by oxic waters, at rates which seem to be controlled primarily by diffusion.
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