ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The fundamental possibility of the synthesis of 2-substituted 1,3-dioxanes by reaction of 1,3-dioxanium perchlorates with organometallic compounds is demonstrated. A method for the synthesis of acyl derivatives of heterocycles was developed on the basis of these compounds. The existence of 2,2,4,4-substituted 1,3-dioxanes in the twist conformation was shown by 1H NMR spectroscopy; the twist conformation is explained by the effect of nonbonded 1,3-syn-axial interactions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00509546
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