ALBERT

Description: The crustally derived High Himalayan leucogranites (HHL) are characterized by strong isotopic heterogeneity and occurrence of magmatic muscovite. Such attributes indicate that the HHL were non-convecting magma bodies and crystallized at pressure-equivalent depths of more than 8.5 km. We have performed one-dimensional thermal modelling in order to simulate the process of incremental growth of a laccolith whose roof is tectonically removed during intrusion, in a context of crustal exhumation due to channel flow. The objective is to define under what conditions HHL laccoliths emplaced close to active normal faults may be built without convecting while crystallizing muscovite. The results indicate that for a HHL thickness in the range 5-10 km, denudation rates cannot be higher than 4 mm a-1, and are more likely below 3 mm a-1. At such denudation rates, the intrusion process needs to start at depths of c. 22 km, except when the final laccolith thickness is 10 km, in which case the depth of first-emplaced magmas cannot exceed 18 km. Thick HHL laccoliths (〉7 km) may require a minimum denudation rate, on the order of 1 mm a-1, to prevent wholesale convection and allow muscovite crystallization. Yet, emplacement of such thick HHL laccoliths during normal faulting implies that the top part of the leucogranite nearly reaches the surface while its base is still fed by active intrusions. Overall, such relatively low denudation rates suggest that, when HHL were intruded, the overlying crustal column was not undergoing vigorous erosion. Within the framework of a crustal channel flow, this suggests that the zone of focused erosion during the Miocene was located to the south of the current exposures of the HHL belt. Our results also show that to explain the steep cooling histories documented in many HHL, denudation must have been active after HHL solidification, especially when they were intruded close to their source region. However, to preserve the HHL from exhumation and erosion until the present time, the average denudation rate after emplacement cannot have exceeded 0.5 mm a-1.

Description: We combine field, petrological, geochemical and experimental observations to evaluate the timescales of compaction-driven and shear-assisted melt extraction and ascent in the Himalaya. The results show that melt migration via compaction and channelling is inescapable and operates on timescales of less than 1 million years and possibly as short as 0.1 million years. Field and petrological data show that such a fast and efficient melt transfer results from a combination of favourable factors, including: (1) low but constant melt viscosity (104.5 Pa s) during extraction and ascent; (2) grain size coarsening of the source rocks in response to prolonged heating prior to melting; and (3) high source fertility and thus high melt fraction, owing to elevated modal amounts of muscovite in leucogranite sources. All three factors dramatically increase source permeability. Calculations show that shear-assisted melt extraction had a time interval recurrence in the range 10 000-100 000 years (10-100 ka), leading to sill thicknesses of 1-30 m. Yet melts falling at the low end of the viscosity range when coupled to high shear velocities may lead to veins several hundred metres thick. The deepest structural levels (e.g. central Zanskar Range) show that in-situ melts formed where pure shear compaction was greatest and where simple shear was also operative. Magma extracted from migmatite leucosomes was injected along planes of weakness parallel to the ductile shear fabric, probably by some form of hydraulic fracturing crack propagation mechanism. Large High Himalayan leucogranite (HHL) bodies (e.g. c. 5 km thick sills at Manaslu, Makalu and northern Bhutan) may thus represent inflated laccoliths assembled via dykes that tapped a 100-300 m melt layer produced by compaction of the Greater Himalayan Series (GHS). Thermal simulations show that such melt layers may have incubation times of several million years. Although transport time for magmas associated with the HHL is short, the time for assembly may take several million years for the largest HHL, as geochronological data indicate (up to 5 million years for Manaslu, Shisha Pangma). Transport of leucogranite melt from mid-crustal levels towards the surface was concomitant with active low-angle normal faulting along the South Tibetan Detachment (STD) normal fault, a structure that effectively formed the lid to the extrusion of a partially molten layer of mid-crustal rocks (channel flow). Rapid cooling of the granites emplaced at the top of the GHS implies rapid extrusion and lateral flow of GHS rocks beneath the STD during the period c. 20-17 Ma. Weakening of the crust by partial melting is thus likely to be pulsatory in time, and future thermomechanical models should incorporate such aspects to model tectonic evolution of hot orogens.

Description: Recent phase equilibrium studies, combined with analytical and petrological data, provide rigorous constraints on the pre-eruptive P-T-fH2O-fO2-fS2-fCO2 conditions of silicic to mafic arc magmas. Pre-eruptive melts show a broad negative correlation between temperature and melt H2O contents. Pre-eruptive melt S contents cluster around 100 ppm in residual rhyolitic liquids of silicic to andesitic magmas, and range up to 5000 ppm in more mafic ones. For the entire compositional spectrum, melt sulphur contents are almost independent of prevailing fO2. In contrast, they are positively correlated to fS2, in agreement with experimental observations. Using these intensive constraints, the composition of coexisting fluid phases has been modelled through a MRK equation of state. Pre-eruptive fluids in silicic to andesitic magmas have XH2O (mole fraction of H2O) in the range 0.65-0.95. XH2O decreases as pressure increases, whereas XCO2 increases up to 0.2-0.3. Pre-eruptive fluids in hydrous mafic arc magmas, such as high-alumina basalts, generally have similar mole fractions of H2O and CO2 at mid-crustal levels, with XH2O increasing only for magmas stored at shallow levels in the crust (〈1 kbar). The sulphur content of the fluid phase ranges from 0.12 up to 6.4 wt% in both mafic and silicic magmas. For silicic magmas coexisting with 1-5 wt% fluid, this implies that more than 90% of the melt+fluid mass of sulphur is stored in the fluid. Calculated partition coefficients of S between fluid and melt range from 17 up to 467 in silicic to andesitic magmas, tending to be lower at low fO2, although exceptions to this trend exist. For mafic compositions, the sulphur partition coefficient is constant at around 20. The composition of both melt and coexisting fluid phases under pre-eruptive conditions shows marked differences. For all compositions, pre-eruptive fluids have higher C/S and lower H/C atomic ratios than coexisting melts. Comparison between volcanic gas and pre-eruptive fluid compositions shows good agreement in the high temperature range. However, to reproduce faithfully the compositional field delineated by volcanic gases, silicic to andesitic arc magmas must be fluid-saturated under pre-eruptive conditions, with fluid amounts of at least 1 wt%, whereas mafic compositions require lower amounts of fluid, in the range 0.1-1 wt%. Nevertheless, volcanic gases colder than 700 {degrees}C are generally too H2O-rich and S-poor to have been in equilibrium with silicic to andesitic magmas under pre-eruptive conditions, which suggests that such gases probably contain a substantial contribution from meteoric or hydrothermal water.

Description: Two mafic eruptive products from Vesuvius, a tephrite and a trachybasalt, have been crystallized in the laboratory to constrain the nature of primitive Vesuvius magmas and their crustal evolution. Experiments were performed at high temperatures (from 1000 to ≥1200°C) and both at 0·1 MPa and at high pressures (from 50 to 200 MPa) under H 2 O-bearing fluid-absent and H 2 O- and CO 2 -bearing fluid-present conditions. Experiments started from glass except for a few that started from glass plus San Carlos olivine crystals to force olivine saturation. Melt H 2 O concentrations reached a maximum of 6·0 wt % and experimental f O 2 ranged from NNO – 0·1 to NNO + 3·4 (where NNO is nickel–nickel oxide buffer). Clinopyroxene (Mg# up to 93) is the liquidus phase for the two investigated samples; it is followed by leucite for H 2 O in melt 〈3 wt %, and by phlogopite (Mg# up to 81) for H 2 O in melt 〉3 wt %. Olivine (Fo 85 ) crystallized spontaneously in only one experimental charge. Plagioclase was not found. Upon progressive crystallization of clinopyroxene, glass K 2 O and Al 2 O 3 contents strongly increase whereas MgO, CaO and CaO/Al 2 O 3 decrease; the residual melts follow the evolution of Vesuvius whole-rocks from trachybasalt to tephrite, phonotephrite and to tephriphonolite. Concentrations of H 2 O and CO 2 in near-liquidus 200 MPa glasses and primitive melt inclusions from the literature overlap. The earliest evolutionary stage, corresponding to the crystallization of Fo-rich olivine, was reconstructed by the olivine-added experiments. They show that the primitive Vesuvius melts are trachybasalts (K 2 O ~ 4·5–5·5 wt %, MgO = 8–9 wt %, Mg# = 75–80, CaO/Al 2 O 3 = 0·9–0·95) that crystallize Fo-rich olivine (90–91) as the liquidus phase between 1150 and 1200°C and from 300 to 〈200 MPa. Primitive Vesuvius melts are volatile-rich (1·5–4·5 wt % H 2 O and 600–4500 ppm CO 2 in primitive melt inclusions) and oxidized (from NNO + 0·4 to NNO + 1·2). Assimilation of carbonate wall-rocks by ascending primitive magmas can account for the disappearance of olivine from crystallization sequences and explains the lack of rocks representative of olivine-crystallizing magmas. A correlation between carbonate assimilation and the type of feeding system is proposed: carbonate assimilation is promoted for primitive magma batches of small volumes. In contrast, for longer-lived, large-volume, less frequently recharged, hence more evolved, cooler reservoirs, magma–carbonate interaction is limited. Primitive magmas from Vesuvius and other Campanian volcanoes have similar redox states. However, the Cr# of Vesuvius spinels is distinctive and therefore the peridotitic component in the mantle source of Vesuvius differs from that of the other Campanian magmas.

Description: Santorini volcano in the Aegean region (Greece) is characterized by andesitic- to silicic-dominated explosive activity and caldera-forming eruptions, sourced from magmatic reservoirs located at various structural levels beneath the volcano. There is a good understanding of the silica-rich magmatism of the island whereas the andesite-dominated volcanism and the petrogenesis of the parental mafic magmas are still poorly understood. To fill this gap we have performed crystallization experiments on a representative basalt from Santorini with the aim of determining the conditions of differentiation (pressure, temperature, volatile fugacities) and the parental magma relationship with the andesitic eruptive rocks. Experiments were carried out between 975 and 1040°C, in the pressure range 100–400 MPa, f O 2 from QFM to NNO + 3·5 (where QFM is quartz–fayalite–magnetite and NNO is nickel–nickel oxide), with H 2 O melt contents varying from saturation to nominally dry conditions. The results show that basalt phenocrysts within the basalt crystallized at around 1040°C in a magma storage reservoir located at a depth equivalent to 200–400 MPa pressure, with 3–5 wt % dissolved H 2 O, and f O 2 around QFM. Comparison with the xenocryst and phenocryst assemblages of the Upper Scoria 1 andesite shows that andesitic liquids are produced by fractionation of a similar basalt at 1000°C and 400 MPa, following 60–80 wt % crystallization of an ol + cpx + plag + Ti-mag + opx ± pig–ilm assemblage, with melt water contents around 4–6 wt %. At Santorini, the andesitic low-viscosity and water-rich residual liquids produced at these depths segregate from the parent basaltic mush and feed the shallow magma reservoirs, eventually erupting upon mixing with resident magma. Changes in prevailing oxygen fugacity may control the tholeiitic–calc-alkaline character of Santorini magmas, explaining the compositional and mineralogical differences observed between the recent Thyra and old eruptive products from Akrotiri.

Description: We performed crystallization experiments at 2–3 GPa at 700–950°C on basaltic and pelitic lithologies with added water and sulphur to constrain the factors controlling sulphur behaviour in subduction zones and how it may have varied through geological time. The resulting hydrous silicic melts have up to 20 times more dissolved sulphur (up to 1 wt %) than at 0·2–0·4 GPa, when moderately oxidized conditions prevail. Such high solubilities appear to result from the combined effects of enhanced solubility of water in high-pressure silicate melts (10–20 wt % H 2 O), which acts to decrease silica activity, and oxidizing conditions. The results confirm previous findings that high sulphur contents in silicate melts do not necessarily require iron-rich compositions, suggesting instead that sulphur–water complexes play a fundamental role in sulphur dissolution mechanisms in iron-poor silicic melts, in agreement with recent spectroscopic data. The experimental melts reproduce Phanerozoic slab-derived magmas, in particular their distinct Ca- and Mg-rich composition. The results also show that sulphur increases the degree of melting of basalt lithologies. Hence, we suggest that subducted slabs will preferentially melt where sulphur is present in abundance and that the variability in arc magma sulphur output reflects, in part, the vagaries of sulphur distribution in the slab source. In contrast, comparison with the composition of Archean felsic rocks suggests that, in the early Earth, much less sulphur was present in subducted slabs, in agreement with a number of independent lines of evidence showing that the Archean ocean, hence the hydrothermally altered subducted Archean oceanic crust, was considerably poorer in sulphur than at present. Volcanic degassing of sulphur was thus probably much weaker during the Archean than in Proterozoic–Phanerozoic times.

Description: Phase equilibrium experiments were performed to determine the pre-eruptive conditions of the explosive eruption of Montaña Blanca (2020 bp ) that occurred from a satellite vent located on the east flank of Teide volcano (Tenerife). Crystallization experiments used a phonolitic obsidian from the fall-out deposit as the starting material; this contains 5 wt % anorthoclase, diopside and magnetite with minor amounts of biotite and ilmenite, set in a glassy matrix that contains microlites of Ca-rich alkali feldspar. Temperature was varied between 850 and 800°C, and pressure between 200 and 50 MPa. The oxygen fugacity ( f O 2 ) was varied between NNO + 0·2 (0·2 log units above the Ni–NiO solid buffer) and NNO – 2, and dissolved water contents varied from 7 to 1·5 wt %. Comparison between natural and experimental phase proportions and compositions indicates that the main body of phonolitic magma was stored at 850 ± 15°C, 50 ± 20 MPa, 2·5 ± 0·5 wt % H 2 O at an f O 2 around NNO – 0·5 prior to eruption, equivalent to depths of between 1 and 2 km below the surface. Some clinopyroxene crystals hosting H 2 O-rich melt inclusions possibly originate from an intermittent supply of phonolitic magma stored at somewhat deeper levels (100 MPa). The Ca- and Fe-rich composition of alkali feldspar phenocryst rims and microlites attests to the intrusion of a more mafic magma into the reservoir just prior to eruption; this is evidenced by the appearance of banded pumices in the later products of the eruptive sequence. The comparison with other phonolitic magmas from Tenerife and elsewhere (e.g. Vesuvius, Laacher See) shows that differences in the eruption dynamics of phonolitic magmas can be correlated with differences in magma storage depths, along with variations in pre-eruptive volatile contents.

Description: Peritectic crystals in igneous rocks may be derived from either the source or country rocks, or may have formed by reactive assimilation of source-inherited solids, primary magmatic minerals during self- or magma mixing, or country-rock xenoliths or xenocrysts. Identifying such peritectic crystals is important for constraining the components and textures of igneous rocks and the underlying processes of magmatic evolution. In this study we demonstrate that peritectic olivine formed in melting experiments crystallizes as clusters of euhedral to subhedral crystals. Olivine replacing orthopyroxene, amphibole, and phlogopite forms crystal clusters with distinct crystal to melt ratios, 2D surface area, grain boundary segmentation, and inclusion relations. In our experiments the textures of peritectic crystals are primarily controlled by the stability temperature and decomposition rate of reactive minerals. High-temperature minerals such as orthopyroxene slowly decompose to form high-density clusters of large crystals with long grain boundary segments. The SiO 2 -rich peritectic melt produced favours formation of melt inclusions. Low-temperature minerals such as amphibole and phlogopite rapidly decompose to form low-density clusters of small crystals with short grain boundary segments. The relatively SiO 2 -poor peritectic melt produced results in the formation of fewer melt inclusions. Host melt composition has a minor effect on the textures of peritectic olivine formed in the melting experiments of this study and previous contamination experiments, but affects the assemblages of the peritectic crystal clusters. Cluster density and 2D surface area of peritectic olivine tend to decrease, whereas grain boundary segment length increases with increasing experimental temperature and H 2 O content. Using textural criteria that distinguish olivine formed after different minerals in our melting experiments, we hypothesize that two olivine populations from a basaltic–andesitic lava flow of the Tatara–San Pedro volcanic complex, Chile, may be peritectic crystals formed after amphibole and orthopyroxene. Both amphibole and orthopyroxene are common in xenoliths preserved in some Tatara–San Pedro lava flows. One notable difference between the experimental and natural olivine crystals is that the natural olivine crystals have 2D surface areas and 2D grain boundary segments up to ~1000 and ~100 times larger, respectively, than those produced in our experiments. We propose that this size difference is primarily controlled by comparatively slow heating and decomposition of reactive crystals and textural coarsening of peritectic crystals during prolonged magma residence in the natural system.

Description: Despite claims to the contrary, the compositions of magnetite and ilmenite in the Bishop Tuff correctly record the changing conditions of T and f O 2 in the magma reservoir. In relatively reduced (NNO 〈 1) siliceous magmas (e.g., Bishop Tuff, Taupo units), Ti behaves compatibly (D Ti 2–3.5), leading to a decrease in TiO 2 activity in the melt with cooling and fractionation. In contrast, FeTi-oxides are poorer in TiO 2 in more oxidized magmas (NNO 〉 1, e.g., Fish Canyon Tuff, Pinatubo), and the d ( a TiO 2 )/ dT slope can be negative. Biotite, FeTi-oxides, liquid, and possibly plagioclase largely maintained equilibrium in the Bishop Tuff magma (unlike the pyroxenes, and cores of quartz, sanidine, and zircon) prior to and during a mixing event triggered by a deeper recharge, which, based on elemental diffusion profiles in minerals, took place at least several decades before eruption. Equilibrating phases and pumice compositions show evolving chemical variations that correlate well with mutually consistent temperatures based on the FeTi-oxides, sanidine-plagioclase, and 18 O quartz-magnetite pairs. Early Bishop Tuff (EBT) temperatures are lower (700 to ~780 °C) than temperatures (780 to 〉820 °C) registered in Late Bishop Tuff (LBT), the latter defined here not strictly stratigraphically, but by the presence of orthopyroxene and reverse-zoned rims on quartz and sanidine. The claimed similarity in compositions, Zr-saturation temperatures and thermodynamically calculated temperatures (730–740 °C) between EBT and less evolved LBT reflect the use of glass inclusions in quartz cores in LBT that were inherited from the low-temperature rhyolitic part of the reservoir characteristic of the EBT. LBT temperatures as high as 820 °C, the preservation of orthopyroxene, and the presence of reverse-zoned minerals (quartz, sanidine, zircons) are consistent with magma recharge at the base of the zoned reservoir, heating the cooler rhyolitic melt, partly remelting cumulate mush, and introducing enough CO 2 (0.4–1.4 wt%, mostly contained in the exsolved fluid phase) to significantly lower H 2 O-activity in the system.