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  • 1
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: Fischer, Cornelius; Arvidson, Rolf S; Lüttge, Andreas (2012): How predictable are dissolution rates of crystalline material? Geochimica et Cosmochimica Acta, 98, 177-185, https://doi.org/10.1016/j.gca.2012.09.011
    Publication Date: 2023-05-12
    Description: The large discrepancy between field and laboratory measurements of mineral reaction rates is a long-standing problem in earth sciences, often attributed to factors extrinsic to the mineral itself. Nevertheless, differences in reaction rate are also observed within laboratory measurements, raising the possibility of intrinsic variations as well. Critical insight is available from analysis of the relationship between the reaction rate and its distribution over the mineral surface. This analysis recognizes the fundamental variance of the rate. The resulting anisotropic rate distributions are completely obscured by the common practice of surface area normalization. In a simple experiment using a single crystal and its polycrystalline counterpart, we demonstrate the sensitivity of dissolution rate to grain size, results that undermine the use of "classical" rate constants. Comparison of selected published crystal surface step retreat velocities (Jordan and Rammensee, 1998) as well as large single crystal dissolution data (Busenberg and Plummer, 1986) provide further evidence of this fundamental variability. Our key finding highlights the unsubstantiated use of a single-valued "mean" rate or rate constant as a function of environmental conditions. Reactivity predictions and long-term reservoir stability calculations based on laboratory measurements are thus not directly applicable to natural settings without a probabilistic approach. Such a probabilistic approach must incorporate both the variation of surface energy as a general range (intrinsic variation) as well as constraints to this variation owing to the heterogeneity of complex material (e.g., density of domain borders). We suggest the introduction of surface energy spectra (or the resulting rate spectra) containing information about the probability of existing rate ranges and the critical modes of surface energy.
    Keywords: Calcite dissolution rate; Center for Marine Environmental Sciences; Experiment_single_calcite_crystal; Frequency; MARUM; Surface height; Vertical scanning interferometer (VSI), Zemetrics ZeMapper (Tucson AZ)
    Type: Dataset
    Format: text/tab-separated-values, 6744 data points
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  • 2
    Publication Date: 2024-01-09
    Keywords: 136-842A; Amorphous phase; Augite; Calcite; Clay minerals; Clinoptilolite; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Joides Resolution; Leg136; North Pacific Ocean; Ocean Drilling Program; ODP; Opal-CT; Phillipsite; Plagioclase; Quartz; Sample code/label; X-ray diffraction (XRD)
    Type: Dataset
    Format: text/tab-separated-values, 70 data points
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  • 3
    Publication Date: 2024-01-09
    Keywords: 136-842A; 136-842B; Amorphous phase; Clinoptilolite; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Illite; Joides Resolution; Kaolinite+Chlorite; Leg136; North Pacific Ocean; Ocean Drilling Program; ODP; Phillipsite; Plagioclase; Quartz; Sample code/label; Smectite; X-ray diffraction TEXTUR, clay fraction
    Type: Dataset
    Format: text/tab-separated-values, 234 data points
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  • 4
    Publication Date: 2024-01-09
    Keywords: 136-842A; 136-842C; 136-843A; Amorphous phase; Augite; Calcite; Clay minerals; Clinoptilolite; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Joides Resolution; Leg136; North Pacific Ocean; Ocean Drilling Program; ODP; Opal-CT; Phillipsite; Plagioclase; Quartz; Sample code/label; X-ray diffraction (XRD)
    Type: Dataset
    Format: text/tab-separated-values, 670 data points
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  • 5
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: Tribble, Jane S; Wilkens, Roy H; Arvidson, Rolf S; Busing, Christopher J (1993): Sediments of the Hawaiian Arch: X-ray mineralogy and microfabric. In: Wilkens, RH; Firth, J; Bender, J; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 136, 65-76, https://doi.org/10.2973/odp.proc.sr.136.205.1993
    Publication Date: 2024-01-09
    Description: The mineralogy of both bulk- and clay-sized (〈2 µm) fractions of sediments from Holes 842A and 842B of Ocean Drilling Program Leg 136 was determined by X-ray diffraction. The sediments consist of a combination of terrigenous (quartz, plagioclase, smectite, illite, kaolinite, and chlorite), volcaniclastic (augite, plagioclase, and volcanic glass), and diagenetic minerals (smectite, phillipsite, clinoptilolite, and opal-CT). Although biogenic silica (radiolarians and diatoms) is common in near-seafloor (〈10 mbsf) sediments, biogenic calcite is rare. Variations with depth in abundances of the terrigenous minerals reflect temporal changes in the flux of eolian material to the site. Volcanogenic material derived from the Hawaiian Islands is present in lithologic Unit 1 (0-19.9 meters below seafloor) both as discrete layers and as finely disseminated silt- and clay-sized material. Volcanic glass is present only in the upper 10 m of the sediment column. In Unit 2 (19.9-35.7 mbsf), increased smectite and zeolite abundances with depth as well as indurated, zeolite-rich layers are thought to be the alteration products of volcanogenic material. The source of this older (late Oligocene to middle Miocene) volcanogenic detritus may be continental volcanism. Microfabrics imaged using back-scattered electron imaging reflect the effects of compaction and diagenesis on sediment porosity and matrix structure. As porosity decreases during burial, the matrix changes from an open, floc-like fabric, to an interlocking network of clay mineral domains, and finally to a dense intergrowth of clay minerals and zeolites. Despite the substantial changes in sediment microfabric and mineralogy, correlations between physical and acoustic properties and mineralogy are weak or absent. The sediment has maintained high porosity (〉70%), and water content appears to dominate the sediment's physical character and acoustic response.
    Keywords: Ocean Drilling Program; ODP
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 72 (1968), S. 845-855 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 31 (1966), S. 887-891 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 35 (1970), S. 1010-1015 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 149-151 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Amorphous silicon–carbon based thin films deposited in a microwave plasma reactor using organosilane vapors from liquid sources show efficient photoluminescence (several %) when excited with ultraviolet (UV) light together with a low absorptivity (down to 1 cm−1 at the long-wavelength side) in the spectral range of the luminescence emission (400–550 nm). On the basis of these films we have prepared luminescent waveguiding layer structures which we propose for an application as a fast, sensitive, and selective UV detector integrated on silicon. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 35 (1970), S. 1004-1009 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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