ISSN:
1572-879X
Keywords:
Radical cations
;
HM zeolite
;
C-C bond formation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The radical cation of 2,5-dimethyl-2,4-hexadiene is identified by ESR upon adsorption of the parent molecule on activated H-mordenite. The same radical is observed when 2,3-dimethyl-1-butene or 2-methylpropene is adsorbed. This is clear evidence for highly specific dimerisation-fragmentation reactions of the primary radical cations in the zeolite at room temperature.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00769675
Permalink