ISSN:
1476-4687
Source:
Nature Archives 1869 - 2009
Topics:
Biology
,
Chemistry and Pharmacology
,
Medicine
,
Natural Sciences in General
,
Physics
Notes:
[Auszug] Oxocarbonium ion intermediates such as I (Fig. 1) and the glycosyl cation have lifetimes in water in the order of 105-1012 s (refs 3, 4). In the acid-catalysed hydrolysis of enol ether 1, the rate-determining step with the transition state of highest energy is ...
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1038/374143a0
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