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  • 1
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 83 (1994), S. 502-513 
    ISSN: 1437-3262
    Keywords: Eastern Desert ; Egypt ; Granitoid gneisses ; Single zircon dating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Strongly deformed and locally migmatized gneisses occur at several places in the southern Eastern Desert of Egypt and in Sinai and have variously been interpreted as a basement to Pan-african (≈900 to 600 Ma) supracrustal and intrusive assemblages. A suite of grabbroic to granitic gneisses was investigated in the Hafafit area, which constitutes an I-type calc-alkaline intrusive assemblage whose chemistry suggests emplacement along an active continental margin and whose granitoid members can be correlated with the so-called ‘Older Granites’ of Egypt.207Pb/206Pb single zircon evaporation from three samples of the Hafafit gneisses yielded protolith emplacement ages between 677 ± 9 and 700 ± 12 Ma and document granitoid activity over a period of about 23 Ma. A migmatitic granitic gneiss from Wadi Bitan, south-west of Ras Banas, has a zircon age of 704 ± 8 Ma, and its protolith was apparently generated during the same intrusive event as the granitoids at Hafafit. Single zircons from a dioritic gneiss from Wadi Feiran in south-west Sinai suggest emplacement of the protolith at 796 ± 6 Ma and this is comparable with ages for granitoids in north-east Sinai and southern Israel. None of the above gneisses is derived from remelting of older continental crust, but they are interpreted as reflecting subduction-related calc-alkaline magmatism during early Pan-african magmatic arc formation.
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  • 3
    ISSN: 1437-3262
    Keywords: Arabian-Nubian Shield ; Egypt ; Pan-African orogeny ; Proterozoic ; Extensional collapse ; Thrust tectonics ; Transpression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Detailed structural geological and related studies were carried out in a number of critical areas in the Proterozoic basement of eastern Egypt to resolve the structural pattern at a regional scale and to assess the general characteristics of tectonic evolution, orogeny and terrane boundaries. Following a brief account of the tectonostratigraphy and timing of the orogenic evolution, the major structural characteristics of the critical areas are presented. Collisional deformation of the terranes ended about 615-600 Ma ago. Subsequent extensional collapse probably occurred within a relatively narrow time span of about 20 Ma (575 – 595 Ma ago) over the Eastern Desert and was followed by a further period of about 50 Ma of late to post-tectonic activity. The regional structures originated mainly during post-collisional events, starting with those related to extensional collapse (molasse basin formation, normal faulting, generation of metamorphic core complexes). Subsequent NNW-SSE shortening is documented by large-scale thrusting (towards the NNW) and folding, distributed over the Eastern Desert, although with variable intensity. Thrusts are overprinted by transpression, which was localized to particular shear zones. Early transpression produced, for example, the Allaqi shear zone and final transpression is documented in the Najd and Wadi Kharit-Wadi Hodein zones. Two terrane boundaries can be defined, the Allaqi and South Hafafit Sutures, which are apparently linked by the high angle sinistral strike-slip Wadi Kharit-Wadi Hodein shear zone with a tectonic transport of about 300 km towards the W/NW. In general, the tectonic evolution shows that extensional collapse is not necessarily the final stage of orogeny, but may be followed by further compressional and transpressional tectonism. The late Pan-African high angle faults were reactivated during Red Sea tectonics both as Riedel shears and normal faults, where they were oriented favourably with respect to the actual stress regime.
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Food Chemistry 30 (1988), S. 167-180 
    ISSN: 0308-8146
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 80 (1991), S. 155-170 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract The late Precambrian Shadli Metavolcanics of SE Egypt constitute a slightly metamorphosed bimodal sequence that has been previously interpreted as manifesting volcanic activity at an island arc. We report the first Rb-Sr geochronologic, trace element (including REE), and Nd isotopic data for these rocks. Two types of basalt are recognized, the stratigraphically lower suite having compositions like N-MORB ferrobasalt while the overlying basalt is similar to slightly fractionated E-MORB. The two basalt types were derived from melting of a strongly depleted source, most likely within the upper 60–75 km of the upper mantle. The origin of the felsic melts is problematic, and these could either have fractionated from a mafic melt or resulted from melting of juvenile crust. The mafic and felsic lavas yield a Rb-Sr isochron age of 712±24 Ma that probably represents the time of volcanic eruption. The trace element characteristics of both mafic and felsic members of the Shadli Metavolcanics show few of the hallmarks of subduction-related melts, and we reject the hypothesis that these formed at an island arc. Instead, the field and geochemical data are most consistent with the hypothesis that these rocks originated in a magmatic rift, where the eruption of large volumes of lava accompanied large-scale lithospheric extension. This inference suggests that the tectonic setting of the important 700–715 Ma crust-forming event in NE Africa and Arabia needs to be critically reexamined.
    Abstract: Résumé Les roches volcaniques faiblement métamorphisées du Précambrien tardif de Shadli dans le Sud-Est de l'Egypte se caractérisent par une séquence bimodale qui était jusqu'ici interprétée comme résultant d'un volcanisme d'arc insulaire. Nous présentons ici les premières données isotopiques (Rb-Sr, Nd) obtenues pour ces roches ainsi que des données d'éléments en trace (y compris les Terres Rares). Deux types principaux de basaltes peuvent être distingués: les basaltes qui se trouvent dans la partie inférieure de la colonne stratigraphique, ont une composition comparable aux ferrobasaltes de type N-MORB, tandis que les roches se trouvant dans la partie supérieure de la séquence s'apparentent plutôt aux E-MORB légèrement fractionnés. Les deux types de basalte proviennent de la fusion partielle d'un manteau fortement appauvri, et ce à une profondeur probable de 60 à 75 km dans le manteau supérieur. L'origine des laves acides pose, quant à elle, quelques problèmes: elles peuvent s'être formées par cristallisation fractionnée à partir d'un liquide basique, ou alors elles sont le produit de la fusion partielle d'une croûte juvénile. La combinaison des données Rb-Sr obtenues pour les roches acides et basiques permet l'obtention d'une isochrone définissant un âge de 712 ± 24 Ma. Cet âge est interprété comme datant les éruptions volcaniques. Les données d'éléments en traces obtenues pour les laves basiques et acides ne présentent aucune des caractéristiques associées au volcanisme d'arc insulaire. Par conséquent, nous rejetons l'hypothèse selon laquelle les roches volcaniques de Shadli se seraient formées dans un contexte d'arc insulaire. Les données géochimiques et de terrain seraient plutôt en accord avec une hypothèse selon laquelle les roches volcaniques métamorphiques de Shadli se seraient formées dans une zone de rift où de très volumineux épanchements de laves auraient succédé à une extension à grande échelle de la lithosphère. Cette interprétation des données nous conduit à suggérer un réexamen critique du contexte tectonique entourant la période de formation crustale se situant entre 700 a 715 Ma, dans le nord-est de l'Afrique ainsi qu'en Arabie.
    Notes: Zusammenfassung Die spätpräkambrischen Shadli-Metavulkanite in der südöstlichen Eastern Desert von Ägypten sind eine schwach metamorphe bimodale Basalt-Rhyodazit-Abfolge, die bisher als Ausdruck eines Inselbogen-Vulkanismus gedeutet wurde. Zwei Basalt-Typen können aufgrund ihrer unterschiedlichen chemischen Zusammensetzung unterschieden werden: der stratigraphisch untere Typ ist ein N-MORB ähnlicher Ferrobasalt, während der überlagernde Typ Charakteristika eines leicht fraktionierten E-MORB aufweist. Die beiden Basaltvarietäten werden von stark an inkompatiblen Elementen verarmten Schmelzen aus den oberen 60–75 km des Mantels abgeleitet. Die Entstehung der sauren Metavulkanite ist nicht eindeutig geklärt; sowohl Fraktionierung aus einer mafischen Schmelze als auch Aufschmelzung juveniler Kruste vom Inselbogen-Typ sind denkbar. Die mafischen und felsischen Gesteine definieren zusammen ein Rb-Sr-Isochronenalter von 712 ± 24 Ma, das wir als den Zeitraum der Eruption deuten. Die Spurenelement-Verteilung der Shadli-Metavulkanite weist keine der charakteristischen Merkmale von Subduktionsmagmatismus auf, und wir sehen daher keinen direkten Zusammenhang mit einer Inselbogen-Entwicklung. Wir interpretieren den Shadli-Vulkanismus als Resultat eines Riftprozesses in junger kontinentaler Kruste, ähnlich dem Rio Grande-Rift oder dem Afar-Dreieck, wo starke Lithosphärendehnung die Förderung großer Lavamengen ermöglichte. Diese Interpretation stellt das einfache Schema einer panafrikanischen Krustenbildung durch Inselbogen-Addition im arabisch-nubischen Schild in Frage und erfordert eine Neubewertung bisheriger Modellvorstellungen.
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  • 6
    ISSN: 1437-3262
    Keywords: Arabian-Nubian Shield ; Egypt ; Pan-African orogeny ; Proterozoic ; Extensional collapse ; Thrust tectonics ; Transpression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Detailed structural geological and related studies were carried out in a number of critical areas in the Proterozoic basement of eastern Egypt to resolve the structural pattern at a regional scale and to assess the general characteristics of tectonic evolution, orogeny and terrane boundaries. Following a brief account of the tectonostratigraphy and timing of the orogenic evolution, the major structural characteristics of the critical areas are presented. Collisional deformation of the terranes ended about 615-600 Ma ago. Subsequent extensional collapse probably occurred within a relatively narrow time span of about 20 Ma (575 – 595 Ma ago) over the Eastern Desert and was followed by a further period of about 50 Ma of late to post-tectonic activity. The regional structures originated mainly during post-collisional events, starting with those related to extensional collapse (molasse basin formation, normal faulting, generation of metamorphic core complexes). Subsequent NNW-SSE shortening is documented by large-scale thrusting (towards the NNW) and folding, distributed over the Eastern Desert, although with variable intensity. Thrusts are overprinted by transpression, which was localized to particular shear zones. Early transpression produced, for example, the Allaqi shear zone and final transpression is documented in the Najd and Wadi Kharit-Wadi Hodein zones. Two terrane boundaries can be defined, the Allaqi and South Hafafit Sutures, which are apparently linked by the high angle sinistral strike-slip Wadi Kharit-Wadi Hodein shear zone with a tectonic transport of about 300 km towards the W/NW. In general, the tectonic evolution shows that extensional collapse is not necessarily the final stage of orogeny, but may be followed by further compressional and transpressional tectonism. The late Pan-African high angle faults were reactivated during Red Sea tectonics both as Riedel shears and normal faults, where they were oriented favourably with respect to the actual stress regime.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 83 (1994), S. 502-513 
    ISSN: 1437-3262
    Keywords: Eastern Desert ; Egypt ; Granitoid gneisses ; Single zircon dating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Strongly deformed and locally migmatized gneisses occur at several places in the southern Eastern Desert of Egypt and in Sinai and have variously been interpreted as a basement to Pan-african (≈900 to 600 Ma) supracrustal and intrusive assemblages. A suite of grabbroic to granitic gneisses was investigated in the Hafafit area, which constitutes an I-type calc-alkaline intrusive assemblage whose chemistry suggests emplacement along an active continental margin and whose granitoid members can be correlated with the so-called ‘Older Granites’ of Egypt. 207Pb/206Pb single zircon evaporation from three samples of the Hafafit gneisses yielded protolith emplacement ages between 677 ± 9 and 700 ± 12 Ma and document granitoid activity over a period of about 23 Ma. A migmatitic granitic gneiss from Wadi Bitan, south-west of Ras Banas, has a zircon age of 704 ± 8 Ma, and its protolith was apparently generated during the same intrusive event as the granitoids at Hafafit. Single zircons from a dioritic gneiss from Wadi Feiran in south-west Sinai suggest emplacement of the protolith at 796 ± 6 Ma and this is comparable with ages for granitoids in north-east Sinai and southern Israel. None of the above gneisses is derived from remelting of older continental crust, but they are interpreted as reflecting subduction-related calc-alkaline magmatism during early Pan-african magmatic arc formation.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 43 (1992), S. 63-68 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zerstörung der Passivität von Cadmium in alkalischer LösungDas elektrochemische Verhalten einer Cd-Anode wurde in 0,05 bis 2 M NaOH potentiodynamisch untersucht. Die Polarisationskurven zeigen vor der Sauerstoffentwicklung Aktiv-Passiv-Übergang. Das Schwellenpotential der aktiven Auflösung liegt sehr nahe am reversiblen Potential des Systems Cd/Cd(OH)2. Röntgenbeugung und XPS-Analyse zeigen, daß die Passivschicht aus sowohl CdO als auch Cd(OH)2 besteht. Der Einfluß steigender Mengen von Chlor-, Brom- und Jodionen auf das anodische Verhalten von Cd in NaOH wurde untersucht. Die Halidionen stimulieren danach die anodische Auflösung im aktiven Bereich und durchbrechen die Passivschicht im passiven Bereich, so daß Lochkorrosion auftritt. Das Lochkorrosionspotential verschiebt sich mit zunehmender Halidionekonzentration nach negativeren. mit zunehmender Alkalikonzentration jedoch nach positiveren Werten.
    Notes: The electrochemical behaviour of a Cd anode was investigated in 0.05-2 M NaOH solutions by the potentiodynamic technique. The polarization curves exhibit active to passive transition prior to oxygen evolution. The threshold potential of the active dissolution is very close to the reversible potential of the system Cd/Cd(OH)2. X-Ray diffraction and XPS measurements reveal that the passive layer is composed of both Cd(OH)2 and CdO. The influence of increasing amounts of Cl-, Br- or I- ions on the anodic behaviour of Cd in NaOH solution has been investigated. The halides stimulate the anodic dissolution in the active region and tend to break-down the passive layer in the passive region, leading to pitting attack. The pitting potential shifts to more negative values with increasing halide ion concentration but to the reverse direction with increasing alkali concentration.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 243-250 
    ISSN: 0009-2940
    Keywords: Cyanide complexes, organometallic, polynuclear / Redox chemistry / Ruthenium clusters ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Redox Chemistry, Dinuclear Complexes, and Ru3,-Cluster Derivatives of the “Ligand” [Cp(CO)2Mn - CN]-By means of the compounds Na[Cp(CO)2MnCN] (1a, b) the abilities of the cyanide ion to link different organometallic units and to stabilize unusual electron counts in organometallic complexes were tested. The dinuclear complexes [Cp(CO)2Mn-CN-M]- [form M = MnCp(CO)2 and W(CO)5 as PPN salts 2a, 3a] as well as Cp(CO)2Mn-Cn-M [for M = MoCp(CO)3 and NiCpPPh3, 4a, 5a] were obtained in a pure state. From the reactions with Ru3(CO)12 the cluster derivatives HRu3(CO)10[μ-NC-Mn(CO)2Cp] (6a, b) and Ru3(CO)10[μ-NC-Mn(CO)2Cp]2 (7b) were characterized. One-electron transfers were investigated for the starting complex and for the two anionic dinuclear complexes 2a, 3a. Crystal structures were determined of the dinuclear Mn-CN-Mn compex 2a and of the two cluster derivatives 2b, 7b.
    Additional Material: 5 Ill.
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  • 10
    Publication Date: 2019-07-31
    Print ISSN: 0944-1344
    Electronic ISSN: 1614-7499
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Springer
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