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  • 1
    Publication Date: 2020-07-08
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
    Publication Date: 2022-05-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124, (2019): 9141-9170, doi: 10.1029/2019JC015210.
    Description: The observational network around the North Atlantic has improved significantly over the last few decades with subsurface profiling floats and satellite observations and the recent efforts to monitor the Atlantic Meridional Overturning Circulation (AMOC). These have shown decadal time scale changes across the North Atlantic including in heat content, heat transport, and the circulation. However, there are still significant gaps in the observational coverage. Ocean reanalyses integrate the observations with a dynamically consistent ocean model and can be used to understand the observed changes. However, the ability of the reanalyses to represent the dynamics must also be assessed. We use an ensemble of global ocean reanalyses to examine the time mean state and interannual‐decadal variability of the North Atlantic ocean since 1993. We assess how well the reanalyses are able to capture processes and whether any understanding can be gained. In particular, we examine aspects of the circulation including convection, AMOC and gyre strengths, and transports. We find that reanalyses show some consistency, in particular showing a weakening of the subpolar gyre and AMOC at 50°N from the mid‐1990s until at least 2009 (related to decadal variability in previous studies), a strengthening and then weakening of the AMOC at 26.5°N since 2000, and impacts of circulation changes on transports. These results agree with model studies and the AMOC observations at 26.5°N since 2005. We also see less spread across the ensemble in AMOC strength and mixed layer depth, suggesting improvements as the observational coverage has improved.
    Description: This work was initiated through the EU COST‐EOS‐1402 project which supported the development of this paper by funding project meetings, both in person and virtual. We would like to thank Aida Azcarate for organizing the funding for the meetings and would like to thank Martha Buckley, Gokhan Danabasoglu, and Simon Josey for useful discussions. Jackson, Storto and Zuo were partially funded, by the Copernicus Marine Environment Monitoring Service (CMEMS: 23‐GLO‐RAN) and Zuo was partially funded by the Copernicus Climate Change Service. Jackson was also partially funded by the joint UK BEIS/Defra Met Office Hadley Centre Climate Programme (GA01101). Haines and Robson acknowledge funding under the NERC RAPID projects RAMOC and DYNAMOC (NE/M005127/1) respectively, and Robson also acknowledges funding from the ACSIS project. Mignac was supported for PhD scholarship by the CAPES Foundation, Ministry of Education of Brazil (Proc. BEX 1386/15‐8). Forget acknowledges support from the Simons Foundation (549931) and the NASA IDS program (6937342). Work by Piecuch was carried out under the ECCO project, funded by the NASA Physical Oceanography, Cryospheric Science, and Modeling, Analysis and Prediction programs, and supported by the Independent Research and Development Program at Woods Hole Oceanographic Institution. Wilson was funded by the NERC UK‐OSNAP project (NE/K010875.1) as part of the international OSNAP program. NorCPM‐v1 reanalysis was cofunded by the Center for Climate Dynamics at the Bjerknes Center, the Norwegian Research Council under the EPOCASA (229774/E10) and SFE (270733) research projects, the NordForsk under the Nordic Centre of Excellence (ARCPATH, 76654), and the Trond Mohn Foundation under the project BFS2018TMT01. NorCPM‐v1 reanalysis received a grant for computer time from the Norwegian Program for supercomputer (NOTUR2, project NN9039K) and a storage grant (NORSTORE, NS9039K). Data for the figures are available to download (from https://doi.org/10.5281/zenodo.2598509). Data from some reanalysis products are available to download (from http://marine.copernicus.eu/services-portfolio/access-to-products/) under product names GLOBAL_REANALYSIS_PHY_001_025 (GLORYS2v4), GLOBAL_REANALYSIS_PHY_001_026 (C‐GLORSv7, GLORYS2v4, GloSea5 and ORAS5) and GLOBAL_REANALYSIS_PHY_001_030 (GLORYS12V1).
    Description: 2020-05-06
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-06-20
    Description: Accurate knowledge of the location and magnitude of ocean heat content (OHC) variability and change is essential for understanding the processes that govern decadal variations in surface temperature, quantifying changes in the planetary energy budget, and developing constraints on the transient climate response to external forcings. We present an overview of the temporal and spatial characteristics of OHC variability and change as represented by an ensemble of dynamical and statistical ocean reanalyses (ORAs). Spatial maps of the 0–300 m layer show large regions of the Pacific and Indian Oceans where the interannual variability of the ensemble mean exceeds ensemble spread, indicating that OHC variations are well-constrained by the available observations over the period 1993–2009. At deeper levels, the ORAs are less well-constrained by observations with the largest differences across the ensemble mostly associated with areas of high eddy kinetic energy, such as the Southern Ocean and boundary current regions. Spatial patterns of OHC change for the period 1997–2009 show good agreement in the upper 300 m and are characterized by a strong dipole pattern in the Pacific Ocean. There is less agreement in the patterns of change at deeper levels, potentially linked to differences in the representation of ocean dynamics, such as water mass formation processes. However, the Atlantic and Southern Oceans are regions in which many ORAs show widespread warming below 700 m over the period 1997–2009. Annual time series of global and hemispheric OHC change for 0–700 m show the largest spread for the data sparse Southern Hemisphere and a number of ORAs seem to be subject to large initialization ‘shock’ over the first few years. In agreement with previous studies, a number of ORAs exhibit enhanced ocean heat uptake below 300 and 700 m during the mid-1990s or early 2000s. The ORA ensemble mean (±1 standard deviation) of rolling 5-year trends in full-depth OHC shows a relatively steady heat uptake of approximately 0.9 ± 0.8 W m−2 (expressed relative to Earth’s surface area) between 1995 and 2002, which reduces to about 0.2 ± 0.6 W m−2 between 2004 and 2006, in qualitative agreement with recent analysis of Earth’s energy imbalance. There is a marked reduction in the ensemble spread of OHC trends below 300 m as the Argo profiling float observations become available in the early 2000s. In general, we suggest that ORAs should be treated with caution when employed to understand past ocean warming trends—especially when considering the deeper ocean where there is little in the way of observational constraints. The current work emphasizes the need to better observe the deep ocean, both for providing observational constraints for future ocean state estimation efforts and also to develop improved models and data assimilation methods.
    Description: Published
    Description: 909–930
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2022-06-20
    Description: Uncertainty in ocean analysis methods and deficiencies in the observing system are major obstacles for the reliable reconstruction of the past ocean climate. The variety of existing ocean reanalyses is exploited in a multi-reanalysis ensemble to improve the ocean state estimation and to gauge uncertainty levels. The ensemble-based analysis of signal-to-noise ratio allows the identification of ocean characteristics for which the estimation is robust (such as tropical mixed-layer-depth,upper ocean heat content), and where large uncertainty exists (deep ocean, Southern Ocean, sea-ice thickness, salinity), providing guidance for future enhancement of the observing and data assimilation systems.
    Description: This work has been partially funded by the European Commission funded projects MyOcean, MyOcean2 and COMBINE; by the GEMINA project-funded bythe Italian Ministry for Environment; by the NERC-funded VALOR project; by the NERC-funded NCEO program; by the Research Program on Climate Change adaptation of the Ministry of Education, Culture, Sports, Science and Technology of the Japanese government; by the Joint UK DECC/Defra Met Office Hadley Centre Climate Programme (GA01101); by NASA’s Modeling Analysis and Prediction Program under WBS 802678.02.17.01.25 and by the NASA Physical Oceanography Program; by the NOAA's Climate Observation Division (COD); by the LEFE/GMMC French national program.
    Description: Published
    Description: s80-s97
    Description: 4A. Clima e Oceani
    Description: JCR Journal
    Description: open
    Keywords: Global ocean–sea-ice modelling ; Ocean model comparisons ; DATA ASSIMILATION SCHEME ; multi-analysis ensemble ; Ocean climate ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 22 (1989), S. 874-879 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 106-117 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The structure of the gas-phase trimeric complex H2O–H2O–CO2 is determined through an analysis of the rotational spectra of ten isotopically substituted species. These spectra were measured in the region between 7.5 and 18 GHz using a pulsed-molecular-beam Fourier-transform microwave spectrometer. The nondeuterated species display two sets of transitions separated by ∼1 MHz. The splittings of the perdeuterated form are smaller and three partially deuterated forms have no splittings. The rotational constants for the lower frequency set of transitions of the normal species are A=6163.571(4) MHz, B=2226.157(2) MHz, C=1638.972(1) MHz, δJ=0.000 83(3) MHz, ΔJ=0.002 98(4) MHz, ΔJK=−0.0005(2) MHz. The differences in the rotational constants between the upper and lower states are ΔA=498 kHz, ΔB=520 kHz, and ΔC=−133 kHz. The dipole moments are μa=1.571(5) D and μb=0.761(4) D with μc=0 D. The dipole moments and the intertial defect of −0.620 uA(ring)2 both indicate an essentially planar complex. The structure is found to be cyclical with the dimer-type bond lengths within the trimer being approximately the same as those found in the free heterodimers. One water molecule is oxygen bound to the carbon atom of the CO2 and is also hydrogen bonded to the oxygen of the second water molecule. The second water molecule is in turn hydrogen bonded to one of the oxygens of the CO2 molecule. The observed splittings are most likely due to a hydrogen-exchanging internal rotation of this second water molecule.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 7095-7109 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Rotational transitions between J≤3 levels within the K=0 manifold have been observed for H2O–CO, HDO–CO, D2O–CO, H2O–13CO, HDO–13CO, and H217O–CO using the molecular beam electric resonance and Fourier transform microwave absorption techniques. ΔMJ=0→1 transitions within the J=1 level were also measured at high electric fields. A tunneling motion which exchanges the equivalent hydrogens gives rise to two states in the H2O and D2O complexes. The spectroscopic parameters for H2O–CO in the spatially symmetric tunneling state are [∼(B0) =2749.130(2)MHz, D0=20.9(2)kHz, and μa=1.055 32(2)D] and in the spatially antisymmetric state are [∼(B0) =2750.508(1)MHz, D0=20.5(1)kHz, and μa=1.033 07(1)D]. Hyperfine structure is resolved for all isotopes. The equilibrium structure of the complex has the heavy atoms approximately collinear. The water is hydrogen bonded to the carbon of CO; however the bond is nonlinear. At equilibrium, the O–H bond of water makes an angle of 11.5° with the a axis of the complex; the C2v axis of water is 64° from the a axis of the complex. The hydrogen bond length is about 2.41 A(ring). The barrier to exchange of the bound and free hydrogens is determined as 210(20) cm−1 (600 cal/mol) from the dipole moment differences between the symmetric and antisymmetric states. The tunneling proceeds through a saddle point, with C2v structure, with the hydrogen directed towards the CO subunit. The equilibrium tilt away from a linear hydrogen bond is in the direction opposite to the tunneling path.
    Type of Medium: Electronic Resource
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