ISSN:
1572-879X
Keywords:
oscillation
;
CO + H2 cooxidation
;
chemical sensor
;
pellistor
;
platinum
;
platinum/alumina
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Oscillation behaviour of the oxidation of CO (0.2–2.2%) in air over Pt wire coils and over Pt/Al2O3 catalysts deposited onto the coils (pellistors) has been investigated. The waveforms differ considerably between the two catalytic systems. Over unsupported Pt at 240–260° C, regular oscillations were accompanied by slowly declining activity and by deposition of carbon. Over supported Pt at 110–180°C, relatively complex but sustained oscillation occurred by a different mechanism. This oscillation was greatly enhanced by H2 (0.25–1.0%), and may involve fluctuations in the concentrations of CO and H2 around the supported catalyst.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00806880
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