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  • 1
    ISSN: 1573-0417
    Keywords: carbon cycling ; climate change ; organic matter ; peat ; peatland ; Sphagnum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Using210Pb-dating of peat cores, corroborated by pollen and acid-insoluble ash approaches, rates of vertical height growth, dry mass accumulation, and organic matter accumulation were determined for fiveSphagnum-dominated peatland sites (one in Minnesota, one in Pennsylvania, one on the Maryland/West Virginia border, two in West Virginia), spanning a mean annual temperature range of 4.5 °C and differing in total annual precipitation by a factor of almost 2. Site differences in rates of vertical height growth and dry mass accumulation were documented, but both within-core and between-site differences in bulk density and ash concentrations of peat confound efforts to relate vertical height growth and dry mass accumulation to net organic matter accumulation. Taking bulk densities and ash concentrations into account, rates of net organic matter accumulation over the past 150–200 years were strikingly similar at four of the five sites, an unexpected result given the general trend that with decreasing latitude, peat deposits become older, thinner, and more highly decomposed. More comprehensive studies are needed in which net organic matter accumulation is determined at several locations within a single peatland, at several peatlands within a particular geographic/climatic region, and at peatland sites in different geographic/climatic regions. If additional studies confirm that recent (past 200 years) net organic matter accumulation is relatively insensitive to broad-scale regional climatic differences, boreal and subarctic peatlands may continue to function as a net sink for atmospheric CO2 and a net source of atmospheric CH4 with no change in rates of net organic matter accumulation, even under predicted scenarios of global climate change.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 45 (1999), S. 35-52 
    ISSN: 1573-515X
    Keywords: Sphagnum-peat ; 210Pb-dating ; Pb-mobility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract One important assumption in applying210Pb-dating is that atmospherically deposited Pb is immobilized in the peat or sediment column. This assumption has been challenged widely, but has never been evaluated experimentally. We evaluated Pb mobility and the chemical forms in which Pb is stabilized in peat profiles by adding either soluble or particulate Pb to intact peat cores that were maintained under different water level regimes (permanently high, permanently low, fluctuating between high and low) and were subjected to simulated precipitation over a five month period. By analyzing the behavior of stable Pb we made inferences about the expected behavior of210Pb. Results indicate that added soluble Pb2+ was retained in the peat through physiochemical binding to organic matter, and as such Pb2+ was largely immobile in peat even under conditions of a fluctuating water table. Added particulate Pb was largely (most likely by physical entrapment), but not completely, immobilized in peat. In none of the water table treatments was there evidence to support mobility of Pb by alternating formation and oxidation of Sulfides, or by any other mechanism. The binding of Pb2+ with organic matter at the peat surface, and the absence of Pb mobility lend credence to210Pb-dating ofSphagnum-dominated peat deposits, which are over 90% organic matter throughout, and have high cation exchange capacities.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 45 (1999), S. 35-52 
    ISSN: 1573-515X
    Keywords: Sphagnum-peat ; 210Pb-dating ; Pb-mobility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract One important assumption in applying 210Pb-dating is that atmospherically deposited 210Pb is immobilized in the peat or sediment column. This assumption has been challenged widely, but has never been evaluated experimentally. We evaluated Pb mobility and the chemical forms in which Pb is stabilized in peat profiles by adding either soluble or particulate Pb to intact peat cores that were maintained under different water level regimes (permanently high, permanently low, fluctuating between high and low) and were subjected to simulated precipitation over a five month period. By analyzing the behavior of stable Pb we made inferences about the expected behavior of 210Pb. Results indicate that added soluble Pb2+ was retained in the peat through physiochemical binding to organic matter, and as such Pb2+ was largely immobile in peat even under conditions of a fluctuating water table. Added particulate Pb was largely (most likely by physical entrapment), but not completely, immobilized in peat. In none of the water table treatments was there evidence to support mobility of Pb by alternating formation and oxidation of sulfides, or by any other mechanism. The binding of Pb2+ with organic matter at the peat surface, and the absence of Pb mobility lend credence to 210Pb-dating of Sphagnum-dominated peat deposits, which are over 90% organic matter throughout, and have high cation exchange capacities.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 79 (1995), S. vii 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 79 (1995), S. ix 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Lead-210 dating of peat cores is one approach that has been used to arrive at historical rates of heavy metal deposition. Despite concerns regarding the validity of210Pb dating due to Pb mobility,210Pb dating can be used if the dates are corroborated with some other independent dating technique. In this study, based on analyses of210Pb dated, pollen corroborated peat cores from two sites in the Czech Republic (Jezerní sla and BoŽí Dar Bog), we illustrate a previously unexplored problem concerning the computation of metal deposition, using Pb as an example. When peat cores are collected, sectioned into depth intervals,210Pb dated and analyzed for metal contents, the210Pb dates most appropriately correspond to the midpoint depth for each interval, whereas the metal contents correspond to the interval between the top and bottom of each section. Thus the210Pb dates and metal content values throughout the core are offset by half the distance of each depth interval. In calculating historical rates of heavy metal deposition two approaches are available for correcting for the depth interval offsets, the traditional approach of date interpolation and our newly proposed metal content interpolation. We see noa priori reason for choosing one approach over the other, and suggest simultaneous use of both date and metal content interpolation. Additionally, acid-insoluble ash (AIA), which has been proposed as a dating technique in and of itself, may be more useful as an interpretive tool which may provide insights into the nature or sources of atmospherically deposited Pb. For example, plots of Pb content per core section versus AIA content per core section for Jezerní slat, located in a relatively pristine area, reveal increased Pb content without increased AIA contents in depths shallower than 6 cm, indicating deposition of gasoline-derived Pb after its introduction in 1922. Similar plots for BoŽí Dar Bog, located in a polluted industrialized region, indicate greater inputs of Pb than would be predicted from AIA, based on the Jezerní sla analyses. We interpret the apparent excess Pb deposition at BoŽí Dar Bog as being contributed by soil-derived dust from local metal mining. Elevated rates in Pb deposition at BoŽí Dar Bog are consistent with the history of local mining known to have occurred in the vicinity. Finally, magnetic susceptibility measurements identify combustion of fossil fuels as a source of atmospheric Pb deposition at BoŽí Dar Bog, but not at Jezerní sla
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 65 (1992), S. 353-369 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Depth profiles of total S, organic S, soluble SO 4 2− -S, FeS, and FeS2 were characterized for Sphagnum-derived peat cores collected from 9 sites. Marcell S-2 Bog (MN), Tamarack Swamp (PA), Cranesville Swamp (MD/WV), and Big Run Bog (WV) receive water from precipitation and upland runoff; atmospheric S deposition is 13, 47, 54, and 114 mmol m−2, yr−1, respectively. McDonald's Branch Swamp (NJ) is predominantly groundwater fed. Tub Run Bog (WV) and Allegheny Mining Bog (MD) receive augmented SO 4 2− inputs through acid coal mine drainage. Jezerní slat' and BoŽí Dar Bog in Czechoslovakia receive atmospheric S inputs of 33 and 243 mmol m−2 yr−1, respectively. In the peat from all sites except Allegheny Mining Bog, where the substantially augmented SO 4 2− input was reflected in an unusually high dissolved SO 4 2− pool in the surface peat, organic S (probably mostly carbon bonded S) was the dominant S fraction; FeS2 was generally the dominant inorganic S fraction. Subsurface peaks in total S, organic S and FeS2-S in peat from the runoff water fed sites were interpreted as indicative of depth-dependent patterns in S reduction/oxidation and in S immobilization/mineralization. Unless SO 4 2− inputs to a site are tremendously augmented (e.g., Allegheny Mining Bog), the rapid turnover of the dissolved SO 4 2− pool combined with the relative stability of the other inorganic and organic S pools, apparently functions as an effective buffer against site differences in S inputs, leading to a general similarity in vertical S profiles in the peat deposits.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geochemistry and health 17 (1995), S. 83-94 
    ISSN: 1573-2983
    Keywords: Soil sulphur ; 35S radiolabelling ; soil incubation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract Changes in chemistry and vertical distribution of35S were investigated in column experiments using intact topsoil and repacked mineral soil horizons 1 to 20 weeks after tracer application (901 kBq35S-SO4 2− per column 6.5 cm in diameter). Horizons O, A, AE and Bvs of an Orthic Podzol were incubated at 20°C and wetted twice a week with 11 mm of natural throughfall precipitation (38.5 mg S04 2− L−1-, pH 3.3). The top 35 cm of the soil contained 1,290 kg S ha−1, or 18 times more than is the annual atmospheric S input (71.4 kg S ha−1 yr−1). Of this amount, 17.8 % was stored as inorganic sulphate S, 4.6 % as reduced inorganic S, and 77.6 % as organic S. In O + A and AE, free sulphate was the most abundant35S form, while in Bvs the 35S activity of free and adsorbed sulphate was similar. The proportion of adsorbed sulphate increased with depth, averaging 23, 30 and 47 % of total inorganic sulphate35S in O + A, AE and Bvs, respectively. Total specific activity of chemically transformed35S (i.e., of reduced inorganic S and organic S) constituted 3.4, 3.8 and 105 % of inorganic sulphate35S activity in O + A, AE and Bvs, respectively, in averaged weeks 2–4, and 7.5, 6.4 and 39.6 % in averaged weeks 11–13 in O+A, AE and Bvs, respectively. The turnover time of C-bonded35S was shorter than that of ester sulphate35S. An increase in FeS2− 35S with time indicated anaerobic conditions suitable for bacterial sulphate reduction. After 13 weeks, 68 % of the tracer was found deeper than 8 cm below soil surface.
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