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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geochemistry and health 21 (1999), S. 227-256 
    ISSN: 1573-2983
    Keywords: land use ; lithology ; sampling ; trace metals ; tropical soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract Surface soils (0–15 cm) were sampled at 10–20 km intervals along two transects in Venezuela. One (1162 km, 70 samples) ran west to east parallel with the Caribbean coastline, the other (920 km, 92 samples) ran south to north from the frontier with Brazil to the Caribbean shore. Sampling took place in both a wet and a dry season. Trace metals were extracted from dried, sieved (〈2 mm) soil with boiling aqua regia followed by analysis by ICP or flame AAS. Metal values did not differ significantly between the two seasons and dates were averaged. Geometric mean values for the west–east transect were: Cr = 41.5, Cu 17.9, Cs 3.6, Li = 13.9, Mn = 294, Ni = 21.3, Pb = 17.4, Sr = 39.4, V = 60.4 and Zn = 83.7 μg g−1, respectively. Similarly, for the south–north transect Cr = 21.3, Cu = 4.3, Cs = 1.1, Li = 2.0, Mn = 55.7, Ni = 4.4, Pb = 6.1, Sr = 13.3, V = 28.2 and Zn = 16.7 μg g−1, respectively. A classification of samples by lithology showed surface soil composition to be related to rock composition. Metal values were low in the soils in the south of the country, in the Guyana highlands (Gran Sabana). Low Zn contents were prevalent. Lead contents were affected by roadside fallout from vehicles using leaded petrol except that high Pb contents of soils in the Gran Sabana were of more complex origin.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geochemistry and health 17 (1995), S. 113-118 
    ISSN: 1573-2983
    Keywords: Metal contaminants ; sediment cores ; Venezuela
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract Total extractable concentrations of AI, Fe, Mn, Pb, Cu, Zn, Hg and organic carbon (Corg) were determined along four sediment cores from Lake Valencia. In one selected core, the percentage labile fractions were determined in order to establish anthropic enrichment factors, the depth reached by the contaminants and their mobilities. The distribution patterns of concentration versus depth reflect the original concentrations of the settling sediments. Only Mn seems to show diagenetic cycling. No enrichment of Fe and Mn occurs in the upper part of the cores, in spite of good water circulation and aeration of bottom lake waters during five months of the year. This immobility can be attributed to the high pH of water (7.6 – 8.9). Pb, Zn, Cu and Hg are enriched in the upper part of the cores, probably reflecting the input of contaminants. These elements show enrichment factors of up to 3.0. Background concentrations of the studied metals are reached below a depth of 30 cm.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geochemistry and health 22 (2000), S. 55-74 
    ISSN: 1573-2983
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract The concentrations of organic carbon (Corg), inorganic carbon (Cinorg), organic nitrogen (Norg) and total aromatic (AromT) were determined in 25 samples of bottom sediments from the Lake Valencia, Venezuela, as a contribution to the knowledge about pollution by organic compounds in tropical lakes. Results demonstrate that the Corg and Norg concentrations do not show the pollution indexes by themselves. This is a consequence of the masking effect of naturally derived organic matter from the decay of algae and organisms in the water column and terrestrial plants, which are transported to the lake. Nevertheless, the AromT concentrations and the normalised AromT (normalized to organic carbon) make it possible to detect organic matter of anthropogenic origin, in the AromT levels are about nine times higher than those natural. The variation in the band intensity of the IRFT spectra for some functional groups present in the saturate and aromatic hydrocarbon fractions gives an indication of anthropogenic contribution for some zones of the lake. With the 1H NMR spectra it was not possible to differentiate a natural source from an anthropogenic one in the lake. Naturally occurring organic compounds (eicosane, pentacosane, and hexacosane) were detected with GC technique in the saturated hydrocarbon fraction. The presence of an unresolved complex mixture (UCM) in the GC chromatograms indicates pollution by branched and cyclic hydrocarbons. These compounds are probably produced by the incomplete combustion of oil products. Potentially toxic organic compounds such as anthracene, phenanthrene and chrysene were found in the aromatic hydrocarbon fraction, which despite presenting low concentrations (ppb order) accumulate in the lake sediments along with the natural source organic matter. The main access paths of organic pollutants to the lake are the rivers which cross the two urban and industrial areas (Maracay and Valencia cities). The mixture of polluted sediments with bottom natural sediments and the autochthonous contribution of organic matter mitigate the pollution levels progressively towards the center of the lake.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 1996-09-01
    Print ISSN: 0002-9599
    Electronic ISSN: 1945-452X
    Topics: Geosciences
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  • 5
    Publication Date: 1994-01-01
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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