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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Environmental science & technology 12 (1978), S. 934-937 
    ISSN: 1520-5851
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Changes in organic materials preserved within sediments of Saginaw Bay deposited over the past two centuries record corresponding periods in the environmental history of this part of Lake Huron and its watershed. Sediments deposited since 1940 show an increasingly greater input of aquatic organic matter in response to accelerating cultural eutrophication of Saginaw Bay. Concentrations of fatty acids, sterols, fatty alcohols, and aliphatic hydrocarbons are higher in these modern sediments than in deeper ones. Molecular distributions of these geolipids reflect less aquatic material deeper in the sediments. Prior to 1875, sediment organic matter appears to be diluted by mineral matter from enhanced erosion caused by clearing of the watershed for farming and settlement. During this period there is better preservation of carbonate minerals due to quicker burial. Since 1875, petroleum components comprise over 90% of the total aliphatic hydrocarbon content of these sediments, reflecting the advent and continued existence of chronic, low-level petroleum contamination of this part of the Great Lakes.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-1157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The oxidation and reduction that occur during early diagenesis of sediments has been studied in the interstitial waters of a rapidly accumulating sedimentary sequence from the Mediterranean margin of Spain. A series of reactions that are mediated by progressively lower free energy derived from oxidation of organic matter is evident in the sedimentary sequence. Iron and manganese are rapidly reduced. Phosphate and alkalinity maxima at a subbottom depth of 15 m indicate maximal organic matter degradation. Methane first appears at ∼20 m subbottom after sulfate is depleted, and its concentrations quickly climb.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-1157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The amount and type of organic matter present in an exceptionally complete upper Aptian to lower Cenomanian sequence of sediments from ODP site 763 on the Exmouth Plateau has been determined. Organic carbon concentrations average 0.2%. Organic matter is marine in origin, and its production and preservation was low over the ca. 20-million-year interval recorded by this sequence. Because this section was tectonically isolated from mainland Australia in the early Aptian, it better represents global oceanic conditions than the many basin-edge locations in which Albian-age black shales have been found. Formation of the basin-edge black shales evidently resulted from rapid, turbiditic burial of organic matter rather than from enhanced oceanic production or from basin-wide anoxia during the Albian.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 287 (1980), S. 534-536 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The types of chemical alterations which biological materials experience during early diagenesis in geological settings are important to biogeochemistry. A particularly interesting approach which has been used to describe some of these changes has involved chemical analysis of fossil materials, ...
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 244 (1973), S. 23-24 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Our experiments were done in litre volumes of saline solution (30 g NaCl kg?1 solution) adjusted to pH 8.0. The experimental method has been described in ref 2. The recovery of sorbed hydrocarbons from bentonite clay (〈44 µm) was 100 + 3.1% for eicosane (n-C20H42), 101 ±3.1% for ...
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-1421
    Keywords: Alkanols ; C/N ratios ; σ13C ; fatty acids ; lignin hydrolysates ; n-alkanes ; organic matter ; sterols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither σ13C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 18 (1997), S. 211-218 
    ISSN: 1573-0417
    Keywords: δ13C organic ; glacial-interglacial cycles ; mass accumulation rates ; C/N ratios
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A 911-m-long sediment core from Lake Biwa, Japan, provides a record of organic matter delivery and accumulation in this large lake during a succession of tectonic and climatic changes dating back to the latest Pliocene. Sediments deposited since 430 ky are profundal; older sediments vary in setting between shallow-water and fluviodeltaic conditions, with occasional deep-water intervals. C/N ratios identify algal production as the dominant source of organic matter throughout the core, although the proportion of land-derived contributions episodically increases in the fluviodeltaic and shallow-water sediments. Rates of organic matter delivery and burial in lake sediments change in response to glacial-interglacial climate changes over the past 430 ky. Sediments deposited during interglacial intervals have organic carbon mass accumulation rates up to 9 times greater than those from glacial intervals, reflecting interglacial climates that were wetter than glacial climates. Algal production of organic matter increased during interglacial times because of greater wash-in of soil nutrients, and organic matter preservation was enhanced because of faster sedimentation rates.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 21 (1999), S. 345-372 
    ISSN: 1573-0417
    Keywords: carbon isotyopes ; nitrogen isotopes ; hydrogen isotopes ; Rock-Eval analysis ; C/N ratios ; pollen ; organic carbon mass accumulation rates ; organic petrography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Identification of the sources of organic matter in sedimentary records provides important paleolimnologic information. As the types and abundances of plant life in and around lakes change, the composition and amount of organic matter delivered to lake sediments changes. Despite the extensive early diagenetic losses of organic matter in general and of some of its important biomarker compounds in particular, bulk identifiers of organic matter sources appear to undergo minimal alteration after sedimentation. Age-related changes in the elemental, isotopic, and petrographic compositions of bulk sedimentary organic matter therefore preserve evidence of past environmental changes. We review different bulk organic matter proxies of climate change in tropical and temperate sedimentary records ranging in age from 10-500 ka. Times of wetter climate result in enhanced algal productivity in lakes as a consequence of greater wash-in of soil nutrients, and these periods are recorded as elevated Rock-Eval hydrogen indices, lowered organic C/N ratios, less negative organic δ13C values, and increased organic carbon mass accumulation rates. Lowering of lake water levels, which typically depresses algal productivity, can also cause an apparent increase in organic carbon mass accumulation rates through suspension of sediments from lake margins and redeposition in deeper basins. Alternations between C3 and C4 watershed plants accompany climate changes such as glacial/interglacial transitions and wet/dry cycles, and these changes in land-plant types are evident in δ13C values of organic matter in lake sediments. Changes in climate-driven hydrologic balances of lakes are recorded in δD values of sedimentary organic matter. Visual microscopic examination of organic matter detritus is particularly useful in identifying changes in bulk organic matter delivery to lake sediments and therefore is important as an indicator of climate changes.
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  • 10
    ISSN: 1573-0417
    Keywords: Great Basin ; climatic variations ; productivity ; organic matter ; nitrogen ; phosphorus ; hardwater lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediment cores from the shallow and deep basins of Pyramid Lake, Nevada, revealed variations in composition with depth reflecting changes in lake level, river inflow, and lake productivity. Recent sediments from the period of historical record indicate: (1) CaCO3 and organic content of sediment in the shallow basin decrease at lower lake level, (2) CaCO3 content of deep basin sediments increases when lake level decreases rapidly, and (3) the inorganic P content of sediments increases with decreasing lake volume. Variations in sediment composition also indicate several periods for which productivity in Pyramid Lake may have been elevated over the past 1000 years. Our data provide strong evidence for increased productivity during the first half of the 20th Century, although the typical pattern for cultural eutrophication was not observed. The organic content of sediments also suggests periods of increased productivity in the lake prior to the discovery and development of the region by white settlers. Indeed, a broad peak in organic fractions during the 1800's originates as an increase starting around 1600. However, periods of changing organic content of sediments also correspond to periods when inflow to the lake was probably at extremes (e.g. drought or flood) indicating that fluctuations in river inflow may be an important factor affecting sediment composition in Pyramid Lake.
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