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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2006. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Journal of Petroleum Science and Engineering 56 (2007): 127-135, doi:10.1016/j.petrol.2006.02.003.
    Description: To improve our understanding of the interaction of methane gas hydrate with host sediment, we studied: (1) the effects of gas hydrate and ice on acoustic velocity in different sediment types, (2) effect of different hydrate formation mechanisms on measured acoustic properties (3) dependence of shear strength on pore space contents, and (4) pore-pressure effects during undrained shear. A wide range in acoustic p-wave velocities (Vp) were measured in coarse-grained sediment for different pore space occupants. Vp ranged from less than 1 km/s for gascharged sediment to 1.77 - 1.94 km/s for water-saturated sediment, 2.91 - 4.00 km/s for sediment with varying degrees of hydrate saturation, and 3.88 - 4.33 km/s for frozen sediment. Vp measured in fine-grained sediment containing gas hydrate was substantially lower (1.97 km/s). Acoustic models based on measured Vp indicate that hydrate which formed in high gas flux environments can cement coarse-grained sediment, whereas hydrate formed from methane dissolved in the pore fluid may not. The presence of gas hydrate and other solid pore-filling material, such as ice, increased the sediment shear strength. The magnitude of that increase is related to the amount of hydrate in the pore space and cementation characteristics between the hydrate and sediment grains. We have found, that for consolidation stresses associated with the upper several hundred meters of subbottom depth, pore pressures decreased during shear in coarse-grained sediment containing gas hydrate, whereas pore pressure in fine-grained sediment typically increased during shear. The presence of free gas in pore spaces damped pore pressure response during shear and reduced the strengthening effect of gas hydrate in sands.
    Description: This work was supported by the Coastal and Marine Geology, and Energy Programs of the U.S. Geological Survey and funding was provided by the Gas Hydrate Program of the U.S. Department of Energy.
    Keywords: Acoustic modeling ; Acoustic velocity ; Cementation ; Gas hydrate ; Physical properties ; Shear strength
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 2
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Journal of Geophysical Research 113 (2008): B07102, doi:10.1029/2007JB005351.
    Description: Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed, at least briefly, to non-in situ conditions during recovery. To examine the effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes, and speeds of the original and depressurized/repressurized samples are compared. X–ray computed tomography images track how the gas-hydrate distribution changes in the hydrate-cemented sands owing to the depressurizaton/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.
    Description: U. S. Geological Survey contributions were supported by the Gas Hydrate Project of the U. S. Geological Survey’s Coastal and Marine Geology Program, in addition to Department of Energy contract DE-AI21-92MC29214. CT scanning at the Lawrence Berkeley National Laboratory was artfully performed by L. Tomutsa and supported by the Assistant Secretary for Fossil Energy, Office of Oil and Natural Gas, through the National Energy Technology Laboratory of the U. S. Department of Energy under contract DE-AC02-05CH11231.
    Keywords: Gas hydrate ; Physical properties ; Pressure core
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in American Mineralogist 89 (2004): 1202-1207.
    Description: Bulk properties of gas hydrate-bearing sediment strongly depend on whether hydrate forms primarily in the pore fluid, becomes a load-bearing member of the sediment matrix, or cements sediment grains. Our compressional wave speed measurements through partially water-saturated, methane hydrate-bearing Ottawa sands suggest hydrate surrounds and cements sediment grains. The three Ottawa sand packs tested in the Gas Hydrate And Sediment Test Laboratory Instrument (GHASTLI) contain 38(1)% porosity, initially with distilled water saturating 58, 31, and 16% of that pore space, respectively. From the volume of methane gas produced during hydrate dissociation, we calculated the hydrate concentration in the pore space to be 70, 37, and 20% respectively. Based on these hydrate concentrations and our measured compressional wave speeds, we used a rock physics model to differentiate between potential pore-space hydrate distributions. Model results suggest methane hydrate cements unconsolidated sediment when forming in systems containing an abundant gas phase.
    Description: This work was supported by the U.S. Geological Surveyʼs Coastal and Marine Geology and Eastern Region Gas Hydrate Programs, in addition to DOE contract DE-AI21-92MC29214.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Geophysical Journal International 169 (2007), 767–774, doi:10.1111/j.1365-246X.2007.03382.x.
    Description: Thermal conductivity, thermal diffusivity and specific heat of sI methane hydrate were measured as functions of temperature and pressure using a needle probe technique. The temperature dependence was measured between −20°C and 17°C at 31.5 MPa. The pressure dependence was measured between 31.5 and 102 MPa at 14.4°C. Only weak temperature and pressure dependencies were observed. Methane hydrate thermal conductivity differs from that of water by less than 10 per cent, too little to provide a sensitive measure of hydrate content in water-saturated systems. Thermal diffusivity of methane hydrate is more than twice that of water, however, and its specific heat is about half that of water. Thus, when drilling into or through hydrate-rich sediment, heat from the borehole can raise the formation temperature more than 20 per cent faster than if the formation's pore space contains only water. Thermal properties of methane hydrate should be considered in safety and economic assessments of hydrate-bearing sediment.
    Description: Gas Hydrate Project of the U.S. Geological Survey’s Coastal and Marine Geology Program, in addition to Department of Energy contract DE-AI21–92MC29214
    Keywords: Methane hydrate ; Specific heat ; Thermal conductivity ; Thermal diffusivity
    Repository Name: Woods Hole Open Access Server
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  • 5
    ISSN: 1573-5052
    Keywords: Cyperus alopecuroides ; Hydrilla verticillata ; Ipomoea aquatica ; Primary production ; Scirpus tuberosus ; Sporobolus helvolus ; Standing crop ; Water level
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Paspalum distichum L. has been the dominant species in the monsoonal wetlands of the Keoladeo National Park in northcentral India since 1982 when grazing by water buffalo and domestic cattle was halted. Maximum water levels in these wetlands occur immediately after the end of the summer monsoon in late September of early October and then decline until the next summer monsoon the following June. After the normal 1985 monsoon, maximum water depths were around 140 cm. After the poor 1986 monsoon, maximum water depths were only around 60 cm. Paspalum distichum maximum aboveground biomass at four sites ranged from 850 g m-2 at the shallowest site to 3400 g m−2 at a deep water site. The maximum biomass of other vegetation types, which had dominated this wetland prior to 1982, ranged from 1400 g m-2 at a deep water site (Ipomoea aquatica Forsk.) to only 240 g m-2 to 400 g m-2 at a deep-water submersed site (Hydrilla verticillata (L. f.) Royle/Cyperus alopecuroides Rottb.) and at a shallow emergent site (Scirpus tuberosus Desf./Sporobolus helvolus (Trin.) Dur. et Schinz). For all vegetation types, biomass changed seasonally in response to changing water levels and temperatures. After the 1986 monsoon, above-ground biomass for all vegetation types was much lower than it had been after the 1985 monsoon. Mean below-ground biomass was very low in all vegetation types (1 to 47 g m-2). Paspalum distichum had a higher aboveground biomass at nearly all water depths in all seasons than that of the pre-1982 vegetation types. Paspalum distichum belowground biomass, however, is comparable to, or less than, that of the pre-1982 vegetation types. During years with an average monsoon, the overall primary production of these wetlands is estimated to have increased 2.5 to 3.5-fold since they were overgrown with Paspalum distichum.
    Type of Medium: Electronic Resource
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  • 6
    Publication Date: 1993-09-01
    Print ISSN: 1385-0237
    Electronic ISSN: 1573-5052
    Topics: Biology
    Published by Springer
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  • 7
    Publication Date: 2008-07-03
    Print ISSN: 0148-0227
    Electronic ISSN: 2156-2202
    Topics: Geosciences
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  • 8
    Publication Date: 2007-05-01
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
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