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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 13 (1980), S. 626-632 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 998-1008 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report high-pressure liquid chromatography (HPLC) and transmission electron microscopy studies of the size-dependent absorbance properties of Au and Ag nanoclusters dispersed in organic solvents. These nanosize metal clusters are synthesized by an inverse micelle synthetic technique at room temperature in inert oils and those investigated range in diameter from 1.3–8 nm. HPLC allows us to separate the clusters from all other chemicals and size select to a resolution of ±2 Å. We use an on-line photodiode array to study the size-dependent absorbance properties of these clusters. For both Au and Ag clusters in the size range d=8 to d=1.5 nm, the plasmon linewidth broadens following a 1/R linewidth size dependence whose slope is greatest for Au. The peak asymmetry in the plasmon band shape is greatest for Au and increases with decreasing size for both Au and Ag clusters. The plasmon peak energy blue shifts with decreasing size for Au clusters while in the case of Ag nanoclusters a red shift is observed. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 108 (1963), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 196 (1962), S. 762-763 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] These predictions have been confirmed by X-ray diffraction photographs of InSb-II. The apparatus, which will be described in detail elsewhere, consists of two diamond hardness indenters which have had the points ground off to leave small flat surfaces. These are held in a framework and thrust ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 42 (1991), S. 311-339 
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 9137-9143 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have observed visible light emission from nanosize gold clusters. Liquid chromatographic analysis of the metal clusters shows that relatively intense photoluminescence occurs only when the size of the metal nanocluster is sufficiently small (〈5 nm). The emission is strongly Stokes shifted and is assigned to radiative recombination of Fermi level electrons and sp- or d-band holes. The electron and/or hole states are perturbed by surface states, as indicated by the dependence of the emission spectrum on the nature of the cluster surface. Finally, we found that large, nonemitting gold clusters can also be made luminescent by partial dissolution using KCN. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 41 (1993), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: An experiment was undertaken at BP's Fulbeck Geophysical test site to compare the viability of various simultaneous vibroseis recording techniques, which are often recommended as a means of improving data acquisition production rates for 3D seismic surveys. Of particular interest were: (a) the ability to separate the signals from each source during processing, (b) the generation and suppression of harmonics and (c) the effects of any source interaction.Two vibrators were deployed with a baseplate separation of 10 m, about a borehole containing a vertical array of geophones. Our analysis concentrated on the groundforce signals measured at each vibrator and the far-field signatures measured using a vertical geo-phone at a depth of 204 m.By comparing single vibrator records with similar but separated records from a simultaneous recording sequence, signal separability, harmonic suppression and vibrator interaction could be fully studied.Separated far-field signatures from simultaneous vibroseis methods using combinations of up and downsweeps exhibited unsuppressed harmonics and substantial energy from the undesired source which leaked through the correlation process. The ‘up/down’ method was capable of separating the signal from each source by only 12.7 dB, and is therefore unsuitable as a field technique.The variphase simultaneous vibroseis methods studied afforded some harmonic suppression and gave signal separations of about 30.0 dB. Use of variphase simultaneous vibroseis methods will compromise the quality of the data recorded, when compared with single-source acquisition methods.None of the simultaneous vibroseis methods tested provided adequate signal separation and, therefore, cannot be recommended as data acquisition techniques. The ‘alternate sweeping’ method coupled with multispread recording will give the desired improvement in data acquisition rates, while preserving the necessary quality of our seismic data.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 37 (1989), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The quality of Vibroseis survey data can be improved by continuously monitoring the vibrator's baseplate and reaction mass accelerations. Equipment failures can be detected as they occur, rather than relying on similarity trials at the beginning and end of the day's production. Equipment faults can then be corrected as they happen and thus would not have a detrimental effect on the quality of the survey data. Source efficiency can be optimized by monitoring the amount of harmonic distortion generated by the vibrator at different drive levels on the different surfaces which may be encountered during a survey. Phase problems introduced by poor coupling of the baseplate to the ground can also be identified and addressed in the field.Rapid analysis of vibrator signals is required if continuous monitoring is to be useful. Frequency-time (f-t) analyses of vibrator signals are often used in processing centres, but are slow and require a large storage capacity which makes the technique unsuitable for a field analysis system.The two methods proposed to analyse vibrator signals entail the use of hodograms and time-varying notch filters. Hodograms provide a qualitative analysis of harmonic distortion and vibrator performance. A fast, time-varying notch filter gives quantitative and qualitative information about the harmonic distortion present in the signal and can be used to identify problems with vibrator behaviour. Both the hodogram and fast, time-varying notch filter methods can analyse the vibrator's reaction mass and baseplate accelerations as it progresses through its sweep and can present automatically interpreted results to the operator before moving to the next vibrator point.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 8 (1996), S. 1917-1928 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The mechanisms of vorticity concentration, reorientation, and stretching are investigated in a simplified swirling jet model, consisting of a line vortex along the jet axis surrounded by a jet shear layer with both azimuthal and streamwise vorticity. Inviscid three-dimensional vortex dynamics simulations demonstrate the nonlinear interaction and competition between a centrifugal instability and Kelvin–Helmholtz instabilities feeding on both components of the base flow vorticity. Under axisymmetric flow conditions, it is found that the swirl leads to the emergence of counter-rotating vortex rings, whose circulation, in the absence of viscosity, can grow without bounds. Scaling laws are provided for the growth of these rings, which trigger a pinch-off mechanism resulting in a strong decrease of the local jet diameter. In the presence of an azimuthal disturbance, the nonlinear evolution of the flow depends strongly on the initial ratio of the azimuthal and axisymmetric perturbation amplitudes. The long term dynamics of the jet can be dominated by counter-rotating vortex rings connected by braid vortices, by like-signed rings and streamwise braid vortices, or by wavy streamwise vortices alone. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 6 (1994), S. 1116-1132 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This paper presents detailed computational results for the dispersion of heavy particles in transitional mixing layers forced at both the fundamental and subharmonic frequencies. The results confirm earlier observations of particle streaks forming in the braid region between successive vortices. A scaling argument based on the idealization of the spatially periodic mixing layer as a row of point vortices shows that the formation of these concentrated particle streaks proceeds with optimum efficiency for St(approximately-equal-to)1. It thereby provides a quantitative basis for experimental and numerical observations of preferential particle dispersion at Stokes numbers of order unity. Both the model and full simulation furthermore exhibit oscillatory particle motion, as well as the formation of two bands of high particle concentrations, for larger Stokes numbers. The particle dispersion as a function of time and the Stokes number is quantified by means of two different integral scales. These show that the number of dispersed particles does not reach a maximum for intermediate Stokes number. However, when the distance is weighted, optimum dispersion is observed for Stokes numbers around unity. By tracing the dispersed particles backwards in time, they are found to originate in inclined, narrow bands that initially stretch from the braid region into the seeded free stream. This suggests that particle dispersion can be optimized by phase coupling the injection device with the forcing signal for the continuous phase. In the presence of a subharmonic perturbation, enhanced particle dispersion is observed as a result of the motion of the vortices, whereby a larger part of the flow field is swept out.
    Type of Medium: Electronic Resource
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