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  • 1
    Publication Date: 2018-09-28
    Type: Dataset
    Format: text/tab-separated-values, 583 data points
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  • 2
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    PANGAEA
    In:  Supplement to: Hughen, Konrad A; Lehmann, Scott J; Southon, John R; Overpeck, Jonathan T; Marchal, Olivier; Herring, C; Turnbull, J (2004): 14C Activity and Global Carbon Cycle Changes over the Past 50,000 Years. Science, 303(5655), 202-207, https://doi.org/10.1126/science.1090300
    Publication Date: 2019-02-20
    Description: A series of 14C measurements in Ocean Drilling Program cores from the tropical Cariaco Basin, which have been correlated to the annual-layer counted chronology for the Greenland Ice Sheet Project 2 (GISP2) ice core, provides a high-resolution calibration of the radiocarbon time scale back to 50,000 years before the present. Independent radiometric dating of events correlated to GISP2 suggests that the calibration is accurate. Reconstructed 14C activities varied substantially during the last glacial period, including sharp peaks synchronous with the Laschamp and Mono Lake geomagnetic field intensity minimal and cosmogenic nuclide peaks in ice cores and marine sediments. Simulations with a geochemical box model suggest that much of the variability can be explained by geomagnetically modulated changes in 14C production rate together with plausible changes in deep-ocean ventilation and the global carbon cycle during glaciation.
    Type: Dataset
    Format: text/tab-separated-values, 3013 data points
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  • 3
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    PANGAEA
    In:  Physikalisches Institut, Universität Bern
    Publication Date: 2018-12-14
    Type: Dataset
    Format: text/tab-separated-values, 133 data points
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  • 4
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    American Meteorological Society
    Publication Date: 2017-01-07
    Description: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 2910-2925, doi:10.1175/2009JPO4139.1.
    Description: The propagation of Rossby waves on a midlatitude β plane is investigated in the presence of density diffusion with the aid of linear hydrostatic theory. The search for wave solutions in a vertically bounded medium subject to horizontal (vertical) diffusion leads to an eigenvalue problem of second (fourth) order. Exact solutions of the problem are obtained for uniform background stratification (N), and approximate solutions are constructed for variable N using the Wentzel–Kramers–Brillouin method. Roots of the eigenvalue relations for free waves are found and discussed. The barotropic wave of adiabatic theory is also a solution of the eigenvalue problem as this is augmented with density diffusion in the horizontal or vertical direction. The barotropic wave is undamped as fluid parcels in the wave move only horizontally and are therefore insensitive to the vortex stretching induced by mixing. On the other hand, density diffusion modifies the properties of baroclinic waves of adiabatic theory. In the presence of horizontal diffusion the baroclinic modes are damped but their vertical structure remains unaltered. The ability of horizontal diffusion to damp baroclinic waves stems from its tendency to counteract the deformation of isopycnal surfaces caused by the passage of these waves. The damping rate increases (i) linearly with horizontal diffusivity and (ii) nonlinearly with horizontal wavenumber and mode number. In the presence of vertical diffusion the baroclinic waves suffer both damping and a change in vertical structure. In the long-wave limit the damping is critical (wave decay rate numerically equal to wave frequency) and increases as the square roots of vertical diffusivity and zonal wavenumber. Density diffusion in the horizontal or vertical direction reduces the amplitude of the phase speed of westward-propagating waves. Observational estimates of eddy diffusivities suggest that horizontal and vertical mixing strongly attenuates baroclinic waves in the ocean but that vertical mixing is too weak to notably modify the vertical structure of the gravest modes.
    Description: This work was supported by the U.S. National Science Foundation.
    Keywords: Rossby waves ; Extratropics ; Buoyancy ; Mixing
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2017-01-05
    Description: Author Posting. © The Author(s), 2010. This is the author's version of the work. It is posted here by permission of Springer-Verlag for personal use, not for redistribution. The definitive version was published in Climate Dynamics 6 (2010): 763-779, doi:10.1007/s00382-010-0790-6.
    Description: An ocean-atmosphere-sea ice model is developed to explore the time-dependent response of climate to Milankovitch forcing for the time interval 5-3 Myr BP. The ocean component is a zonally averaged model of the circulation in five basins (Arctic, Atlantic, Indian, Pacific, and Southern Oceans). The atmospheric component is a one-dimensional (latitudinal) energy balance model, and the sea-ice component is a thermodynamic model. Two numerical experiments are conducted. The first experiment does not include sea ice and the Arctic Ocean; the second experiment does. Results from the two experiments are used to investigate (i) the response of annual mean surface air and ocean temperatures to Milankovitch forcing, and (ii) the role of sea ice in this response. In both experiments, the response of air temperature is dominated by obliquity cycles at most latitudes. On the other hand, the response of ocean temperature varies with latitude and depth. Deep water formed between 45°N-65°N in the Atlantic Ocean mainly responds to precession. In contrast, deep water formed south of 60°S responds to obliquity when sea ice is not included. Sea ice acts as a time-integrator of summer insolation changes such that annual mean sea-ice conditions mainly respond to obliquity. Thus, in the presence of sea ice, air temperature changes over the sea ice are amplified, and temperature changes in deep water of southern origin are suppressed since water below sea ice is kept near the freezing point.
    Description: This work was supported by an NSERC Discovery Grant awarded to L.A.M. We also thank GEC3 for a Network Grant.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 6
    Publication Date: 2017-01-04
    Description: Author Posting. © The Author(s), 2012. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 90 (2012):126–148, doi:10.1016/j.gca.2012.05.009.
    Description: The ability of paired measurements of thorium isotope activity and particle concentration to constrain rate constants of sorption reactions and particle dynamics in the ocean is examined. This study is motivated by GEOTRACES and other sampling programs where Th and particle data are gathered in various oceanic environments. Our approach relies on inversions with a model of trace metal and particle cycling in the water column. First, the model is used to simulate vertical profiles of (i) the activity of three Th isotopes (228,230,234Th) in the dissolved phase, small suspended particles, and large sinking particles, and (ii) the concentration of small and large particles. The simulated profiles are then subsampled and corrupted with noise to generate a pseudo data set. These data are combined with the model with arbitrary values of rate constants of Th adsorption, Th desorption, particle sinking, particle remineralization, and particle (dis)aggregation in an effort to recover the actual values used to generate the data. Inversions are performed using a least-squares technique with varying assumptions about data noise, data sampling, and model errors. We find that accurate and precise recovery of rate parameters is possible when all data have a relative error of less than 20%, vertical sampling is dense enough to resolve activity and concentration gradients, and model errors are negligible. Estimating cycling rates from data with larger errors and (or) at locations where model assumptions are not tenable would remain challenging. On the other hand, the paired data set would improve significantly the relative precision of rate parameters compared to that of prior estimates (⩾100%), even with current data uncertainties and significant model errors. Based on these results, we advocate the joint measurement of all three Th isotopes, 228Ra, and particles collected by in situ filtration within GEOTRACES and other sampling programs targeted at the study of particle processes in the ocean.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 7
    Publication Date: 2016-05-12
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 30 (2015): 1470-1489, doi:10.1002/2014PA002743.
    Description: The ocean circulation modifies mixed layer (ML) tracer signals as they are communicated to the deep ocean by advection and mixing. We develop and apply a procedure for using tracer signals observed “upstream” (by planktonic foraminifera) and “downstream” (by benthic foraminifera) to constrain how tracer signals are modified by the intervening circulation and, by extension, to constrain properties of that circulation. A history of ML equilibrium calcite δ18O (δ18Oc) spanning the last deglaciation is inferred from a least-squares fit of eight benthic foraminiferal δ18Oc records to Green's function estimated for the modern ocean circulation. Disagreements between this history and the ML history implied by planktonic records would indicate deviations from the modern circulation. No deviations are diagnosed because the two estimates of ML δ18Oc agree within their uncertainties, but we suggest data collection and modeling procedures useful for inferring circulation changes in future studies. Uncertainties of benthic-derived ML δ18Oc are lowest in the high-latitude regions chiefly responsible for ventilating the deep ocean; additional high-resolution planktonic records constraining these regions are of particular utility. Benthic records from the Southern Ocean, where data are sparse, appear to have the most power to reduce uncertainties in benthic-derived ML δ18Oc. Understanding the spatiotemporal covariance of deglacial ML δ18Oc will also improve abilities of δ18Oc records to constrain deglacial circulation.
    Description: 2016-05-12
    Keywords: Oxygen isotopes ; Inverse modeling ; Deglaciation ; Tracers ; Ocean circulation ; Green's function
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 8
    Publication Date: 2017-01-04
    Description: Author Posting. © Blackwell, 2007. This is the author's version of the work. It is posted here by permission of Blackwell for personal use, not for redistribution. The definitive version was published in Tellus A 59 (2007): 141–154, doi:10.1111/j.1600-0870.2006.00193.x.
    Description: The 'Sandström theorem' as interpreted by Jeffreys (1925) is that in a flow maintained by a temperature difference, the pathline from the cold region to the warm region must lie below the return path. A formal demonstration of the argument for a rotating fluid requires three assumptions about the relative circulation around a closed material line: (i) the flow is steady, (ii) the closed material line is a closed streamline and (iii) the work done by friction along the streamline is negative. The argument extends to unsteady flows, thereby relaxing (i-ii), if the absolute circulation along the material line is a bounded function of time - a condition that is met for flows with small Rossby number. Its validity for time-periodic two-dimensional flows of horizontal convection is verified numerically. Poincaré sections reveal the presence of chaotic particle transport in these flows, even though the Eulerian velocity fields have a simple time dependence. In spite of chaotic advection, particle motion is in general downwards in the cold region and upwards in the warm region of the fluid, which is consistent with the flow shape envisioned by Jeffreys. This paper gives support to the validity of his argument for the unsteady case and enhances its relevance for the dynamical interpretation of the basic structure of geophysical flows.
    Description: This work has been supported in part by a grant from the U.S. National Science Foundation
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 9
    Publication Date: 2017-01-04
    Description: Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Deep Sea Research Part I: Oceanographic Research Papers 54 (2007): 557-585, doi:10.1016/j.dsr.2007.01.002.
    Description: An inverse finite-difference model of the abyssal circulation in the North Atlantic Ocean is developed in order to evaluate the dynamical information contained in measurements of thorium-230 (230Th). The model has a very coarse resolution and is based on lowest order balances for planetary flows. The naturally occurring 230Th differs from more conventional oceanic tracers in several respects, e.g., its production (by 234U radioactive decay) is globally uniform to a good approximation and its removal can be understood in terms of a simple reversible exchange with particles sinking slowly to the seafloor. The time required for 230Th to reach steady state with respect to particle exchange is estimated to increase with depth, reaching O(10) yr below 1000 m. In the North Atlantic 230Th activities at distant locations share a similar increase with depth in the upper 1000m—a pattern consistent with a reversible exchange—but show drastic differences in the abyssal interior. Two inversions are conducted in order to determine whether the 230Th differences reflect the effects of the circulation—by preventing the slow attainment to steady state w.r.t. particle exchange in deep water—and provide complementary information about the abyssal flow. In a first inversion, observations of density from a hydrographic compilation and of volume transports at specific locations are combined with the dynamical balances in order to infer the basin-scale flow. The inferred flow displays the western boundary current and coherent structures in the abyssal interior with low statistical significance. In a second inversion, the flow is further constrained by the 230Th measurements and the condition that 230Th divergence by the flow field and particle sinking must be locally balanced by 230Th production from 234U decay. The addition of 230Th leads to the estimation of a larger amplitude of the integrated meridional transports below 1000 m (by 2–9 Sv), where the range reflects the uncertainties in the large scale 230Th distribution and in the radiochemical balance. This result is interpreted as a correction by 230Th for the tendency of inverse geostrophic models to lead to the inference of a vanishing circulation when horizontal density gradients are insignificant.
    Description: OM acknowledges the support from the Ocean and Climate Change Institute at WHOI and from the US National Science Foundation. The IAEA (JS) is grateful for the support provided to its Marine Environment Laboratory by the Government of the Principality of Monaco. JS is grateful to Jan Fietzke for ICPMS measurements and for support from the ‘Deutsche Forschungsgemeinschaft’ (grant no. SCHO752/ 2-1).
    Keywords: Thorium-230 ; Abyssal circulation ; North Atlantic ; Inverse method
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 10
    Publication Date: 2017-01-05
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 26 (2011): PA1212, doi:10.1029/2010PA002022.
    Description: Records of 231Pa/230Th from Atlantic sediments have been interpreted to reflect changes in ocean circulation during the geologic past. Such interpretations should be tested with due regard to the limited spatial coverage of 231Pa/230Th data and the uncertainties in our current understanding of the behavior of both nuclides in the ocean. Here an inverse method is used to evaluate the information contained in 231Pa/230Th compilations for the Holocene, Last Glacial Maximum (LGM), and Heinrich Event 1 (H1). An estimate of the abyssal circulation in the modern Atlantic Ocean is obtained by combining hydrographic observations and dynamical constraints. Then sediment 231Pa/230Th data for each time interval are combined with an advection-scavenging model in order to determine their (in)consistency with the modern circulation estimate. We find that the majority of sediment 231Pa/230Th data for the Holocene, LGM, or H1 can be brought into consistency with the modern circulation if plausible assumptions are made about the large-scale distribution of 231Pa and about model uncertainties. Moreover, the adjustments in the data needed to reach compatibility with a hypothetical state of no flow (no advection) are positively biased for each time interval, suggesting that the 231Pa/230Th data (including that for H1) are more consistent with a persistence of some circulation than with no circulation. Our study does not imply that earlier claims of a circulation change during the LGM or H1 are inaccurate, but that these claims cannot be given a rigorous basis given the current uncertainties involved in the analysis of the 231Pa/230Th data.
    Description: O.M. acknowledges the support from the U.S. National Science Foundation. J.F.M. acknowledges support from the U.S. National Science Foundation and the Comer Research and Education Foundation.
    Keywords: Pa-231/Th-230 ; Meridional overturning circulation ; Inverse method ; Heinrich Event
    Repository Name: Woods Hole Open Access Server
    Type: Article
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