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  • 1
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The effect of an epitaxial 20 nm thick CoSi2 layer on the diffusion of B and Sb in Si is investigated during oxidation and is compared to thermal diffusion in Si. B and Sb doping superlattices (DSLs) were grown by molecular beam epitaxy (MBE). They consisted of six spikes with peak concentrations of about 1018 cm–3 (B) and about 1019 cm–3 (Sb) and peak centres spaced 100 nm apart. The shallowest spike was capped with 100 nm of Si followed by 20 nm of CoSi2 grown by molecular beam allotaxy (MBA). Oxidation in dry O2 and annealing in pure N2 were performed at temperatures of 800 °C to 1200 °C. Concentration depth profiles were measured by secondary ion mass spectrometry (SIMS). The results showed that the diffusion of B and Sb in Si was markedly different for specimens with or without a CoSi2 layer. Oxidation enhanced diffusion (OED) of B and oxidation retarded diffusion (ORD) of Sb was observed for specimens without a CoSi2 layer. The effect of CoSi2 layer was a strong retardation of B diffusion and an enhancement of Sb diffusion. The B diffusivity was retarded by a factor of 2–10 as compared to the thermal diffusivity and by a factor of 20–100 as compared to the corresponding diffusivity for oxidation of Si without a CoSi2 layer. Sb diffusivity was enhanced by a factor of 2 with respect to thermal diffusivity and by about a factor of 5 as compared to the case without a CoSi2 layer.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3347-3352 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Recently, Ru2Si3 has been predicted to be a direct semiconductor with a band gap of (approximate)0.8 eV. Since the corresponding wavelength of this potential light emitter coincides with the absolute absorption minimum of glass fibers of 1.5 μm, considerable attention has been attracted. Measurements of the temperature dependence of the electrical resistivity of silicide films on insulating substrates were carried out in van der Pauw geometry. The results were explained by assuming carrier hopping over grain boundaries. The optical absorption coefficient was measured on thin films grown on various substrates, on self-sustaining films, where the substrate was partly removed and on a single crystal by photothermal deflection spectroscopy. A direct band gap at 0.84 eV was found. The absorption coefficient is very low up to (approximate)1.5 eV, likely due to a low density of states, and then strongly increases at higher energies. The experimental results qualitatively confirm the predictions of the band structure calculations. © 2001 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 3608-3610 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The atomic structure of mesotaxial CoSi2/Si(001) interfaces has been investigated by Z-contrast scanning transmission electron microscopy. The directly interpretable images reveal a 2×1 ordered structure at the interface, which is clearly seen to involve a doubling of the periodicity of the interfacial Co atoms. From these high-resolution images, we deduce a new structure model for the CoSi2/Si(001) interface.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1590-1596 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A silicon wafer was implanted by a high dose of cobalt ions. Afterwards it was annealed in situ while grazing incidence x-ray diffraction measurements in a temperature range up to 690 °C were carried out. The formation of cobalt disilicide (CoSi2) precipitates starts during implantation. The annealing dependence of the precipitate growth, of strain relaxation, and of improvements of the silicide crystallinity was determined. We got an activation energy of (0.47±0.08) eV for the observed annealing process. The result is a buried cobalt disilicide layer with very rough interfaces. The film quality can be improved by a subsequent annealing at about 1000 °C.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 3001-3008 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The formation of buried CoSi2 layers by high-dose Co+ implantation into Si depends sensitively on the implantation temperature. Continuous buried epitaxial layers are only obtained at implantation temperatures above ∼300 °C. At temperatures below ∼200 °C, the implanted Si amorphizes, and the Co profile appears shifted towards the surface by about 250 A(ring) compared to implantations performed above 300 °C, such that no buried layers are formed. A larger sputtering yield of the amorphous than the crystalline Si and a larger mean projected range of the implanted Co+ ions in single-crystalline Si seem to be responsible for the observed shift. For sputtering yields of 100- and 200-keV Co+ ions, we obtained values of Y=2.0±0.1 at room temperature and Y=1.7±0.1 at 350 °C. Implantations with energies ≤50 keV in (100) Si and subsequent annealing yield CoSi2 precipitates or layers at the surface, but not buried layers. The growth of rhombohedral precipitates in (100)Si aggravates the formation of very thin buried silicides. The minimum thickness of buried epitaxial silicides in (100)Si produced by high-dose implantations seems to be ∼400 A(ring), which is significantly larger than the minimum thickness in (111)Si (∼200 A(ring)). Rapid thermal annealing leads to lower specific electrical resistivity values (13 μΩ cm) than conventional furnace annealing. Rutherford backscattering, He+-ion channeling, transmission electron microscopy, and sheet resistivity measurements were employed to characterize the implanted samples.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 3788-3794 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A continuous buried β-FeSi2 layer was obtained by implantation of 200 keV Fe+ ions into Si(111) wafers at elevated temperature. During the subsequent rapid thermal annealing at 1150 °C for 10-s, a continuous buried layer of the metallic α-FeSi2 phase is formed. During the second annealing step at 800 °C, the α phase is completely transformed into the semiconducting β phase. The epitaxial relationship between the β-FeSi2 and the silicon substrate was investigated by transmission electron microscopy. It was found that the β-FeSi2(010) plane grows parallel to the Si(111) substrate. Two different azimuthal orientations were observed. For the first azimuthal orientation, the β-FeSi2[001] direction is oriented almost parallel to one of the three Si〈110〉 directions lying in the interface. In the second azimuthal orientation, the β-FeSi2[100] direction lies parallel to one of the Si〈110〉 directions in the interface. The lattice parameter mismatch and the growth mechanism must be considered to be the main reasons for the epitaxial relationship of the Si(111)/β-FeSi2/Si(111) heterostructures studied in this investigation. The orientation of the β-phase is likely to be predetermined by the orientation of the α-phase which is formed during the first annealing step. Different orientation relationships were observed for β-FeSi2 prepared by solid phase epitaxy and ion beam synthesis without high-temperature annealing.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 74 (1999), S. 454-456 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A nanometer patterning method, based on local oxidation of silicide layers, was used to pattern epitaxial CoSi2 layers. A feature size as small as 50 nm was obtained for 20 nm epitaxial CoSi2 layers on Si(100) after patterning by local rapid thermal oxidation in dry oxygen. A Schottky source/drain metal–oxide–semiconductor field effect transistor with epitaxial CoSi2 on p-Si(100) was fabricated using this nanopatterning method to make the 100 nm gate. The device shows good I–V characteristics at 300 K. © 1999 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 79 (2001), S. 824-826 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have developed a method for fabricating epitaxial CoSi2 nanowires using only conventional optical lithography and standard silicon processing steps. This method was successfully applied to ultrathin epitaxial CoSi2 layers grown on Si(100) and silicon-on-insulator substrates. A nitride mask induces a stress field near its edges into the CoSi2/Si heterostructure and leads to the separation of the CoSi2 layer in this region during a rapid thermal oxidation step. A subsequent etching step and a second oxidation generate highly homogenous silicide wires with dimensions down to 50 nm. © 2001 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 866-868 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on design, fabrication, and characterization of an ultrafast vertical metal–semiconductor–metal photodetector. A CoSi2 layer in silicon acts both as a bottom Schottky contact and a buried light reflector. A semi-transparent metallization on top of a photosensitive silicon mesa serves as top Schottky contact. Time-domain studies of the pulse response are performed by electro-optic sampling measurements on photodetectors integrated monolithically into microstrip transmission lines. At room temperature, carrier sweep-out is dominated by hopping transport involving shallow traps. At low temperatures, hopping transport is strongly suppressed. As a consequence, the speed of the diode is considerably enhanced, reaching a pulse response with a full width at half maximum of 6.5 ps. © 1995 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 61 (1992), S. 2409-2411 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The synthesis of buried CoSi2 layers in Si0.91Ge0.09 alloys by the implantation of high doses of 100 and 150 keV Co+ ions and subsequent rapid thermal annealing at T≥1000 °C is studied by x-ray diffraction, Rutherford backscattering spectroscopy, He ion channeling, Auger electron spectroscopy, and transmission electron microscopy. After annealing, a buried single-crystal CoSi2 layer containing ≈1 at. % Ge is formed in the SiGe alloy. Silicide formation causes an outdiffusion of Ge leading to an increase in the Ge concentration of the adjacent SiGe layers. The remaining Ge within the silicide layer is found to be present as Si-Ge islands with the composition of the virgin Si0.91Ge0.09 alloy.
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