Springer Online Journal Archives 1860-2000
Chemistry and Pharmacology
Energy, Environment Protection, Nuclear Power Engineering
Abstract Several adducts of U(IV) and Th(IV) with 1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedione (FOD) as β-diketone and a variety of neutral oxodonors were synthesized and characterized by visible spectral, proton magnetic resonance as well as thermogravimetric studies. Adducts with dimethylformamide (DMF) were found to be most volatile, whereas with trioctylphosphine oxide (TOPO) were quite susceptible towards decomposition.
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