ISSN:
1573-1111
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The enthalpies of transfer of cyclohexanol from aqueous to aqueous α- or β-cyclodextrin solutions have been measured at various mole fractions at 298.15 K on a rocking twin-microcalorimeter of heat-conduction type and the molar enthalpies, Gibbs energies, and entropies of inclusion in the aqueous solutions have been determined by the method proposed by the authors [Netsu Sokutei 10, 103 (1983)], to elucidate the “driving force” of the molecular inclusion. Discussions are given for all the systems obtained by the authors, concluding that the “driving force” is the enhancement of the entropy.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00662245
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