ISSN:
1608-3199
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A rapid method is proposed for the preparation of binuclear rhodium(II) tetraacetate [Rh2(OAc)4(HOAc)2] under the action of microwave radiation. This complex is potentially suitable for the coulometric determination of rhodium. The mechanism of the redox process Rh2(III, II) ⇄ Rh2(II, II) in acetic acid solutions of this complex has been characterized by cyclic voltammetry, controlled-potential coulometry, and spectrophotometry.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1026602717639
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