ISSN:
1434-193X
Keywords:
Synthesis design
;
Conformational analysis
;
Perhydroanthracene
;
Biconformational triple-ring flip
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
-2,3,6,7-Tetrasubstituted perhydroanthracenes with the relative configuration 2β,3α,4aα,6β,7α,8aβ,9aα,10aβ have been synthesized stereoselectively. The biconformationality of these compounds has been investigated in solution by NMR and in the solid state by X-ray crystallography. A triple-ring flip 2 → 3 was realized for the first time by the covalently induced transition 29 → 30.Supporting information for this article is available on the WWW under -http://www.wileY-Vch.de/contents/jc_2046/1999/98441_s.pdf or from the author.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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