ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Mass spectra of acetophenone azine-d10 (II) and acetophenone azine-d6 (III) were obtained to ascertain the validity of the proposed mass spectral fragmentation mechanisms proposed for acetophenone azine (I). Data from II and III reveal that the [M -1] ion in the spectrum of I is formed via loss of ring hydrogen. Within experimental uncertainty the major fragmentation reactions of the molecular ion of I, the [M -1] ion, and the [M -15] ion occur without loss of structural identity of the phenyl and methyl moieties. Ionization of I occurs with a high degree of structural integrity.
Additional Material:
6 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210030506
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