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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 25 (1992), S. 3097-3105 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 35 (1963), S. 2135-2138 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 58 (1936), S. 1808-1811 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochemical and Biophysical Research Communications 187 (1992), S. 609-614 
    ISSN: 0006-291X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 3141-3144 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effective magnetoelastic (ME) coupling coefficients Beff of polycrystalline Ni79Fe21 and Ni films have been reported as functions of thickness t. Beff was observed to have a thickness-independent bulk term, Bb, and a thickness-dependent surface term, Bs/t consistent with the Néel model. For thickness below 50 A(ring) the surface term is important; it can change the sign of the effective ME coupling constant and dramatically increase its magnitude. We expect that the surface ME coupling we observe in polycrystalline thin films may be a combination of the intrinsic Néel surface effect and extrinsic microstructure effects. Our transmission electron microscopy, Auger depth profiling, and atomic force microscopy rule out film discontinuity and compositional gradients as significant sources of the surface ME effect. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 4237-4242 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The integration of the catalytic properties of platinum (Pt) and tin oxide (SnOx) in the Pt-SnOx-Si3N4-SiO2-Si metal-insulator-semiconductor (MIS) capacitor allows the detection of oxygen (O2) and carbon monoxide (CO) gases at a much lower operating temperature than that of the conventional solid-state gas detectors. The operation characteristics of the device for the detection of O2 and CO are described as a function of the gas pressure and temperature ranging from 27 to 100 °C. Repeatability of the device for CO detection in an open air ambient is also presented. A model based on adsorption/reaction of oxygen ions at the Pt-SnOx interface of the MIS capacitor is proposed for oxygen/carbon monoxide detection. The physical and chemical mechanisms responsible for the gas sensing behaviors are discussed. The detection mechanisms explain the device behaviors and account for the following experimental observations and reaction kinetic analysis of the experimental data: (1) the dependence of the reaction kinetics on the square root of the O2 partial pressure, (2) the requirement of oxygen as a constituent of the background gas for CO detection, (3) the inverse proportional relationship of the reaction kinetics to CO partial pressure, and (4) the need of Pt and SnOx as the catalytic layers in the MIS capacitor for gas detection.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 2752-2755 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The microstructure of the NiFe/Co(CoFe)/Al(Ta)-oxide/Co(CoFe) ferromagnetic tunnel junction was investigated using cross-sectional transmission electron microscopy (TEM). The effect of the insulating layer on the magnetoresistive (MR) properties of the junction was studied. The multilayer junction was formed using magnetron sputtering and the insulating layer was created by plasma oxidation of the deposited metal film. TEM analysis showed that the MR ratio was highly dependent on the insulating layer. For the NiFe/Co/Al-oxide/Co junction, when the Al2O3 layer was 13 Å, the oxide layer was flat and the highest MR ratio of 15% was attained. As the Al2O3 thickness increased, the interface roughness rapidly increased, and the MR ratio also markedly dropped. In contrast, NiFe/CoFe/Al-oxide/CoFe junction showed a comparatively flatter interface and recorded a higher MR ratio. The Ta-oxide insulating layer remained flat regardless of the thickness; however, the largest MR ratio of only 9% was obtained within a narrow thickness range. We have demonstrated that there exists a direct correlation between the microstructure of the oxide layer and the MR ratio of the junction, which could be utilized to optimize the electrical properties of the ferromagnetic tunneling junction. © 2001 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 217-220 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Transmission electron microscopy (TEM) and Rutherford backscattering spectroscopy (RBS) were used to characterize low resistance (100–1000 Ω μm2) tunneling junctions consisting of Ta/NiFe/Cu/NiFe/IrMn/CoFe/Al (6.6 and 7.7 Å)–oxide/CoFe/NiFe/Ta multilayers after annealing at temperatures ranging from 250 to 500 °C. The Al (7.7 Å) junction showed continual improvement in the magnetoresistance (MR) ratio when annealed up to 300 °C while the MR ratio of the Al (6.6 Å) junction dropped sharply above 250 °C in spite of the only 1 Å difference in the deposited thickness of aluminum metal prior to plasma oxidation. TEM measurement provided evidence that the annealing process improves, in general, structural uniformity in the insulation layer, but thermal treatment can also degrade junction performance at a relatively low temperature due to current leakage through the electrodes. Current leakage can be problematic for a junction whose insulation barrier may be too thin (less than ∼10 Å). Both RBS and TEM analyses indicated that the maximum annealing temperature of exchange biased junctions lies between 400 and 500 °C above which the multilayer structure in the pinned electrode is destroyed by interdiffusion. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 1431-1435 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Auger electron spectroscopy (AES) and Rutherford backscattering spectroscopy (RBS) analysis were carried out in order to study the extent of interdiffusion during thermal treatment of the pinned electrode (Ta/NiFe/Cu/NiFe/IrMn/CoFe) of the magnetic tunneling junction. From the concentration profile results from RBS and AES, a significant amount of Mn–CoFe interdiffusion was observed when the sample was annealed at 200 °C–400 °C under vacuum. The multilayer was completely intermixed at 400 °C, losing the exchange bias interaction between the IrMn and CoFe layers. It was demonstrated that the migration of Mn was enhanced by the preferential oxidation of Mn on the surface. In fact, when a thin layer of Ta for oxidation protection was deposited on top of the electrode, the Mn diffusion was minimal up to 300 °C. Our experiment suggests that in actual magnetic tunneling junctions, the Mn diffusion to the insulation layer could be enhanced by the presence of the free oxygen radicals in the insulation layer produced during the plasma oxidation of the Al layer. © 2002 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 74 (1999), S. 1815-1817 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Trapped electrons and holes, and their dynamics, were visualized from spatially resolved capacitance–voltage (C–V) curves and dC/dV images using scanning capacitance microscopy. A trapped charge of 10−16–10−18 C, localized within 2 μm diam circular test structures, was imaged. The detrapping process of the trapped electrons can be explained with a quantum-mechanical tunneling model. © 1999 American Institute of Physics.
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