ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Infra-red and Raman spectra of [Me(NH3)6]X2 crystals were measured for Me = Co, Ni and X = Cl, Br, I. BF4, ClO4, PF6. The bands obtained were interpreted as being connected with vibrations of the [Me(NH3)6] octahedron. A far infra-red band at ca. 80 cm-1 was interpreted as an IR active lattice mode. A lattice dynamics model based on electrostatic interactions between point ions was developed. A low frequency Raman active lattice mode was theoretically foreseen by this model.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250010206
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