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  • 1
    Monograph available for loan
    Monograph available for loan
    London [u.a.] : Chapman & Hall
    Associated volumes
    Call number: 11/M 99.0457
    In: The Mineralogical Society series
    Type of Medium: Monograph available for loan
    Pages: xiv, 333 S.
    ISBN: 0412752905
    Series Statement: Mineralogical Society series 8
    Classification:
    Petrophysics
    Location: Reading room
    Branch Library: GFZ Library
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 108 (1991), S. 356-367 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In the aureole of the Beinn an Dubhaich granite, Skye, the minimum observed median forsterite-calcite-calcite dihedral angle varies from 110° at the olivinein isograd to about 165° (the equilibrium value) at the granite-limestone contact. Laboratory experiments were performed to investigate the kinetics of this textural change. It was found that the rate of change of the forsterite-calcite-calcite dihedral angle followed approximately first-order kinetics with an activation energy of 48±4 kJ mol-1 for fluid-present conditions, and 90 ±4 kJ mol-1 for fluid-absent conditions. Scanning ion imaging demonstrated that, at least in the early stages of textural change, solution-reprecipitation of the calcite was the rate determining step in the fluid-present runs. The latter result and the value of the activation energy are both consistent with the activation energy found by previous authors for (albeit zeroth order) silicate-aqueous solution solution-reprecipitation reactions. The value of activation energy for the dry data does not correspond to those for either grain boundary or volume diffusion of oxygen or magnesium in forsterite. The mechanism for textural equilibration in the fluid-absent runs is uncertain. Application of the experimentally-derived rate equation to the Beinn an Dubhaich marbles gave activation energies higher than those obtained experimentally. It is concluded from consideration of grain growth effects that activation energies derived from the Beinn an Dubhaich marbles probably reflect textural equilibration under predominantly fluid-absent conditions.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 108 (1991), S. 368-383 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Fluid-calcite-calcite dihedral angles have been measured for fluids in the system H2O−CO2−NaCl, between 1 and 2 kbar, and 550–750° C. It is found that the calcite-calcite-H2O dihedral angle decreases steadily with addition of NaCl from a value of about 80° (pure water) to 44° (60 wt% NaCl). The CO2−H2O system displays a well-defined minimum at $$X_{CO_2 } = 0.5$$ , with a dihedral angle of 50°, in contrast to those of pure CO2 and H2O which are 90° and 80° respectively. Experiments containing fluids which are immiscible at run conditions showed a bimodal distribution of dihedral angles in the CO2−H2O−NaCl system, which can be approximately correlated with the compositions of the two fluid phases. Such bimodality was only observed for immiscible fluids in the H2O−NaCl system if the quench rate exceeded about 200°C per min. This is probably due to the extremely rapid establishment of the single phase dihedral angle on quenching. The fluid phase topology in devolatilising marbles will only be a connected network for very saline brines and fluids with $$X_{CO_2 } $$ close to 0.5. Fluids trapped in fluid inclusions in calcite grains in marbles may be predominantly H2O-rich or CO2-rich, and of low salinity. All other fluid compositions in the H2O−CO2−NaCl-calcite system will occupy isolated pores, the largest of which will grow at the expense of the smallest. Escape of fluid produced during devolatilisation reactions under such conditions will occur by fluid overpressuring and hydrofracture. In contrast, previous experimental studies of quartz-fluid dihedral angles between 950° and 1100° C (Watson and Brenan 1987) predict that quartz-dominated lithologies will permit pervasive flow of H2O−NaCl fluids, but not of H2O−CO2 fluids. Documented geological examples of differences in permeability and fluid flow mechanism between metamorphic argillites, psammites and limestones which support the results of the experimental studies are discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 118 (1995), S. 356-364 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract An investigation was made of the effect of trace amounts of feldspar (Na and/or K) on dihedral angles in the quartz-H2O-CO2 system at 4 kbar and 450–1050°C. Quartz-quartz-H2O dihedral angles in feldspar-bearing quartz aggregates are observed to be the same as those in pure quartz aggregates at temperatures below 500°C. Above this temperature, they decrease with increasing temperature until the solidus. The final angle at the inception of melting is about 65° for microcline-quartz-H2O and microcline-albite-quartz-H2O, and much less than 60° (the critical value for formation of grain-edge fluid channels in an isotropic system) for the albite-quartz-H2O system. CO2 was observed to produce a constant quartz-quartz-fluid dihedral angle of 97° in feldspar-bearing quartz aggregates at all temperatures studied. Also examined were the dihedral angles for the two co-existing supersolidus fluids in quartz aggregates. In all systems the quartz-volatile fluid angle is greater than 60°, whereas the quartz-melt angle is lower than 60°. Both super-solidus angles decrease with increasing temperature. The transition from nonconnected to connected poro- sity with increasing temperature observed in the quartz-albite-H2O system some tens of degrees below the solidus (termed a permeability transition), if a common feature of rocks near their melting points, will play an important role in controlling the permeability of high-grade rocks to aqueous fluids.
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  • 5
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Ballachulish Igneous Complex consists of an outer quartz diorite and an inner granite, emplaced at about 300 MPa, initially at 1000 to 1050 °C. The contact aureole (0.5–2 km wide) occurs in metapelites and metapsammites plus minor graphitic slates, carbonate rocks and metaquartzites. A textural examination of the arkosic Appin Quartzite, which was previously believed to have melted only within a few metres of the intrusion, demonstrates that partial melting occurred up to 500 m away from the vertical eastern contact. Coupling petrographic observations with Qtz-Ab-Or-H2O phase relations, we determined both the amounts of actual melt and the maximum possible amounts of melt in the samples. Melting efficiency was everywhere less than 100% and decreased with distance from the intrusion. Though perhaps not the only possible source of fluid throughout the aureole, simple models demonstrate that H2O evolution from the pluton would have been volumetrically sufficient and persisted long enough to account for the observed partial melting. A time-integrated fluid flux of 7000 kg/m2 from the pluton is necessary to account for the observed amounts of partial melt in the Appin Quartzite. From its inefficiency, we infer that infiltration of the Appin Quartzite cannot have occurred along interconnected grain-edge channels. Rather, it was controlled by hydraulic fracturing, with fracture density determining melting efficiency. Bulk-rock permeability is calculated to be 10−20 m2, an order of magnitude lower than that necessary to permit pervasive flow of all the fluid exsolving from the pluton. There is little difference between the calculated time-integrated fluid flux through the Appin Quartzite on the eastern flank and an estimate of the infiltrating flux through the pelitic Leven Schist on the western flank in the time interval during which both rock types were above their solidus temperature, despite differences in their equilibrium quartz-H2O dihedral angles at temperatures immediately below the solidus, and differences in the attitude of the contact. The rates of H2O expulsion from the cooling pluton are consistent with highly efficient fracture-dominated flow, allowing insufficient time for textural equilibration.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Visual geosciences 5 (2000), S. 1-14 
    ISSN: 1610-2924
    Keywords: textures ; partial melting ; contact metamorphism ; contact aureole ; Ballachulish
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Recognition of partial melting in metamorphic rocks is a difficult task, as leucosomes can have a variety of origins. By comparing the observed values of the solid-solid dihedral angles with the known equilibrium values, and close examination of the shapes and compositions of feldspar grains, it is possible to unequivocally identify melt textures. Textural relations in a series of meta-arkose samples from the contact aureole of the Ballachulish Igneous Complex in the Scottish Highlands demonstrate that, when former melt pockets are not highly deformed, their presence can be recognized petrographically, by detailed examination of textures on the grain scale. Identification of melt textures and their distribution in the Ballachulish aureole has led to appreciation of the fundamental role of magmatically derived H2O in producing the partial melting. It has also allowed calculation of the H2O flux involved, and recognition that fractures were the major fluid pathways during metamorphism.
    Type of Medium: Electronic Resource
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  • 7
    Publication Date: 1998-09-01
    Print ISSN: 0022-1376
    Electronic ISSN: 1537-5269
    Topics: Geosciences
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  • 8
    Publication Date: 1989-05-01
    Print ISSN: 0022-1376
    Electronic ISSN: 1537-5269
    Topics: Geosciences
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  • 9
    Publication Date: 2020-07-10
    Description: Replacive symplectites (vermicular intergrowths of two or more minerals) are an important feature of layered igneous intrusions, recording evidence of late-stage reactions between interstitial liquid and crystals. They are common throughout the Layered Series of the 564 Ma Sept Iles layered intrusion in Quebec, Canada, and fall into three types: oxy-symplectites, ‘Type I’ symplectites, and ‘Type II’ symplectites. Oxy-symplectites are comprised of magnetite and orthopyroxene, nucleate on olivine primocrysts, and form via the reaction Olivine + O2 → Orthopyroxene + Magnetite; Type I symplectites (of which there are 3 distinct categories) are comprised of anorthitic plagioclase with pyroxene, amphibole, or olivine vermicules, grow from primocryst oxide grains, and replace primary plagioclase; and Type II symplectites (of which there are 2 distinct categories) are comprised of anorthitic plagioclase with orthopyroxene ± amphibole vermicules, grow from primocryst olivine grains, and replace primocryst plagioclase. Rare symplectites composed of biotite and plagioclase are also present. Symplectite growth occurred at 700-1030 °C with pressure constraints of 1-2 kbar. We propose that Type I symplectites, and some Type II symplectites, formed from interaction of primocrysts with residual Fe-rich liquid as a consequence of differential loss of an immiscible Si-rich liquid conjugate from the crystal mush. However, redistribution and concentration of hydrous fluids in incompletely solidified rock, or an increase in water activity of the interstitial melt, may be more plausible processes responsible for the formation of replacive symplectites comprising abundant hydrous mineral assemblages.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 10
    Publication Date: 2011-08-01
    Description: Recognising the former presence of melt in rocks which have undergone cooling and exhumation over millions of years following regional metamorphism commonly relies on the correct interpretation of grain-scale structures visible only under the microscope. The evolution of these structures during prograde melting and, later, retrograde cooling can be understood using concepts derived from experimental simulation and materials science.
    Print ISSN: 1811-5209
    Electronic ISSN: 1811-5217
    Topics: Geosciences
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