ALBERT

Description: Results are reported on the performance of the NASA and NCAR PAN measurement instruments during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation 2 (CITE 2) mission in August-September 1986. Both PAN instruments employ the electron-capture gas chromatography approach for detection and are calibrated using a liquid PAN standard in a diffusion tube. Details of the instrument design, experimental protocols, and CITE 2 test flights are discussed, and the results are presented in extensive tables and graphs. It is found that the NASA and NCAR instruments agreed to within about 17 parts per trillion by volume (pptv) when the PAN mixing ratio was below 100 pptv and to within about 25 percent when the mixing ratio was 100-300 pptv.

Description: Results are reported from a comparison of three tropospheric NO measurement instruments during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation 2 (CITE 2) in summer 1986. The instruments tested were those used in CITE 1 (Hoell et al., 1987): a two-photon LIF system and two chemiluminescence systems. It is found that the mixing ratios obtained with the three systems agreed to within 15-20 parts per trillion volume (pptv) for sampling perods of 1-6 min at mixing ratios less than 20 pptv; the average difference between pairs of measurements was 5-7 pptv, which is considered to be the uncertainty in state-of-the-art ambient NO measurements.

Description: Results from an airborne intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and included a laser differential absorption method and two grab sample/gas chromatograph methods. Measurements were obtained during approximately 90 flight hours, during which the CO mixing ratios ranged from about 60 to 140 ppbv. The level of agreement observed for the ensemble of measurements was well within the overall accuracy stated for each instrument. The correlation observed between the measurements from the respective pairs of instruments ranged from 0.85 to 0.98, with no evidence for the presence of either a constant or proportional bias between any of the instruments.

Description: Results from an airborne intercomparison of techniques to measure tropospheric levels of nitric oxide (NO) are discussed. The intercomparison was part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and was conducted during missions flown in the fall of 1983 and spring of 1984. Instruments intercompared included a laser-induced fluorescence (LIF) system and two chemiluminescence instruments (CL). NO mixing ratios from below 5 pptv (parts per trillion by volume) to greater than 100 pptv were reported, with the majority less than 20 pptv. Good correlation was observed between the measurements reported by the CL and LIF techniques. The general level of agreement observed for the ensemble of measurements obtained during the two missions provides the basis from which one can conclude that equally 'valid' measurements of background levels of NO can be expected from either CL or LIF instruments. At the same time the periods of disagreement that were observed between the CL and LIF instruments as well as between the two CL instruments highlight the difficulty of obtaining reliable measurements with NO mixing ratios in the 5-20 pptv range and emphasize the vigilance that should be maintained in future NO measurements.

Description: Results from an airborne intercomparison of techniques to measure tropospheric levels of sulfur trace gases are presented. The intercomparison was part of the NASA Global Tropospheric Experiment (GTE) and was conducted during the summer of 1989. The intercomparisons were conducted on the Wallops Electra aircraft during flights from Wallops Island, Virginia, and Natal, Brazil. Sulfur measurements intercompared included sulfur dioxide (SO2), dimethylsulfide (DMS), hydrogen sulfide (H2S), carbon disulfide (CS2), and carbonyl sulfide (OCS). Measurement techniques ranged from filter collection systems with post-flight analyses to mass spectrometer and gas chromatograph systems employing various methods for measuring and identifying the sulfur gases during flight. Sampling schedules for the techniques ranged from integrated collections over periods as long as 50 minutes to one- to three-minute samples every ten or fifteen minutes. Several of the techniques provided measurements of more than one sulfur gas. Instruments employing different detection principles were involved in each of the sulfur intercomparisons. Also included in the intercomparison measurement scenario were a host of supporting measurements (i.e., ozone, nitrogen oxides, carbon monoxide, total sulfur, aerosols, etc.) for purposes of: (1) interpreting results (i.e., correlation of any noted instrument disagreement with the chemical composition of the measurement environment); and (2) providing supporting chemical data to meet CITE-3 science objectives of studying ozone/sulfur photochemistry, diurnal cycles, etc. The results of the intercomparison study are briefly discussed.

Description: An overview of the airborne intercomparisons of CO, NO, and OH instrumentation is presented in this first paper of the series on the NASA Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation (GTE/CITE 1). This paper provides the reader with background information about several important characteristics of the project. These include the overall objectives and approach, the measurements taken, the intercomparison protocol, aircraft platform, profiles of each aircraft flight, and the participants. A synopsis of the overall results of the CO, NO, and OH instrument intercomparisons is also included. Companion papers discuss the detailed results of the CO and NO intercomparison tests as well as pertinent scientific findings.

Description: The proposed Information Sciences Experiment System (ISES) will offer the opportunity for real-time access to measurements acquired aboard the Earth Observation System (Eos) satellite. These measurements can then be transmitted to remotely located ground based stations. The application of such measurements to issues related to atmospheric science which was presented to a workshop convened to review possible application of the ISES in earth sciences is summarized. The proposed protocol for Eos instruments requires that measurement results be available in a central data archive within 72 hours of acquiring data. Such a turnaround of raw satellite data to the final product will clearly enhance the timeliness of the results. Compared to the time that results from many current satellite programs, the 72 hour turnaround may be considered real time. Examples are discussed showing how real-time measurements from one or more of the proposed Eos instruments could have been applied to the study of certain issues important to global atmospheric chemistry. Each of the examples discussed is based upon a field mission conducted during the past five years. Each of these examples will emphasize how real-time data could have been used to alter the course of a field experiment, thereby enhancing the scientific output. For the examples, brief overviews of the scientific rationale and objectives, the region of operation, the measurements aboard the aircraft, and finally how one or more of the proposed Eos instruments could have provided data to enhance the productivity of the mission are discussed.

Description: Spectroscopic measurements are required to define the spectral background and provide the detailed spectral information that is essential for the design of species-specific systems and the analysis of data obtained from them. This function of spectroscopic measurements is expected to be an important part of any tropospheric remote-sensing program, and both emission and absorption spectroscopy are relevant in this context. The data from such observations are of value to tropospheric science in their own right, during the initial phases while species-specific techniques and instruments are under development. In addition, there are a number of unresolved problems in tropospheric radiative transfer and spectroscopy which presently limit the accuracy and reliability of all remote sensing methods. Only through a supporting program of spectroscopic measurements can progress be made in improving the understanding of these aspects of radiative transfer and ultimately reaching the desired confidence in the accuracy to species-specific monitoring techniques.

Description: A summary of the results from the field expeditions conducted within the framework of the Global Tropospheric Experiment (GTE) is presented. The missions reviewed include the Chemical Instrumentation Test and Evaluation missions and the Atmospheric Boundary Layer Experiment missions. Future GTE missions are also briefly reviewed.

Description: Before the mission, the PI (principal investigator) was instrumental in securing real-time use of the new 51-level ECMWF (European Centre for Medium Range Weather Forecasts) meteorological data. During the mission, he provided flight planning and execution guidance as meteorologist for the P-3B. Mr. Yong Zhu computed and plotted meteorological forecast maps using the ECMWF data and transmitted them to the field from MIT (Massachusetts Institute of Technology). Dr. John Cho was in the field for the Christmas Island portion to extract data from the on-site NOAA (National Oceanic and Atmospheric Administration) radars for local wind profiles that were used at the flight planning meetings. When the power supply for the VHF radar failed, he assisted the NOAA engineer in its repair. After the mission, Mr. Zhu produced meteorological data memos, which were made available to the PEM (Pacific Exploratory Mission)-Tropics B science team on request. An undergraduate student, Ms. Danielle Morse, wrote memos annotating the cloud conditions seen on the aircraft external monitor video tapes. Dr. Cho and the PI circulated a memo regarding the status (and associated problems) of the meteorological measurement systems on the DC-8 and P-3B to the relevant people on the science team. Several papers by members of our project were completed and accepted by JGR (Journal of Geophysical Research) for the first special section on PEM-Tropics B. These papers included coverage of the following topics: 1) examination of boundary layer data; 2) water vapor transport; 3) tropospheric trace constituent layers; 4) summarizations of the meteorological background and events during PEM-Tropics B; 5) concomitant lidar measurements of ozone, water vapor, and aerosol.