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  • 1
    ISSN: 1477-7835
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Economics
    Notes: Recycling of preservative-treated waste wood can be an environmental problem due to toxic elements being emitted into the environment. Pyrolyzing CCA-treated wood at low temperature without any oxidizing agent is applied to capture the arsenic fraction in the solid residue. The influence of well-defined process parameters such as pyrolysis temperature, time and heating rate are studied. Arsenic contents in the gas phase were measured by a wet chemical method while structural analysis of the arsenic reaction products was determined with Transmission Electron Microscopy.
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  • 2
    ISSN: 1611-4663
    Keywords: Wood charcoal ; Chemical structure ; X-ray photoelectron spectroscopy ; X-ray ; Carbonization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Wood charcoal carbonized at various temperatures was analyzed by X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), and X-ray diffractometry to investigate the changes of chemical structures during the carbonization process. From the infrared spectra, the carbon double bonds and aromatic rings were seen to form at a carbonization temperature of about 600°C. From the XPS spectra, the ratio of aromatic carbons increased in the temperature range 800–1000°C and over 1800°C. The condensation of aromatic rings proceeded as carbonization progressed. The drastic reduction of electrical resistivity of charcoals was observed in almost the same temperature range. It was found that the condensation of aromatic rings had some relation to the decline in electrical resistivity. Wood charcoal carbonized at 1800°C was partly graphitized, a finding supported by the results of X-ray diffraction and XPS. The functional groups containing oxygen diminished with the increase in carbonization temperature.
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  • 3
    ISSN: 1611-4663
    Keywords: Fire retardancy ; Plywood ; Glue-additive treatment ; Char length ; XPS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A practical approach to enhancing the fire retardancy of wood-based materials by adding fire-retardant chemicals to the glue was developed. Plywoods were manufactured using urea melamine formaldehyde resin mixed with ammonium pentaborate or dihydrogen phosphate. Treated plywoods had better incombustibility than untreated ones. X-ray photoelectron spectroscopy (XPS) analysis clearly demonstrated the distribution of boron and phosphorus, which had migrated from the glue to the wood, contributing to better fire retardant properties. The cross-sectional micrographs from scanning electron microscopy showed that untreated specimens exhibited a foamy structure near the interface in the glue layer and the deformed structure of wood cells. The cell structure and cell wall thickness retained intact in the specimens treated with urea melamine formaldehyde resin mixed with ammonium pentaborate or dihydrogen phosphate. When observing the effect of the thickness of overlay veneers on incombustibility, a shorter glowing time was obtained from the specimens with a thicker surface layer when the fire retardant chemical was added at 2%, but the differences were smaller at the higher chemical retention of 4%. A similar tendency was observed for the char length.
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  • 4
    ISSN: 1611-4663
    Keywords: Carbonized wood powder ; Removal ; Mercury Specific surface area ; Environmental pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Sugi (Cryptomeria japonica D. Don) wood powder was carbonized at varying temperatures and used as a material to remove heavy metals from their aqueous solutions. Single solutions of mercuric chloride and mixed aqueous solutions containing lead nitrate, arsenic chloride, and cadmium chloride as well as mercuric chloride (1, 5, and 10 ppm) were prepared to determine the efficiency of removing heavy metals by these materials. Wood powder and carbonized wood at 200°, 600°, and 1000°C removed mercury within the concentration range 1–10ppm; mercury was preferentially removed even when mixed with other heavy metals. Wood powder carbonized at 1000°C achieved the best removal of heavy metals among the wood-based materials and even commercial activated carbon in both single and mixed solutions.
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  • 5
    ISSN: 1611-4663
    Keywords: Wood cement composites ; Supercritical fluid ; Curing of cement ; Carbon dioxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of wood science 46 (2000), S. 89-92 
    ISSN: 1611-4663
    Keywords: Fullerenes ; Onion-like graphitic particles ; Wood charcoal ; Pyrolysis ; TEM
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 7
    ISSN: 1611-4663
    Keywords: Microstructure ; Spark plasma sintering ; Wood charcoals ; SEM ; TEM
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of wood science 44 (1998), S. 425-431 
    ISSN: 1611-4663
    Keywords: Thermal diffusivity ; Heat capacity ; Thermal conductivity ; Laser flash method ; Heating process
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The thermal diffusivity, specific heat, and thermal conductivity of 13 species of wood were measured by means of the laser flash method to investigate the thermal properties of wood during the heating process. The temperature ranged from room temperature to 270°C in air or under vacuum. The thermal diffusivity varied little during the heating process up to 240°C. The values in air were larger than those under vacuum. There was a linear relation between the specific heat and the ambient temperature, and the specific heat under vacuum was larger than that in air at high temperature. The thermal conductivity increased with density and the ambient temperature. To discuss the effects of the atmospheric conditions on the thermal constants of wood, a theoretical model of thermal conductivity was proposed and its validity examined, where the wood was assumed to be a uniformly distributed material composed of cell walls and air.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of wood science 46 (2000), S. 16-21 
    ISSN: 1611-4663
    Keywords: Carbon ; Wood charcoal ; Phenol formaldehyde resin ; Anisotropy ; Thermal properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Anisotropic thermal properties of molded carbon phenolic spheres (CPS), a mixture of sugi wood charcoal powders and phenol formaldehyde resin molded with a hot press, were investigated. The effects of the carbonizing temperature, particle size of chars, and density of the CPS on thermal properties were discussed. The molded CPS specimens were measured for their thermal properties using the laser flash method in both horizontal and vertical directions. The configuration of the CPS was observed by scanning electron microscopy. Anisotropy of the thermal properties (thermal diffusivity and thermal conductivity) between horizontal and vertical directions of the molded CPS was much higher than that of the uncarbonized molded phenolic spheres. Therefore, converting wood into molded CPS is an effective way to enhance the thermal-anisotropy properties. More marked effects of the carbonizing temperature, particle size, and density were observed in the horizontal direction than in the vertical direction. Anisotropy in thermal properties of the molded CPS may be considered an advantage for developing a new fire-retardant material for wood composites.
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  • 10
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire retardant fast-growing wood product was developed by coating with fire retardant and densifying the surface of wood. Trimethylol melamineformaldehyde resin mixed with phosphoric acid was coated on the wood surface, preheated and followed by hot pressing. Effects of the amount of coating, preheating temperature, and densifying ratio on the fire retardancy of sugi (Cryptomeria japonica D. Don) wood, and pressing temperature and pressing time on that of albizia (Paraserianthes falcataria Becker) wood were discussed. Bending strength, creep performance under fire and fire retardancy were evaluated. The results showed that the treatments improved the fire retardancy of woods without reduction in the bending strength. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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