ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The Liquid Phase Oxidation of Cyclohexene in Presence of Combinations of Compounds of Different MetalsThe oxidation of cyclohexene (1) with molecular oxygen in chlorobenzene solution at 80°C has been studied using cobalt, manganese and copper compounds, respectively in combination with molybdenum complexes. The selectivity has been determined of cyclohex-2-en-1-hydroperoxide (2), epoxycyclohexane (3), cyclohex-2-en-1-ol (4), cyclohex-2-en-1-one (5), 2,3-epoxy-cyclohexane-1-ol (6) and cyclohexane-1,2-diol (7), formed from reacted 1. Investigation of the consecutive reactions showed that 3 and especially 4 can react in different ways and moreover 4 inhibits the oxidation of 1. From these results conclusions were drawn on the mechanism of oxidation of 1.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19823240405
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