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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 7075-7079 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Amorphous oxide films with a composition of Bi2DyFe5O12 have been prepared by rf sputtering technique. The crystallization process was investigated using x-ray diffraction, differential thermal analysis, magnetic properties, magnetic resonance spectra, magneto-optical Faraday spectra, Raman spectra, and infrared reflection spectra. Amorphous oxide films exhibit very small magnetization and Faraday rotation at room temperature. At about 600 °C amorphous films crystallize to a garnet phase. With crystallization the magnetization and Faraday rotation increase rapidly. Raman and infrared spectra studies show the presence of tetrahedral sites in the amorphous films. As the annealing temperature increases, the peaks corresponding to octahedral and dodecahedral sites occur successively. It is of interest to note that amorphous oxide films containing Fe3+ ions show no magnetic resonance spectra at 71 and 300 K. The films annealed above crystallization temperature show a normal resonance spectrum. With increasing annealing temperature the linewidth decreases rapidly and the effective magnetization and anisotropy constant increase. © 1996 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 4114-4116 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Polycrystalline samples of Ba2(ZnxFe1−x)2Fe28O46 [(ZnxFe1−x)2−X, 0≤×≤1] X-type hexaferrites were prepared by the ceramic method. Magnetization, magnetic moment, and Curie temperature were investigated. With increasing Zn content the magnetization and magnetic moment increase linearly, but the Curie temperature decreases. A discrepancy between experimental and theoretical values of the magnetic moment, which increases with increasing Zn content, was observed. The effect may be due to the partial occupation of the octahedral sites by the Zn2+ ions and resulting in random spin canting.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1247-1249 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Polycrystalline samples of Ba2Cu2xZn2−2xFe28O46 (0≤X≤1) X-type hexaferrites were prepared by the classical ceramic method. Low-temperature magnetic properties and Curie temperature were investigated. The substitution of Zn2+ ion with Cu2+ ion leads to a decrease of the magnetic moment and an increase of Curie temperature due to the preference of Cu2+ ions for the octahedral sites of spinel S blocks.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 6955-6957 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The metastable compound Nd6Fe77B17 has been obtained by the crystallization from the amorphous phase in the Nd-Fe-B system. Its crystal structure is similar to that of the compound Nd2Fe23B3. At high temperature this metastable compound decomposes into α-Fe and Nd1.1Fe4B4 phases. The room temperature magnetization and coercivity are 154 A m2/kg and 12 kA/m, respectively.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 7099-7101 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Crystalline Co spinel ferrite films were prepared by rf sputtering on glass substrates without buffer layer and annealed at temperatures from 400 to 600 °C for 2 h in air. (100) texture was obtained in these films. The anisotropy constant, magnetic hysteresis loops, and magneto-optical Faraday spectra of the films were measured. The texture became poor when the films were annealed below 500 °C, but the perpendicular anisotropy constant Ku, squareness ratio R=(Mr/Ms)⊥/(Mr/Ms)(parallel) increased and showed peak values of 2.2×105 ergs/cm3 and 0.94, respectively, at an annealing temperature Ta=500 °C. For the film annealed at 600 °C (higher than the Curie temperature, 520 °C, of Co spinel ferrite), the texture recovered, but Ku and R dropped. The Faraday rotation spectra of Co spinel ferrite films showed a broad peak centered around 720 nm. The peak value increased monotonically with increasing annealing temperature. These results may be related to the Co ion-induced anisotropy and Co ion distribution in tetrahedral sites and octahedral sites.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 7103-7103 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: (BiDy)Fe5O12 films in the amorphous state were made by rf magnetron sputtering from a sintered Bi2DyFe5O12 ceramic target onto quartz substrates and confirmed by x-ray diffraction. The films were annealed at different temperatures ranging from 500 to 800 °C for 1 h in air. The crystallization temperature was about 650 °C, as measured by DTA method. Magnetization M versus temperature relation of well crystallized films showed both a compensation temperature Tcomp (80 K) and Curie temperature TC (563 K). The M-T curve from 1.5 to 600 K of amorphous film showed no definite TC or Tcomp; M measured in a field of 20 kOe decreased monotonously. The Faraday rotation (500–700 nm) of amorphous films was small. The M and Faraday rotation (633 nm) increased rapidly at the crystallization temperature. The Bi ion induced peak (550 nm) in the Faraday spectra got higher with the increasing annealing temperature and was up to 9.14 degree/μm. The Faraday spectra of films annealed at 650 °C for different times showed that the films were well crystallized after annealing for 10 min. The optical absorption of the films in the visible region varied little during the transformation from amorphous to polycrystalline.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 5103-5106 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Polycrystalline samples of X-type Ba2Me2Fe28O46 (Me2-X, Me=Fe, Co, and Mn) hexagonal ferrite have been prepared by the classic ceramic method. Low-temperature magnetic properties, Curie temperatures, and distribution of divalent cations were studied. The substitution of Fe2+ ions with Co2+ and Mn2+ ions causes a decrease of the spontaneous moment μ and the Curie temperature Tc of X-type hexaferrites. The lower μ and Tc of Co2-X hexaferrite originate from the smaller magnetic moment of Co2+ ions. In the case of Mn2-X, the lower μ may be due to the valence state of Mn and the lower Tc may be caused by the fact that the space distribution of 3d electrons of Mn is different from that of Fe. In the Co2-X and Fe2-X compounds the Co2+ and Fe2+ ions enter the octahedral sites of spinel S blocks.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 7230-7233 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The magnetic behavior of Nd10Fe84−xB6Inx (x=0,1,2) nanocomposites was investigated. It was found that a certain amount of indium (x=1) added to Nd10Fe84B6 magnets enhances the hard magnetic properties. The optimum coercivity and remanence ratio was increased from 5.0 kOe and 0.71 to 5.8 kOe and 0.83, respectively. The squareness of the hysteresis loop is improved greatly. The maximum magnetic energy product (BH)max increases remarkably from 12 to 18 MGOe. The origin for those enhancements is mainly attributed to the magnetically softened grain boundaries and enhanced crystallographical coherency by indium addition. The magnetic annealing is found to be helpful to enhance the coherency and coupling between hard and soft phases. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 372-375 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Polycrystalline samples of Ba2Me2Fe28O46 (Me2-X, Me=Ni, Cu, Mg, and Zn) hexagonal ferrite have been prepared by the classical ceramic method. Low-temperature magnetic properties and Curie temperature were investigated. The substitution of Fe2+ ion with Ni2+, Cu2+, and Mg2+ ions decreases spontaneous moment of Me2-X due to the preference of these ions for the octahedral sites of spinel S blocks. The substitution of Fe2+ ions with Zn2+ ions increases spontaneous moment due to the preference of Zn2+ ions for the tetrahedral sites. Lower Curie temperatures of Zn2-X, Cu2-X and Mg2-X compounds originate from the much small magnetic moment of these ions. Ni2+ ion has a magnetic moment smaller than Fe2+ ion, while Ni2-X compound has a Curie temperature as high as Fe2-X. It may be due to different space distribution of 3d electrons of Ni from Fe.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 65 (1994), S. 3404-3406 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: BaCoTiFe10O19 films were prepared by sputtering. The as-sputtered films are amorphus and have a magnetization of 5 emu/cm3 and a coercivity of 700 Oe at room temperature. Compared with bulk BaCoTiFe10O19 hexaferrites, the magnetization is much smaller, but the coercivity is higher. After annealing at about 750 °C in an oxygen atmosphere, the films crystallize into an M-type hexagonal ferrite with a preferred orientation of the (110) plane being parallel to the film surface. The magnetization increases rapidly to 320 emu/cm3, but the coercivity decreases to 100 Oe. The amorphous samples with a large amount of Fe3+ ions show no ferromagnetic magnetic resonance spectra. After crystallization a well-defined ferromagnetic resonance spectrum occurs. © 1994 American Institute of Physics.
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