ISSN:
1573-9171
Keywords:
diazene oxides, olefins, bromohydrazones
;
radicals, radical addition, cycloaddition
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The addition of 1-aryl-2-bromodiazene 1-oxides to olefins yields 1-aryl-2-(2-bromoalkyl)diazene 1-oxides (4). A radical mechanism of the reaction has been suggested. Compounds4 decompose to give bromohydrazones of formaldehyde and aldehydes. The structural factors that affect the rate of this process are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00696922
Permalink