ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The equilibrium structures of cis- and trans-1,3-diphosphetane were evaluated at the RHF/6-31g** level of optimization, with MP2 electron correlation correction. Both structures are puckered, the trans isomer being slightly lower in energy than the cis isomer. The inversion barrier in 1,3-diphosphetane is lower in energy than in phosphetane.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610081107
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